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EC number: 202-767-9 | CAS number: 99-57-0
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Endpoint summary
Administrative data
Key value for chemical safety assessment
Effects on fertility
Description of key information
Reproductive toxicity study
Based on the data available from different studies, NOAEL for test material was considered to be of 616.0mg/kg bw/day for F0, F1 generation. When male and female rats were treated with test material orally. Thus, comparing this value with the criteria of CLP regulation test material is not likely to classify as reproductive toxicant.
Link to relevant study records
- Endpoint:
- one-generation reproductive toxicity
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- data from handbook or collection of data
- Justification for type of information:
- Data from peer reviewed journal
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- other: As mentioned below
- Principles of method if other than guideline:
- Reproductive toxicity study of test material was performed on CFE-S rats
- GLP compliance:
- not specified
- Limit test:
- no
- Justification for study design:
- No data available
- Species:
- rat
- Strain:
- other: CFE-S
- Details on species / strain selection:
- No data available
- Sex:
- male/female
- Details on test animals or test system and environmental conditions:
- TEST ANIMALS
- Age at study initiation: 15 week old - Route of administration:
- oral: feed
- Vehicle:
- not specified
- Details on exposure:
- Details on exposure
PREPARATION OF DOSING SOLUTIONS:
Test material mixed with feed .
DIET PREPARATION
- Rate of preparation of diet (frequency):No data available
- Mixing appropriate amounts with (Type of food )
- Storage temperature of food: No data available
VEHICLE
- Justification for use and choice of vehicle (if other than water):
- Concentration in vehicle: 0,97.5,616 mg/kg bw/day (0,1950,7800 ppm)
- Amount of vehicle (if gavage): No data available
- Lot/batch no. (if required): No data available
- Purity: No data available - Details on mating procedure:
- - M/F ratio per cage:1:1
- Length of cohabitation: No data available
- Proof of pregnancy: [vaginal plug / sperm in vaginal smear] referred to as [day 0 / day 1] of pregnancy:The presence of sperm during daily vaginal inspections (day 0 of pregnancy). .
- After ... days of unsuccessful pairing replacement of first male by another male with proven fertility.
- Further matings after two unsuccessful attempts: [no / yes (explain)]No data available
- After successful mating each pregnant female was caged (how): individual - Analytical verification of doses or concentrations:
- not specified
- Duration of treatment / exposure:
- 9 days ( from day 6 through day 15 of gestation )
- Frequency of treatment:
- Daily
- Details on study schedule:
- No data available
- Remarks:
- 0, 97.5,616 mg/kg bw/day (0,1950,7800ppm)
- No. of animals per sex per dose:
- Total:120
0 mg/kg bw/day:20male and 20 female
97.5mg/kg bw/day:20male and 20 female
616mg/kg bw/day:20male and 20 female - Control animals:
- yes
- Details on study design:
- No data available
- Positive control:
- No data available
- Parental animals: Observations and examinations:
- Parental animals observation and examinations
CAGE SIDE OBSERVATIONS: yes
DETAILED CLINICAL OBSERVATIONS: Yes
Time schedule:
BODY WEIGHT: Yes
Time schedule for examinations: biweekly
FOOD CONSUMPTION AND COMPOUND INTAKE (if feeding study):
Food consumption for each animal determined and mean daily diet consumption calculated as g food/kg body weight/day: Yes
Compound intake calculated as time-weighted averages from the consumption and body weight gain data: Yes / No / No data: No data available - Oestrous cyclicity (parental animals):
- No data available
- Sperm parameters (parental animals):
- No data available
- Litter observations:
- Each fetus was weighed, measured, and examined for gross abnormalities
- Postmortem examinations (parental animals):
- Postmortem examinations (Parent Animal)
SACRIFICE : All females were killed by chloroform inhalation on the 19th day of pregnancy and the fetuses delivered by Caesarian section.
