Registration Dossier
Registration Dossier
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EC number: 201-469-6 | CAS number: 83-32-9
Guidance on Safe Use
Administrative data
First-aid measures
General instructions
If health problems occur or if you suspect that your health may have been affected, contact your physician and give the information stated on this safety data sheet. It is necessary to keep the vital functions going until a physician arrives (i.e. check heartbeat, ensure artificial respiration, heart massage). If the affected person has lost consciousness or if you believe that he/she may lose consciousness, transport the person to a healthcare provider in a stabilised position, lying on his/her side.
When inhaled
Move the victim to fresh air, keep him or her in absolute repose, inhalation of oxygen. Half sitting position, prevent person from losing heat. Transport to doctor.
SYMPTOMS AND EFFECTS: headache, giddiness, nausea, airway eyes irritation
In case of contact with skin
Wash the affected area thoroughly with water and soap for 10-15 minutes.
SYMPTOMS AND EFFECTS: possible irritation, dermatitis, itching.
In case of contact with eyes
Wash the eye with a plenty of water or physiological solution for 10-15 minutes from inner to outer eye corner.
If the afflicted person is wearing contact lenses, they must be removed immediately. Call for a professional medical help promptly.
SYMPTOMS AND EFFECTS: irritation, lacrimation, burn.
When swallowed
Have the victim drink approx. 2 dl of water and call for a professional medical help promptly. After ingestion possible administrate activated charcoal as a slurry (20 tablets (cca 15g) /250 ml water). Do not induce vomiting.
SYMPTOMS AND EFFECTS: irritation, burning of oesophageal or gastrointestinal tract
Fire-fighting measures
Suitable extinguishing media
Powder or snow fire extinguisher. In the case of a large-scale fire, use heavy foam with a polar foam maker, or a split water stream. Containers should be cooled with a screen of water. You should try to get them out of the fire.
Extinguishing media which shall not be used for safety reasons
Direct water stream.
Special exposure hazards from the substance or preparation itself, combustion products, resulting gases
While the substance burns, it produces toxic products. Mixtures of the steam of the substance with the air are explosive.
Special protective equipment for fire-fighters
When fighting the fire in the dangerous zone, you must use an isolation breathing apparatus and a protective suit against heat of radiation.
Further data:
Temperature class: T1
Explosive group: IIA
Accidental release measures
Personal precautions
Close the place of the accident. When managing the emergency, use the personal emergency equipment described in Personal Protective Section. Remove or switch off all sources of ignition. Avoid generation of dust. Ensure supply of fresh air in enclosed room.
Environmental precautions
Prevent the substance from leaking into the sewerage system, ground and surface water or into the soil.
Method for cleaning
Collect spilled substance and incinerate everything including contaminated soil at the appropriate facility.
The contaminated material must be handled as a waste.
Handling and storage
Handling
Avoid formation of dust or possible vapours (sublimate when processing) at workplace and atmosphere – ensure sufficient ventilation and exhaustion. Use personal protective equipment according to Personal Protection section. Avoid leakage or spillage of the product during handling operations. Avoid contact with open fire, sparks or hot surfaces.
Storage
Store under common storage conditions. Ensure sufficient ventilation. Store only in enclosed packages.
Store in dry area. Use protective equipment.
Specific use
Not determined.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Occupational exposure controls
Collective protection measures:
Plant-wide and local ventilation, effective exhaust system, automation, hermetic sealing.
Individual protection measures :
The staff must wear personal protection equipment (PPE) to protect their eyes, hands and skin. This equipment must be suitable for the nature of the activities they do. Wherever the technical means do not enable obeying the exposure limits determined for the working environment or ensuring that inhaling the substance does not affect a persons’ health, the staff must use also suitable protection of the respiratory system. If the staff are to use this equipment permanently while working, it is necessary to include safety breaks, if required by the nature of the PPE. All the PPE must be kept in good condition. Any polluted or damaged equipment must be replaced immediately.
RECOMMENDED PERSONAL PROTECTION EQUIPMENT (PPE):
· Respiratory protection: In case of short-time exposure or low concentration use the respirator against dust or mask with filter against organic vapours, in case of high concentrations and long-term exposure use self-contained breathing apparatus.
· Eye protection: Protective shield or goggles
· Hand protection: Everyday working activities (possible contact during operation or getting stained in the case of leakage): Protective gloves (Glove material: Nitrile; Layer thickness: 0.85 mm; Penetration time: 480min.)
· Skin protection: protective suit and footwear, unprotected skin must be treated with a protective lotion before beginning to work.
· General safety and hygienic measures: Follow the rules of personal hygiene. Do not eat, drink or smoke while working! Wash your hands as well as any uncovered parts of your body well with water and soap, or treat them with suitable reparation lotion (e.g. Arretil, Stoko UV 18 ).
Environmental exposure controls
Follow the valid legal regulations governing the protection of the air and water.
Stability and reactivity
Conditions under which the product is stable
Conventional physical and chemical conditions
Conditions to avoid
High temperature, formation of explosive mixtures of substance vapours with air. Contact with open flame, hot surfaces, and sparks.
Material to avoid
substance under normal condition chemically resistant.
Hazardous decomposition products
Toxic vapour generation in case of a fire.
Disposal considerations
Methods of substance disposal
The substance must be handled in compliance with the valid legal regulations governing the disposal of waste as well as with other environmental regulations. Leaked product must be handled in the manner described in Handling Section and then handed over to a person authorised to handle hazardous waste. It is recommended to dispose of this substance by making it a material that can be further used for energy generation purposes. Contact the producer for any additional information.
Recommended classification of the waste under Decree No. 381/2001 Coll.: 07 01 99*, 07 01 99*, 16 05 08*
Methods of contaminated packaging disposal
Proceed in the same manner as when disposing of the product.
Recommended classification of the packaging waste under Decree No. 381/2001 Coll.: 15 01 10*
Legal regulations governing the disposal and handling of waste
The Czech Republic
Act No. 185/2001 Coll. on waste modifying certain other acts, in the valid wording including delegated
legislative (e.g. Decree No. 381/2001 Coll. determining the Catalogue of Waste)
The European Union
EP and Council Directive 2006/12/ES on waste
Council Directive 1991/689/EHS on dangerous waste
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
