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EC number: 232-089-9 | CAS number: 7785-87-7
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Oxidising properties
Administrative data
- Endpoint:
- oxidising solids
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 10/07/09 - 15/07/09
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: Study conducted to current accepted guideline.
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 009
- Report date:
- 2009
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.17 (Oxidising Properties (Solids))
- Deviations:
- no
- GLP compliance:
- no
Test material
- Reference substance name:
- Manganese sulphate monohydrate
- IUPAC Name:
- Manganese sulphate monohydrate
- Details on test material:
- - Name of test material (as cited in study report): MnSO4 (NOTE: the batch number relates to the monohydrate, as stated in the GLP study for water solubility)
- Substance type: extremely pale pink powder
- Physical state: Solid
- Lot/batch No.:08729
- Storage condition of test material: Room temperature in the dark.
Constituent 1
Results and discussion
Test results (Oxidising solids)open allclose all
- Sample tested:
- test mixture (not specified)
- Parameter:
- maximum burning rate
- Result:
- 0.943 other: mm/s
- Remarks on result:
- other: Fastest mixture, test material: cellulose, 10:90
- Sample tested:
- test mixture (not specified)
- Parameter:
- maximum burning rate
- Result:
- 0.741 other: mm/s
- Remarks on result:
- other: Second fastest mixture, test material: cellulose, 20:80
- Sample tested:
- reference mixture (not specified)
- Parameter:
- maximum burning rate
- Result:
- 1.424 other: mm/s
Any other information on results incl. tables
Table 1: Reference mixtures
% Barium Nitrate |
Observations |
Burning Time (s) |
Burning Rate (mm/s) |
10 |
The pile burned with a yellow flame which produced grey smoke and left black charred remains. |
217 |
0.922 |
20 |
The pile burned with an yellow/green flame which produced grey smoke and left black/grey charred remains. |
203 |
0.985 |
30 |
The pile burned with an yellow/green flame which produced grey smoke and left black/grey charred remains. |
245 |
0.816 |
40 |
The pile burned with a green/ yellow flame which produced grey smoke and left black/grey charred remains. |
227 |
0.881 |
50 |
The pile burned with a green/ yellow flame which produced grey smoke and left black/grey charred remains. |
196 |
1.020 |
60 |
The pile burned with an green/ yellow flame which produced grey smoke and left black/grey charred remains. |
166 |
1.205 |
70 |
The pile burned with an green/ yellow flame which produced grey smoke and left whitish/grey charred remains. |
161 |
1.242 |
80 |
The pile burned with a small green/yellow flame which self-extinguished without propagating combustion. |
- |
- |
90 |
The pile burned with a small green/yellow flame which self-extinguished without propagating combustion |
- |
- |
Maximum burning rate = 1.242 mm/s |
Table 2: Cellulose mixtures
% Barium Nitrate |
Observations |
Burning Time (s) |
Burning Rate (mm/s) |
10 |
The pile burned with a blue flame which produced grey smoke and left black charred remains. |
240 |
0.833 |
20 |
The pile burned with a blue flame which produced grey smoke and left black charred remains. |
303 |
0.660 |
30 |
The pile burned with a small blue flame which self-extinguished after propagating combustion over 12mm in 67 seconds. |
- |
- |
40 |
The pile burned with a small blue flame which self-extinguished without propagating combustion. |
- |
- |
50 |
The pile burned with a small blue flame which self-extinguished without propagating combustion. |
- |
- |
60 |
The pile burned with a small blue flame which self-extinguished without propagating combustion. |
- |
- |
70 |
The pile failed to ignite |
- |
- |
80 |
The pile failed to ignite |
- |
- |
90 |
The pile failed to ignite |
- |
- |
Maximum burning rate = 0.833 mm/s Maximum burning rate reference mixtures = 1.242 mm/s |
Table 3: Fastest Burning Rate Mixture, Test Material: Cellulose Ratio = 10:90
Test |
Observations |
Burning Time (s) |
Burning Rate (mm/s) |
1 |
The pile burned with a pale blue flame emitting pale grey smoke and leaving dark grey ash. |
243 |
0.823 |
2 |
The pile burned with a pale blue flame emitting pale grey smoke and leaving dark grey ash. |
212 |
0.943 |
3 |
The pile burned with a pale blue flame emitting pale grey smoke and leaving dark grey ash. |
219 |
0.913 |
4 |
The pile burned with a pale blue flame emitting pale grey smoke and leaving dark grey ash. |
253 |
0.791 |
5 |
The pile burned with a pale blue flame emitting pale grey smoke and leaving dark grey ash. |
258 |
0.775 |
6 |
The pile burned with a pale blue flame emitting pale grey smoke and leaving dark grey ash. |
268 |
0.746 |
Maximum burning rate = 0.943 mm/s Maximum burning rate of reference mixtures = 1.242 mm/s |
Table 4: Second Fastest Burning Rate Mixture, Test Material: Cellulose Ratio = 20:80
Test |
Observations |
Burning Time (s) |
Burning Rate (mm/s) |
1 |
The pile ignited with a pale blue flame which self-extinguished without propagating combustion. |
- |
- |
2 |
The pile burned with a pale blue flame which emitted grey smoke and left dark grey ash. |
270 |
0.741 |
3 |
The pile ignited with a pale blue flame which self-extinguished without propagating combustion. |
- |
- |
4 |
The pile burned with a pale blue flame which emitted grey smoke and left dark grey ash. |
296 |
0.676 |
5 |
The pile burned with a pale blue flame which emitted grey smoke but self-extinguished after propagating combustion over 100mm in 283 seconds, and left dark grey ash. |
- |
- |
6 |
The pile burned with a pale blue flame which emitted grey smoke and left dark grey ash. |
416 |
0.481 |
Maximum burning rate = 0.741 mm/s Maximum burning rate of reference mixtures = 1.242 mm/s |
Applicant's summary and conclusion
- Interpretation of results:
- GHS criteria not met
- Conclusions:
- MnSO4 is not an oxidiser
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