Male animals: All surviving animals [describe when, e.g. as soon as possible after the last litters in each generation were produced.]: No data
Maternal animals: yes
GROSS NECROPSY: The number and distribution of fetuses, and the number of corpora lutea, live and
stillboin fetuses, and early and late resorptions were recorded
HISTOPATHOLOGY / ORGAN WEIGHTS
The tissues indicated in Table [#] were prepared for microscopic examination and weighed, respectively.:
macroscopic examination was performed - Postmortem examinations (offspring):
- Each fetus was weighed, measured, and examined for gross abnormalities. One-third of each litter was examined for visceral abnormalities by employing the slicing method of Wilson (1965). The remaining two-thirds were cleared and the bone structure stained with alizarin red S in order to define any skeletal abnormalities
- Statistics:
- Statistical analysis using the 95% confidence level. The methods used included chi square test, analysis of variance and t test, and the Fisher exact probability test (Snedecor, 1962)
- Reproductive indices:
- No data available
- Offspring viability indices:
- No data available
- Clinical signs:
- effects observed, treatment-related
- Description (incidence and severity):
- The 616 mg/kg /day dose group excreted blue-brown colored urine
- Dermal irritation (if dermal study):
- not specified
- Mortality:
- not specified
- Body weight and weight changes:
- no effects observed
- Food consumption and compound intake (if feeding study):
- not specified
- Food efficiency:
- not specified
- Water consumption and compound intake (if drinking water study):
- not specified
- Ophthalmological findings:
- not specified
- Haematological findings:
- not specified
- Clinical biochemistry findings:
- not specified
- Urinalysis findings:
- not specified
- Behaviour (functional findings):
- not specified
- Immunological findings:
- not specified
- Organ weight findings including organ / body weight ratios:
- not specified
- Histopathological findings: non-neoplastic:
- not specified
- Histopathological findings: neoplastic:
- not specified
- Other effects:
- not specified
- Reproductive function: oestrous cycle:
- not specified
- Reproductive function: sperm measures:
- not specified
- Reproductive performance:
- no effects observed
- Description (incidence and severity):
- No dose related significant deference were observed in the average number of implantation sites, live pups, or early and late resorptions per litter, or in the number of females with one or more resorption sites.
- Dose descriptor:
- NOAEL
- Effect level:
- 616 mg/kg bw/day (nominal)
- Based on:
- test mat.
- Sex:
- male/female
- Basis for effect level:
- clinical signs
- reproductive performance
- Remarks on result:
- other: overall no toxic effects on reproductive parameters
- Critical effects observed:
- not specified
- System:
- other: not specified
- Organ:
- not specified
- Treatment related:
- not specified
- Dose response relationship:
- not specified
- Relevant for humans:
- not specified
- Clinical signs:
- not specified
- Dermal irritation (if dermal study):
- not specified
- Mortality / viability:
- not specified
- Body weight and weight changes:
- no effects observed
- Food consumption and compound intake (if feeding study):
- not specified
- Food efficiency:
- not specified
- Water consumption and compound intake (if drinking water study):
- not specified
- Ophthalmological findings:
- not specified
- Haematological findings:
- not specified
- Clinical biochemistry findings:
- not specified
- Urinalysis findings:
- not specified
- Sexual maturation:
- not specified
- Organ weight findings including organ / body weight ratios:
- not specified
- Gross pathological findings:
- no effects observed
- Description (incidence and severity):
- No grossly abnormal pups were noted in the 97.5 mg/kg /day dose group (244 pups); there was one in control group (244 pups). One grossly abnormal pup was noted out of the 262 examined in the 616 mg/kg /day dose group.
- Histopathological findings:
- not specified
- Other effects:
- not specified
- Behaviour (functional findings):
- not specified
- Developmental immunotoxicity:
- not specified
- Dose descriptor:
- NOAEL
- Generation:
- F1
- Effect level:
- 616 mg/kg bw/day (nominal)
- Based on:
- test mat.
- Sex:
- not specified
- Basis for effect level:
- gross pathology
- other: overall no developmental toxic effects observed
- Remarks on result:
- other: overall no developmental toxic effects observed
- Critical effects observed:
- not specified
- System:
- other: not specified
- Organ:
- not specified
- Treatment related:
- not specified
- Dose response relationship:
- not specified
- Relevant for humans:
- not specified
- Reproductive effects observed:
- not specified
- Treatment related:
- not specified
- Relation to other toxic effects:
- not specified
- Dose response relationship:
- not specified
- Relevant for humans:
- not specified
- Conclusions:
- No Observed Adverse Effect Level (NOAEL) for reproductive and developmental toxicity was considered to be 616 mg/kg/day (7800ppm. When male and female CFE-S rats were treated with test material orally.
- Executive summary:
Reproductive and developmental toxicity study of test material was performed on male and female CFE-Srats .20 male and 20 female rats /dose group were used.One male was mated with one female until copulation was confirmed by the presence of sperm during daily vaginal inspections (day 0 of pregnancy).The females then were weighed, transferred into individual cages.The test materialmixed with feed were administers in dose concentration 0, 97.5,616 mg/kg bw/day (0, 1950,7800 ppm)from day from day 6 through day 15. Pregnancy was further confirmed by biweekly weighing of the females. All females were killed by chloroform inhalation on the 19th day of pregnancy and the fetuses delivered by Caesarian section. The number and distribution of fetuses, and the number of corpora lutea, live and stillboin fetuses, and early and late resorptions were recorded. Each fetus was weighed, measured, and examined for gross abnormalities. One-third of each litter was examined for visceral abnormalities by employing the slicing method of Wilson (1965). The remaining two-thirds were cleared and the bone structure stained with alizarin red S in order to define any skeletal abnormalities (Murphy, 1965)
No dose-related significant differences were observed in the parameters examined. The 616mg/kg /day (7800 ppm) dose group excreted blue-brown colour urine.No grossly abnormal pups were noted in the 97.5 mg/kg /day dose group (244 pups); there was one in control group (244 pups). One grossly abnormal pup was noted out of the 262 examined in the 616 mg/kg /day dose group.however, the average numbers of implantation sites, live pups, and early or late resorptions were not significantly different among the groups. HenceNo Observed Adverse Effect Level (NOAEL) for reproductive and developmental toxicity was considered to be 616 mg/kg/day (7800ppm.When male and femaleCFE-Srats were treated with test material orally.
