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Diss Factsheets
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EC number: 405-270-7 | CAS number: 39562-17-9 BM
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
INHALATION
If inhaled, remove to fresh air. If breathing becomes difficult, administer oxygen and conduce him to the hospital.
CONTACT WITH THE SKIN
In case of skin contact, remove all contaminated clothing and shoes and wash the skin with copious amount of water for at least 15 minutes.
CONTACT WITH THE EYES
In case of contact with eyes flush immediately with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with finger.
INGESTION
If swallowed, rinse your mouth with water if victim is conscious. Consult a physician.
Fire-fighting measures
EXTINGUISHING MEDIA
Water spray, dry chemical powder, carbon dioxide or appropriate foams.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE
The heat decomposition or ignition of the product may produce toxic fumes and cause intoxication. Hazardous decomposition and combustion products include: carbon monoxide, carbon dioxide, NOx nitrogen oxides.
ADVICE FOR FIREFIGHTERS
For single units (packages): no special requirements needed.
For larger amounts (multiple packages/pallets) of product: since toxic, corrosive or flammable vapours might be evolved from fires involving the product and associated packaging, self contained breathing apparatus a full protective equipment are recommended for fire fighters (full facial mask with “Universal” filter). If possible, contain and collect fire fighting water for later disposal.
Accidental release measures
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
Prevention of skin and eye contact and personal clothing: wear protective clothing, protective glasses, rubber boots and heavy-duty rubber gloves.
Provision for sufficient ventilation/ respiratory protection: wear an independent respirator. Evacuate the area and aerate the zone contaminated by the spilt product after cleaning it away completely.
Control of dust: avoid forming clouds of dust/powder.
ENVIRONMENTAL PRECAUTIONS
Do not allow the product to enter water or the soil. Prevent it from entering the drains or sewers. Use suitable containers for preventing environmental pollution.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP
Use of absorbent material: vermiculite, dry sand, earth.
Cleaning methods: immediately contact emergency personnel. Evacuate and ventilate area. Wear appropriate personal protective equipment as specified in section 8. Clean up spills or leak immediately. Wash the contaminated area with water then absorb with an inert material (vermiculite, dry sand, earth, etc) and place in a closed chemical waste container for disposal.
Handling and storage
PRECAUTIONS FOR SAFE HANDLING
Containment, local and general ventilation, measures to prevent aerosol and dust generation and fire: the premises set up for the handling of the product must be fitted out with localised and controlled aeration systems (laminar flow hoods, etc.) capable of confining the dispersion of the active ingredient in the form of air-dispersed powder. Use hoods with interchangeable filters
Advice on general occupational hygiene: use suitable personal protection devices including certified respirators, protective safety glasses and compatible gloves resistant against chemical agents. Wash yourself with care after each handling operation. Never eat, drink or smoke during handling. Safety shower and washing stations for rinsing eyes must be provided.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
Specific storage requirements to control of the environmental effects: store in a dry, well-ventilated storage area at room temperature. Keep container tightly closed when not in use or empty.
Type of materials used in packing/containers of substance: pack the product in double polythene bags, individually sealed and store in cardboard bins or plastic drums fitted with an aluminium safety locking ring
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN3077
Shipping information
- Proper shipping name and description:
- environmentally hazardous substance, solid, N.O.S.
- Chemical name:
- methyl 2-(3-nitrobenzylidene)acetoacetate
- Language:
- English
- Labels:
- label 9 + label dangerous for the environment
Special provisions / remarks
- Special provisions:
- If the material is packed in 5H1, 5L1 or 5M1, they must be transported in vehicles or in closed containers. (V13). When there is a leak of materials and have been spilled thereof in a vehicle or in a container, it can be used only after being thoroughly cleaned and, if necessary, disinfected or decontaminated. All other goods and articles carried in the same vehicle or container shall be examined for possible contamination. (CV13)
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
EYE/ FACE PROTECTION
Wear protective glasses (EN 166) during the execution of any industrial type of operations. If necessary, wear a protective face shield.
SKIN PROTECTION
Use work overalls and/or coat, or dustproof overalls in Tyvek with hood for industrial type operations.
HAND PROTECTION
Type of material and thickness: wear nitrile or rubber gloves (neoprene). Minimum thickness of gloves: 0,11 mm.
Typical or minimum breakthrough times of the glove material: permeability is not anticipated with dry solid substances and therefore the duration of the protective gloves has not been calculated. The selected protective gloves have to satisfy the specifications of the EU Directive 89/686/EEC and the standard EN 374 derived from it.
RESPIRATORY PROTECTION
Wear an FFP1 dustproof mask or a Respirator connected to the air supply (if necessary, use a mask with an P1 type filter EN143)
ENVIRONMENTAL EXPOSURE CONTROLS
Avoid dispersion in the environment.
Stability and reactivity
CHEMICAL STABILITY
Stability studies show that the product is stable in normal conditions of storing (room temperature, relative humidity).
POSSIBILITY OF HAZARDOUS REACTIONS
No hazardous polymerisations occur.
HAZARDOUS DECOMPOSITION PRODUCTS
The heat decomposition or ignition of the product may produce toxic fumes and cause intoxication. Hazardous decomposition and combustion products include: carbon monoxide, carbon dioxide, NOx nitrogen oxides..
Disposal considerations
INCINERATION
Dissolve or mix the product with a combustible solvent then incinerate in an incinerator for chemical products equipped with a post-combustion and destruction system.
DISPOSAL METHODS SUITABLE FOR THE SUBSTANCE
This material and its containers must be disposed of as hazardous waste products.
SUITABLE DISPOSAL METHODS FOR COMBINED PACKAGING MATERIALS
The combined packaging materials must be disposed of as hazardous waste products.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.