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EC number: 701-323-6 | CAS number: 2323519-79-3
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
SECTION 4: First aid measures
IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware
of the material(s) involved, and take precautions to protect themselves.
General information
4.1. Description of first aid measures
If exposed to excessive levels of dusts or fumes, remove to fresh air and get medical attention if
cough or other symptoms develop. Move to fresh air. If breathing is difficult, trained personnel
should give oxygen.
Inhalation
Immediately flush skin with plenty of water. Take off contaminated clothing and wash before reuse.
Get medical attention if symptoms occur.
Skin contact
Eye contact
If swallowed, rinse mouth with water (only if the person is conscious). Call a physician or poison
control centre immediately. Only induce vomiting at the instruction of medical personnel. Never
give anything by mouth to an unconsious person. Do not induce vomiting without advice from
poison control center.
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Ingestion
4.2. Most important symptoms
and effects, both acute and
delayed
Dusts may irritate the respiratory tract, skin and eyes.
4.3. Indication of any
immediate medical attention
and special treatment needed
No specific antidotes are recommended. Treat according to locally accepted protocols. For
additional guidance, refer to the current prescribing information or to the local poison control
information centre.
Fire-fighting measures
General fire hazards
5.1. Extinguishing media
This material will support combustion. May form explosible dust-air mixture if dispersed.
Suitable extinguishing
media : Water. Foam. Dry chemical powder.
Unsuitable extinguishing
media: Carbon dioxide (CO2).
5.2. Special hazards arising
from the substance or mixture
Explosion hazard: Avoid generating dust; fine dust dispersed in air in sufficient concentrations and
in the presence of an ignition source is a potential dust explosion hazard. During fire, gases
hazardous to health may be formed.
5.3. Advice for firefighters
Special protective
equipment for firefighters
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Special fire fighting
procedures
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk. Apply extinguishing media carefully to avoid creating airborne dust.
Specific methods
Use standard firefighting procedures and consider the hazards of other involved materials.
Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Use only
non-sparking tools. Dust deposits should not be allowed to accumulate on surfaces, as these may
form an explosive mixture if they are released into the atmosphere in sufficient concentration.
Wear appropriate protective equipment and clothing during clean-up. Ensure adequate ventilation.
Local authorities should be advised if significant spillages cannot be contained. For personal
protection, see section 8 of the SDS.
For non-emergency
personnel
Keep unnecessary personnel away. Use personal protection recommended in Section 8 of the
SDS.
For emergency responders
6.2. Environmental precautions
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take
precautionary measures against static discharge. Use only non-sparking tools. Avoid dispersal of
dust in the air (i.e., clearing dust surfaces with compressed air). Collect dust using a vacuum
cleaner equipped with HEPA filter. Stop the flow of material, if this is without risk.
Avoid discharge into drains, water courses or onto the ground.
6.3. Methods and material for
containment and cleaning up
Large Spills: Wet down with water and dike for later disposal. Shovel the material into waste
container. Following product recovery, flush area with water.
Small Spills: Sweep up or vacuum up spillage and collect in suitable container for disposal.
Never return spills to original containers for re-use.
Handling and storage
SECTION 7: Handling and storage
7.1. Precautions for safe
handling
Minimise dust generation and accumulation. Avoid significant deposits of material, especially on
horizontal surfaces, which may become airborne and form combustible dust clouds and may
contribute to secondary explosions. Routine housekeeping should be instituted to ensure that
dusts do not accumulate on surfaces. Dry powders can build static electricity charges when
subjected to the friction of transfer and mixing operations. Provide adequate precautions, such as
electrical grounding and bonding, or inert atmospheres. Ground/bond container and receiving
equipment. Minimise the use of plastics when handling this material. Explosion-proof general and
local exhaust ventilation. Avoid prolonged exposure. Wear appropriate personal protective
equipment. Observe good industrial hygiene practices.
Keep away from heat, sparks and open flame. Keep containers tightly closed in a dry, cool and
well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS).
7.2. Conditions for safe
storage, including any
incompatibilities
7.3. Specific end use(s)
Isolated Chemical Intermediate.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Biological limit values
No biological exposure limits noted for the ingredient(s).
Recommended monitoring
procedures
Follow standard monitoring procedures.
Derived no effect levels
(DNELs)
Not available.
Predicted no effect
concentrations (PNECs)
Not available.
8.2. Exposure controls
Ventilate as needed to control airborne dust. Use explosion-proof ventilation equipment if airborne
dust levels are high. Use process enclosures, local exhaust ventilation, or other engineering
controls to control airborne levels below recommended exposure limits. Good general ventilation
(typically 10 air changes per hour) should be used. Ventilation rates should be matched to
conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering
controls to maintain airborne levels below recommended exposure limits. If exposure limits have
not been established, maintain airborne levels to an acceptable level. If engineering measures are
not sufficient to maintain concentrations of dust particulates below the OEL (occupational exposure
limit), suitable respiratory protection must be worn.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Use personal protective equipment as required. Personal protection equipment should be chosen
according to the CEN standards and in discussion with the supplier of the personal protective
equipment.
General information
Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Select suitable chemical resistant protective gloves
(EN 374) with a protective index 6 (>480min permeation time).
- Hand protection
Wear safety glasses with side shields (or goggles). (eg. EN 166)
- Other
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. Wear respirator with dust filter.
Wear suitable protective clothing. (EN 14605 for splashes, EN ISO 13982 for dust)
Respiratory protection
Thermal hazards
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
as washing after handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing and protective equipment to remove contaminants. For advice on suitable
monitoring methods, seek guidance from a qualified environment, health and safety professional.
Wear appropriate thermal protective clothing, when necessary.
Hygiene measures
Environmental exposure controls
Hazard guidance and
control recommendations
Environmental manager must be informed of all major releases.
Stability and reactivity
10.1. Reactivity
Material is stable under normal conditions.
The product is stable and non-reactive under normal conditions of use, storage and transport.
10.2. Chemical stability
No dangerous reaction known under conditions of normal use.
10.3. Possibility of hazardous
reactions
Keep away from heat, sparks and open flame. Contact with incompatible materials. Minimise dust
generation and accumulation. Avoid dispersion as a dust cloud.
10.4. Conditions to avoid
10.5. Incompatible materials
Irritating and/or toxic fumes and gases may be emitted upon the product's decomposition.
Strong oxidising agents.
10.6. Hazardous
decomposition products
Disposal considerations
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Residual waste
Contaminated packaging
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
EU waste code
The Waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Disposal methods/information
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not
discharge into drains, water courses or onto the ground. Dispose of contents/container in
accordance with local/regional/national/international regulations.
Special precautions
Dispose in accordance with all applicable regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
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