- Endpoint:
- two-generation reproductive toxicity
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- data from handbook or collection of data
- Justification for type of information:
- Data from peer reviewed journal
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- other: As mentioned below
- Principles of method if other than guideline:
- Reproductive and developmental toxicity study of test material was performed on Sprague Dawley rats.
- GLP compliance:
- not specified
- Limit test:
- no
- Justification for study design:
- No data available
- Species:
- rat
- Strain:
- Sprague-Dawley
- Details on species / strain selection:
- No data available
- Sex:
- male/female
- Details on test animals or test system and environmental conditions:
- No data available
- Route of administration:
- dermal
- Vehicle:
- not specified
- Details on exposure:
- Details on exposure
The hair on the back of the rats (of both the treated and control groups) was clipped short to ensure maximum skin contact with the applied materials. The test materials, prepared fresh for each application by mixing equal volumes of the dye solution and 6% hydrogen peroxide, were topically applied to the shaved areas, (approximately 1 in. diameter) at a twice-weekly dose of 0.5 ml application. Successive applications were made to adjacent areas in order to minimize skin irritation. During the mating and lactation phase in the reproduction study, the dyes were allowed to dry on the skin before the rats were returned to their cages with their mates or offspring. - Details on mating procedure:
- - M/F ratio per cage:
- Length of cohabitation: 15 days
- Proof of pregnancy: [vaginal plug / sperm in vaginal smear] referred to as [day 0 / day 1] of pregnancy:The day on which sperm or the copulatory plug was found was termed day 0 of gestation
- After ... days of unsuccessful pairing replacement of first male by another male with proven fertility.
- Further matings after two unsuccessful attempts: [no / yes (explain)]
- After successful mating each pregnant female was caged (how):
- Any other deviations from standard protocol: - Analytical verification of doses or concentrations:
- not specified
- Duration of treatment / exposure:
- 100 days
- Frequency of treatment:
- daily
- Details on study schedule:
- No data available
- Remarks:
- 0 and 0.5 ml (0 and 0.001418 mg/kg )
- No. of animals per sex per dose:
- Total: 480
F0 geneartion:
Control- 1: 40 male, 40 female
Control- 2: 40 male, 40 female
Control- 3: 40 male, 40 female
0.001418 mg/kg : 40 male, 40 female
F1 geneartion
Control- 1: 20 male, 20 female
Control- 2: 20 male, 20 female
Control- 3: 20 male, 20 female
0.001418 mg/kg : 20 male, 20 female - Control animals:
- yes
- Details on study design:
- After the first (F1a) litters had been weaned the number of F0 parents was reduced from 40 to 20 in each group. After a 10-day rest period the remaining animals were re-mated to produce the F1b litters, following the same procedure as described for the reproduction of the F1a litters. After weaning, 60 male and 60 female F1a pups were selected from each group.The remaining F1a pups were killed. The F0 parents were killed once the F1b litters had been weaned. Twenty male and 20 female rats per group were selected from the F1b litters to become the F0 parents Of the next generation After 100 days these rats were mated, avoiding brother/sister pairing, to produce the F2a and F2b litters. After the F2b litters had been weaned, five male and five female F1 parents were necropsied .
- Positive control:
- No data available
- Parental animals: Observations and examinations:
- Parental animals observation and examinations
CAGE SIDE OBSERVATIONS: yes
DETAILED CLINICAL OBSERVATIONS: Yes
Time schedule:
BODY WEIGHT: Yes
Time schedule for examinations:
FOOD CONSUMPTION AND COMPOUND INTAKE (if feeding study):Yes
Food consumption for each animal determined and mean daily diet consumption calculated as g food/kg body weight/day: Yes
Compound intake calculated as time-weighted averages from the consumption and body weight gain data: Yes / No / No data: No data available
WATER CONSUMPTION AND COMPOUND INTAKE (if drinking water study): No data - Oestrous cyclicity (parental animals):
- No data available
- Sperm parameters (parental animals):
- No data available
- Litter observations:
- On day 21 of lactation the pups were counted, sexed, and weighed individually and observed for signs of pharmacological effects.
- Postmortem examinations (parental animals):
- SACRIFICE
- Male animals: All surviving animals [describe when, e.g. as soon as possible after the last litters in each generation were produced.]
