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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
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EC number: 200-663-8 | CAS number: 67-66-3
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
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Biodegradation in soil
Administrative data
Link to relevant study record(s)
Description of key information
The available data indicate that chloroform in soil is degraded only under specific conditions by methane-utilising bacteria. It is therefore assumed that chloroform is not biodegradable in soil.
Key value for chemical safety assessment
Additional information
The following text is copied from the draft EU Risk Assessment Report for chloroform prepared by the French authorities (France 2007), section 3.1.1.5.1.4 (page 50):
"No results from standardised biodegradation systems for soil and sediment are available. In a study performed on a sandy soil (Strand and Shippert, 1986), it was found that acclimation to an air-natural gas mixture stimulated the biological oxidation of chloroform to carbon dioxide. Acclimation of the soil was carried out for 3-8 weeks in an atmosphere of 1 % natural gas in air and around 200 ml of dechlorinated tap water/day constantly applied to the soil during this period. Degradation experiments were carried out using around 5 g of the acclimated soil and a chloroform concentration of 31 μg/kg wet soil. Incubations were performed at 22-25°C for 5 days. Chloroform oxidation continued up to 31 days but was inhibited by acetylene and high concentrations of methane, indicating that methane oxidising bacteria may catalyse chloroform oxidation. There was some chloroform oxidation observed in soils that were exposed only to ambient air (which may have included some hydrocarbons) but the rate in the natural gas enriched soils was four times greater. In conclusion, these results demonstrate that degradation of chloroform occurs only under certain aerobic conditions by methane-utilising bacteria. However, they cannot be used in the generic assessment. The first order rate constant for aerobic biodegradation in soil and sediment is 0 d-1."
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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