Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 412-000-1 | CAS number: 125051-32-3 CGI 784
Guidance on Safe Use
Administrative data
First-aid measures
Inhalation:
Remove to fresh air, if not breathing give artificial respiration. If breathing is difficult, give oxygen and
get immediate medical attention.
Skin:
After contact with skin, wash immediately with plenty of water and soap.
Get medical attention if irritation occurs.
If clothing is contaminated, remove and launder before reuse.
Eyes:
Immediately flush the eye(s) with lukewarm, gently flowing water for 15 minutes or until the chemical is
removed. Get immediate medical attention if irritation persists.
Ingestion:
Do not induce vomiting. If vomiting occurs naturally, have casualty lean forward to reduce the risk of
aspiration. Seek medical attention immediately.
Notes to physician:
May aggravate pre-existing liver disease or jaundice, kidney disease and anemia.
Fire-fighting measures
Suitable extinguishing media:
carbon dioxide, dry powder, foam, water spray
Unsuitable Extinguishing Media:
water jet
Hazardous combustion products:
Burning may produce toxic combustion products., Carbon oxides., Hydrogen fluoride., Nitrogen oxides
Hazards during fire-fighting:
Standard procedure for chemical fires.
The product can form an explosive dust/air mixture. For further information, see Section 7 Explosion
Hazards.
Product has an exceptional propensity to generate heat and burn briskly once ignited.
Protective equipment for fire-fighting:
Wear self-contained breathing apparatus and chemical-protective clothing.
Accidental release measures
Cleanup:
Sweep up and shovel into suitable containers for disposal.
Avoid raising dust.
Wear suitable protective equipment.
Should not be released into the environment.
Handling and storage
Handling
General advice:
As with all industrial chemicals, use good industrial practices when handling. Avoid eye, skin, and clothing contact. Do not inhale. Do not taste or swallow. Use only with adequate ventilation. Keep away from heat, sparks and flame. Store in area with appropriate fire protection.
Protection against fire and explosion:
Combustible powder. - Avoid creating dusty conditions. - Grounding is required when emptying into a conductive container. - When flammable solvents are present, the container must be inerted or the system otherwise designed to prevent or contain an explosion. Seek expert advice. In addition, for products packaged in fused-lined (coated) fiber drums, fiber drums with conductive liners, steel drums, steel pails, and Type " C " FIBC (bulk bags), or other conductive the following instructions also apply: -Always ground this package before emptying. The user is responsible for designing the system to handle solid and ensuring proper training of employees in the system's use.
Storage
General advice:
Store at temperatures below 25°C (77°F).
Keep away from heat and sources of ignition.
Keep container tightly closed in a dry, cool and well-ventilated place.
Store in area with appropriate fire protection.
Keep only in the original container.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 1325
Shippingopen allclose all
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 1325
Shipping information
- Proper shipping name and description:
- FLAMMABLE SOLID, ORGANIC, N.O.S.
- Chemical name:
- ORGANOTITANIUM COMPLEX
- Labels:
- 4.1
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 1325
Shipping information
- Proper shipping name and description:
- FLAMMABLE SOLID, ORGANIC, N.O.S.
- Chemical name:
- ORGANOTITANIUM COMPLEX
- Labels:
- 4.1
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Exposure Guidelines
Titanium, bis(.eta.5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]- (9CI) (125051-32-3) CIEL 8h TWA: 0.15 mg/m3 (Inhalable)
Toxic effects on blood, kidney and liver observed in animal study
Engineering Controls:
Exposure limit(s) should be monitored using suitable analytical equipments.
Work in well ventilated areas. Do not breathe dust.
Personal protective equipment
Respiratory protection:
Wear a NIOSH-certified respirator as necessary.
Eye protection:
Wear safety goggles (chemical goggles) if there is potential for airborne dust exposures.
Body protection:
Wear chemical resistant gloves and protective clothing.
General safety and hygiene measures:
There are no OSHA or ACGIH exposure guidelines available for component(s) in this product., Eye wash station and safety shower should be available in immediate work area.
Stability and reactivity
Stable
Conditions to avoid: Avoid electro-static discharge.
Avoid sources of ignition. Avoid temperature extremes.
Substances to avoid: strong acids, strong bases, strong oxidizing agents
Possibility of Hazardous Reactions: No hazardous reactions known.
Hazardous decomposition products: No decomposition expected under normal storage conditions.
Disposal considerations
Waste disposal of substance:
Dispose of in accordance with national, state and local regulations.
Contaminated packaging:
Do not cut or weld containers, even empty containers.
Empty containers or liners may retain product residues.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