- Maternal animals: All surviving animals [describe when, e.g. after the last litter of each generation was weaned.]
GROSS NECROPSY: yes
- Gross necropsy consisted of [external and internal examinations including the cervical, thoracic, and abdominal viscera.]
HISTOPATHOLOGY / ORGAN WEIGHTS: yes
The tissues indicated in Table [#] were prepared for microscopic examination and weighed, respectively. - Postmortem examinations (offspring):
- SACRIFICE
- The F1 offspring not selected as parental animals and all F2 offspring were sacrificed at [#?] days of age.
- These animals were subjected to postmortem examinations (macroscopic and/or microscopic examination) as follows:
GROSS NECROPSY: yes
- Gross necropsy consisted of [external and internal examinations including the cervical, thoracic, and abdominal viscera.]
HISTOPATHOLOGY / ORGAN WEIGTHS: yes
The tissues indicated in Table [#] were prepared for microscopic examination and weighed, respectively. - Statistics:
- In the reproduction study fertility, and foetal and postnatal survival were compared using the chi-square criterion with the Yates' corrections for 2 x 2 contingency tables and/or Fisher's exact probability test as described by Siegel (1956) to judge the significance of the differences. Foetal and postnatal survival were also compared using the Mann Whitney U test as described by Siegel (1956) and Weil (1970) to judge the significance of the differences. The mean number of live pups per litter and the mean litter weights at days 0, 4 and 14 in the reproduction study, body weights (at wk 13, 27, 40, 53, 66, 79, 92 and 105), and haematological and biochemical parameters (at months 3, 12, 18 and 24)in the toxicity-carcinogenicity study were compared by one-way analysis of variance, Bartlett's test for homogeneity of variances and the appropriate t test (for equal or unequal variances) as described by Steel & Torrie (1960) using Dunnett's multiple comparison tables (Dunnett, 1964) to judge the significance of the differences. The mean body weights of the pups at day 21 (of the reproduction study) were compared by analysis of variance (hierarchical classification) and a t test as described by Steel & Torrie (1960) using Dunnett's multiple comparison tables to judge the significance of the differences.
- Reproductive indices:
- No data available
- Offspring viability indices:
- offspring viability indices were observed
- Clinical signs:
- no effects observed
- Description (incidence and severity):
- The topical application of hair-dyeing formulations had no effect on the general health of any of the animals in any of the generations tested.
- Dermal irritation (if dermal study):
- effects observed, non-treatment-related
- Description (incidence and severity):
- the skin irritation seen in all of the treated groups which consisted of mild dermatitis seen intermittently throughout the treatment period in each generation No pharmacotoxicological signs were observed to be related to the application of the dyes.
- Mortality:
- no mortality observed
- Body weight and weight changes:
- no effects observed
- Description (incidence and severity):
- Body-weight gains was comparable among the test and control groups in each generation
- Food consumption and compound intake (if feeding study):
- no effects observed
- Description (incidence and severity):
- food consumption was comparable among the test and control groups in each generation
- Food efficiency:
- not specified
- Water consumption and compound intake (if drinking water study):
- not specified
- Ophthalmological findings:
- not specified
- Haematological findings:
- no effects observed
- Clinical biochemistry findings:
- not specified
- Urinalysis findings:
- no effects observed
- Behaviour (functional findings):
- not specified
- Immunological findings:
- not specified
- Organ weight findings including organ / body weight ratios:
- not specified
- Histopathological findings: non-neoplastic:
- not specified
- Histopathological findings: neoplastic:
- not specified
- Other effects:
- not specified
- Reproductive function: oestrous cycle:
- not specified
- Reproductive function: sperm measures:
- not specified
- Reproductive performance:
- no effects observed
- Description (incidence and severity):
- Fertility, gestation, survival and live birth indices and the mean numbers weaned and mean weaning weights for each litter in each generation were comparable among the test and control groups.
- Dose descriptor:
- NOAEL
- Effect level:
- 0.001 mg/kg bw/day (nominal)
- Based on:
- test mat.
- Sex:
- male/female
- Basis for effect level:
- clinical signs
- mortality
- body weight and weight gain
- food consumption and compound intake
- gross pathology
- reproductive performance
- Remarks on result:
- other: No effects on reproductive performance was observed
- Critical effects observed:
- not specified
- System:
- other: not specified
- Organ:
- not specified
- Treatment related:
- not specified
- Dose response relationship:
- not specified
- Relevant for humans:
- not specified
- Clinical signs:
- no effects observed
- Description (incidence and severity):
- The topical application of hair-dyeing formulations had no effect on the general health of any of the animals in any of the generations tested.
- Dermal irritation (if dermal study):
- effects observed, non-treatment-related
- Description (incidence and severity):
- the skin irritation seen in all of the treated groups which consisted of mild dermatitis seen intermittently throughout the treatment period in each generation No pharmacotoxicological signs were observed to be related to the application of the dyes.
- Mortality / viability:
- no mortality observed
- Description (incidence and severity):
- survival was comparable among the test and control groups in each generation
- Body weight and weight changes:
- no effects observed
- Description (incidence and severity):
- Body-weight gains was comparable among the test and control groups in each generation
- Food consumption and compound intake (if feeding study):
- no effects observed
- Description (incidence and severity):
- food consumption was comparable among the test and control groups in each generation
- Food efficiency:
- not specified
- Water consumption and compound intake (if drinking water study):
- not specified
- Ophthalmological findings:
- not specified
- Haematological findings:
- no effects observed
- Clinical biochemistry findings:
- not specified
- Urinalysis findings:
- no effects observed
- Sexual maturation:
- not specified
- Organ weight findings including organ / body weight ratios:
- not specified
- Gross pathological findings:
- not specified
- Histopathological findings:
- not specified
- Other effects:
- not specified
- Behaviour (functional findings):
- not specified
- Developmental immunotoxicity:
- not specified
- Dose descriptor:
- NOAEL
- Generation:
- F1
- Effect level:
- 0.001 mg/kg bw/day (nominal)
- Based on:
- test mat.
- Sex:
- not specified
- Basis for effect level:
- viability
- clinical signs
- mortality
- body weight and weight gain
- Remarks on result:
- other: No toxic effects were observed
- Critical effects observed:
- not specified
- System:
- other: not specified
- Organ:
- not specified
- Treatment related:
- not specified
- Dose response relationship:
- not specified
- Relevant for humans:
- not specified
- Clinical signs:
- no effects observed
- Description (incidence and severity):
- The topical application of hair-dyeing formulations had no effect on the general health of any of the animals in any of the generations tested
- Dermal irritation (if dermal study):
- no effects observed
- Description (incidence and severity):
- the skin irritation seen in all of the treated groups which consisted of mild dermatitis seen intermittently throughout the treatment period in each generation No pharmacotoxicological signs were observed to be related to the application of the dyes.
- Mortality / viability:
- no mortality observed
- Description (incidence and severity):
- survival was comparable among the test and control groups in each generation
- Body weight and weight changes:
- no effects observed
- Description (incidence and severity):
- Body-weight gains was comparable among the test and control groups in each generation
- Food consumption and compound intake (if feeding study):
- no effects observed
- Description (incidence and severity):
- food consumption were comparable among the test and control groups in each generation
- Food efficiency:
- not specified
- Water consumption and compound intake (if drinking water study):
- not specified
- Ophthalmological findings:
- not specified
- Haematological findings:
- not specified
- Clinical biochemistry findings:
- not specified
- Urinalysis findings:
- not specified
- Sexual maturation:
- not specified
- Organ weight findings including organ / body weight ratios:
- not specified
- Gross pathological findings:
- not specified
- Histopathological findings:
- not specified
- Other effects:
- not specified
- Behaviour (functional findings):
- not specified
- Developmental immunotoxicity:
- not specified
- Dose descriptor:
- NOAEL
- Generation:
- F2
- Effect level:
- 0.001 mg/kg bw/day (nominal)
- Based on:
- test mat.
- Sex:
- not specified
- Basis for effect level:
- viability
- clinical signs
- mortality
- body weight and weight gain
- Remarks on result:
- other: No toxic effects were observed
- Critical effects observed:
- not specified
- System:
- other: not specified
- Organ:
- not specified
- Treatment related:
- not specified
- Dose response relationship:
- not specified
- Relevant for humans:
- not specified
- Reproductive effects observed:
- not specified
- Treatment related:
- not specified
- Relation to other toxic effects:
- not specified
- Dose response relationship:
- not specified
- Relevant for humans:
- not specified
- Conclusions:
- NOAEL was considered to be 0.001418 mg/kg as the frequent topical application of test material does not appear to have an adverse effect on reproductive performance or on the health and survival of the developing foetus and postnatal animal. When male and female rats were treated with test material for two generation .
- Executive summary:
The two-generation reproductive and developmental toxicity study of test material was performed on male and female Sprague Dawley rats . The test material in dose concentration 0.001418 mg/kg was applied The hair on the back of the rats (of both the treated and control groups) was clipped short to ensure maximum skin contact with the applied materials. The test materials, prepared fresh for each application by mixing equal volumes of the dye solution and 6% hydrogen peroxide, were topically applied to the shaved areas, (approximately 1 in. diameter) at a twice-weekly dose of 0.05 ml application. Successive applications were made to adjacent areas in order to minimize skin irritation. During the mating and lactation phase in the reproduction study, the dyes were allowed to dry on the skin before the rats were returned to their cages with their mates or offspring. After the first (F1a) litters had been weaned the number of F0 parents was reduced from 40 to 20 in each group. After a 10-day rest period the remaining animals were re-mated to produce the F1b litters, following the same procedure as described for the reproduction of the F1a litters. After weaning, 60 male and 60 female F1a pups were selected from each group.The remaining F1a pups were killed. The F0 parents were killed once the F1b litters had been weaned. Twenty male and 20 female rats per group were selected from the F1b litters to become the F0 parents Of the next generationAfter 100 days these rats were mated, avoiding brother/sister pairing, to produce the F2a and F2b litters. After the F2b litters had been weaned, five male and five female F1 parents were necropsied .The topical application of hair-dyeing formulations had no effect on the general health of anyof the animals in any of the generations tested.Body-weight gains, food consumption and survivalwere comparable among the test and control groups in each generationthe skin irritation seen in all of thetreated groups which consisted of mild dermatitisseen intermittently throughout the treatment period in each generation No pharmacotoxicological signswere observed to be related to the application ofthe dyes. Fertility, gestation, survival and live birthindices and the mean numbers weaned and meanweaning weights for each litter in each generationwere comparable among the test and control groups. Hence NOAEL was considered to be 0.001418 mg/kg as the frequent topical application of test material does not appear to have an adverse effect on reproductive performance or on the health and survival of the developing foetus and postnatal animal. When male and female rats were treated with test material for two generation .
Referenceopen allclose all
Mean litter and reproduction data for the F1a litters of rats topically treated with hair-dyeing formulations
Group |
No. (%) ofpregnancies* |
Mean littersize (range)at birtht |
Gestation index‡ |
Weaningindex§ |
No. ofpupsborn dead |
Average no.weanedll |
Mean (range) weights (g)at weaning |
|
|
|
|
|
|
|
|
Male |
Female |
Control-1 |
28 (70) |
10.8 (5-16) |
98 |
100 |
6 |
9.1 |
49.9 (41-76) |
46.2 (35-72) |
Control-2 |
27 (89) |
11.1 (1-15) |
98 |
99 |
7 |
8.9 |
46.5 (27-61) |
44.5 (28-60) |
Control-3 |
31 (78) |
11.5 (6-17) |
98 |
99 |
8 |
9.3 |
48.1 (40-2) |
46.7 (37-61) |
7405 |
34 (85) |
12.2 (3-18) |
97 |
99 |
15 |
9.2 |
47.1 (37-80) |
47.8 (37-79) |
*The no. (%) of pregnant rats from 40 matings (or from 39 for control group 2).
ɫ Litter size was reduced to ten rats at day 4 if necessary.
‡Gestation index, no. of newborn pups alive/total no. born (%),
§Weaning index, no. of pups surviving to day 21/no. of pups retained at day 4 (%).
ll The average no. weaned is the total no. weaned at day 21/no. of litters born, including those in which all were born dead.
Mean litter and reproduction data for the F1b litters of rats topically treated with hair-dyeing formulations
Group |
No. (%) ofpregnancies* |
Mean littersize (range)at birtht |
Gestation index‡ |
Weaningindex§ |
No. ofpupsborn dead |
Average no.weanedll |
Mean (range) weights (g)at weaning |
|
|
|
|
|
|
|
|
Male |
Female |
Control-1 |
19 (95) |
11.1 (3-15) |
99 |
100 |
3 |
8.9 |
54.6 |
53.3 |
Control-2 |
13 (65) |
12.6 (7-19) |
99 |
100 |
2 |
9.3 |
55.6 |
55.9 |
Control-3 |
14 (70) |
13.5 (8-16) |
99 |
98 |
2 |
9.6 |
54.0 |
51.0 |
7405 |
14 (70) |
12.3 (5-18) |
93 |
100 |
13¶ |
8.9 |
52.0 |
50.7 |
*The no. (%) of pregnant rats from 20 matings.
ɫ Litter size was reduced to ten rats at day 4 if necessary.
‡ Gestation index, no. of newborn pups alive/total no. born (%).
§Weaning index, no. of pups surviving to day 21/no. of pups retained at day 4 (%).
ll The average no. weaned is the total no. weaned at day 21/no. of litters born, including those in which all were born dead.
¶One litter born with ten dead pups.
Mean litter and reproduction data for the F2, litters of rats topically treated with hair-dyeing formulations
Group |
No. (%) ofpregnancies* |
Mean littersize (range)at birtht |
Gestation index‡ |
Weaningindex§ |
No. ofpupsborn dead |
Average no.weanedll |
Mean (range) weights (g)at weaning |
|
|
|
|
|
|
|
|
Male |
Female |
Control-1 |
17 (85) |
11.6 (1-15) |
99 |
98 |
2 |
8.9 |
48.7 |
46.6 |
Control-2 |
18 (80) |
11.8 (2-18) |
98 |
99 |
4 |
9.2 |
48.8 |
45.8 |
Control-3 |
16 (84) |
12.8 (4-17) |
100 |
100 |
0 |
9.4 |
49.4 |
48.8 |
7405 |
16 (80) |
12.1 (9-16) |
96 |
100 |
8 |
9.3 |
49.5 |
47.6 |
*No (%) of pregnant rats from 20 matings (or from 19 for control group 3).
ɫLitter size was reduced to ten rats at day 4 if necessary.
‡Gestation index, no. of newborn pups alive/total no. born (%).
§Weaning index, no. of pups surviving to day 21/no. of pups retained at day 4 (%).
ll the average no. weaned is the total no. weaned at day 21/no. of litters born, including those in which all were born dead.
Mean litter and reproduction data for the F2b litters of rats topically treated with hair-dyeing formulations
Group |
No. (%) ofpregnancies* |
Mean littersize (range)at birtht |
Gestation index‡ |
Weaningindex§ |
No. ofpupsborn dead |
Average no.weanedll |
Mean (range) weights (g)at weaning |
|
|
|
|
|
|
|
|
Male |
Female |
Control-1 |
16 (80) |
12.6 (5-18) |
99 |
99 |
3 |
9.2 |
54.5 |
52.7 |
Control-2 |
14 (74)¶ |
1 12.7 (2-18) |
99 |
100 |
1 |
9.3 |
54.7 |
54.4 |
Control-3 |
14 (74)¶ |
12.6 (5-20) |
95 |
100 |
10 |
9.4 |
54.6 |
55.4 |
7405 |
15 (79)¶ |
10.8 (1-15) |
98 |
100 |
4 |
8.6 |
56.7 |
55.8 |
*No. (%) of pregnant rats from 20 matings (19¶) matings.
ɫ Litter size was reduced to ten rats at day 4 if necessary.
‡Gestation index, no. of newborn pups alive/total no. born (%).
§Weaning index, no. of pups surviving to day 21/no. of pups retained at day 4 (%).
ll the average no. weaned is the total no. weaned at day 21/no. of litters born, including those in which all were born dead.
Effect on fertility: via oral route
- Endpoint conclusion:
- no adverse effect observed
- Dose descriptor:
- NOAEL
- 616 mg/kg bw/day
- Study duration:
- subacute
- Species:
- rat
- Quality of whole database:
- Data is Klimicsh 2 and from authoritative database
Effect on fertility: via inhalation route
- Endpoint conclusion:
- no study available
Effect on fertility: via dermal route
- Endpoint conclusion:
- no adverse effect observed
- Dose descriptor:
- NOAEL
- 0.001 mg/kg bw/day
- Study duration:
- chronic
- Species:
- rat
- Quality of whole database:
- Data is Klimicsh 2 and from authoritative database
Additional information
Reproductive toxicity study
Data available from different studies were reviewed to determine the reproductive toxicity of test chemical.The studies are as mentioned below:
Study 1
Reproductive and developmental toxicity study of test material was performed on male and female CFE-Srats .20 male and 20 female rats /dose group were used.One male was mated with one female until copulation was confirmed by the presence of sperm during daily vaginal inspections (day 0 of pregnancy).The females then were weighed, transferred into individual cages.The test materialmixed with feed were administers in dose concentration 0, 97.5,616 mg/kg bw/day (0, 1950,7800 ppm)from day from day 6 through day 15. Pregnancy was further confirmed by biweekly weighing of the females. All females were killed by chloroform inhalation on the 19th day of pregnancy and the fetuses delivered by Caesarian section. The number and distribution of fetuses, and the number of corpora lutea, live and stillboin fetuses, and early and late resorptions were recorded. Each fetus was weighed, measured, and examined for gross abnormalities. One-third of each litter was examined for visceral abnormalities by employing the slicing method of Wilson (1965). The remaining two-thirds were cleared and the bone structure stained with alizarin red S in order to define any skeletal abnormalities (Murphy, 1965)
No dose-related significant differences were observed in the parameters examined. The 616mg/kg /day (7800 ppm) dose group excreted blue-brown colour urine.No grossly abnormal pups were noted in the 97.5 mg/kg /day dose group (244 pups); there was one in control group (244 pups). One grossly abnormal pup was noted out of the 262 examined in the 616 mg/kg /day dose group.however, the average numbers of implantation sites, live pups, and early or late resorptions were not significantly different among the groups. HenceNo Observed Adverse Effect Level (NOAEL) for reproductive and developmental toxicity was considered to be 616 mg/kg/day (7800ppm.When male and femaleCFE-Srats were treated with test material orally.
Study 2
In a Teratology study,New Zealand White female rabbits were treated with test material in the concentration of0, 19.5 and 97.5 mg/kg/day orally by gavage fromday 6 to day 18 of gestation. Bluebrown colored urine were observed in all treated rabbits. No adverse effect onbody weight gain, Number of pregnancies, numbers of corpora lutea, implantations, resorptions, and live and stillborn fetuses were observed in treated female rabbits. No effect on fetusesweight were observed in treated female rabbits. In addition, No gross abnormalities, visceral and skeletal abnormalities were observed in fetusesof treated female rabbits. Therefore, NOAEL was considered to be 97.5 mg/kg/day for F0 and F1 geneartion when New Zealand White female rabbits were treated with test material orally by gavage for 13 days.
Study 3
The two-generation reproductive and developmental toxicity study of test material was performed on male and female Sprague Dawley rats . The test material in dose concentration 0.001418 mg/kg was applied The hair on the back of the rats (of both the treated and control groups) was clipped short to ensure maximum skin contact with the applied materials. The test materials, prepared fresh for each application by mixing equal volumes of the dye solution and 6% hydrogen peroxide, were topically applied to the shaved areas, (approximately 1 in. diameter) at a twice-weekly dose of 0.05 ml application. Successive applications were made to adjacent areas in order to minimize skin irritation. During the mating and lactation phase in the reproduction study, the dyes were allowed to dry on the skin before the rats were returned to their cages with their mates or offspring. After the first (F1a) litters had been weaned the number of F0 parents was reduced from 40 to 20 in each group. After a 10-day rest period the remaining animals were re-mated to produce the F1b litters, following the same procedure as described for the reproduction of the F1a litters. After weaning, 60 male and 60 female F1a pups were selected from each group.The remaining F1a pups were killed. The F0 parents were killed once the F1b litters had been weaned. Twenty male and 20 female rats per group were selected from the F1b litters to become the F0 parents Of the next generationAfter 100 days these rats were mated, avoiding brother/sister pairing, to produce the F2a and F2b litters. After the F2b litters had been weaned, five male and five female F1 parents were necropsied .The topical application of hair-dyeing formulations had no effect on the general health of anyof the animals in any of the generations tested.Body-weight gains, food consumption and survivalwere comparable among the test and control groups in each generationthe skin irritation seen in all of thetreated groups which consisted of mild dermatitisseen intermittently throughout the treatment period in each generation No pharmacotoxicological signswere observed to be related to the application ofthe dyes. Fertility, gestation, survival and live birthindices and the mean numbers weaned and meanweaning weights for each litter in each generationwere comparable among the test and control groups. Hence NOAEL was considered to be 0.001418 mg/kg as the frequent topical application of test material does not appear to have an adverse effect on reproductive performance or on the health and survival of the developing foetus and postnatal animal. When male and female rats were treated with test material for two generation .
Study 4
In a Teratology study, pregnent female CD rats were treated wtih test material in the concentration of 0 and 0.001418 mg/kg dermally in6% hydrogen peroxide on days 1, 4, 7, 10, 13, 16, and 19 of gestation. Acetylsalicylic acid were used as positive control. Changes in the color of the skin and hair at the site of dye application were observed in treated rats. No irritation or other changes were observed in treated rats.No effect on body weight and food consumption of treated rats was observed as compared to control. Similarly,No significant effects on number of corpora lutea, implantation sites, live fetuses, sex ratio, resorption sites or mean resorptions per pregnancy of treated female rats wereobserved as compared to control. In addition, No effect on body weight offetuseswas observedas compared to control. No significant soft-tissue anomalies were observed infetuses of treated female rats as compared to control.Normally occurring accessory ribs variations wereobserved infetuses of treated female rats as compared to control. Therefore, NOAEL was considered to be 0.001416 mg/kg for F0 and F1 geneartion when pregnent female CD rats were treated wtih test material dermallyon days 1, 4, 7, 10, 13, 16, and 19 of gestation.
Based on the data available from different studies ,test material did not showedreproductive toxicityat dose concentration 616.0 mg/kg body weight/day,when male and female rats were treated with test material orally,Thus, comparing this value with the criteria ofCLP regulationtest materialis not likely to classify as reproductive toxicant.
eproductive toxicity study
Data available from different studies were reviewed to determine the reproductive toxicity of testchemical.The studies are as mentioned below:
Study 1
Reproductive and developmental toxicity study of test material was performed on male and female CFE-Srats .20 male and 20 female rats /dose group were used.One male was mated with one female until copulation was confirmed by the presence of sperm during daily vaginal inspections (day 0 of pregnancy).The females then were weighed, transferred into individual cages.The test materialmixed with feed were administers in dose concentration 0, 97.5,616 mg/kg bw/day (0, 1950,7800 ppm)from day from day 6 through day 15. Pregnancy was further confirmed by biweekly weighing of the females. All females were killed by chloroform inhalation on the 19th day of pregnancy and the fetuses delivered by Caesarian section. The number and distribution of fetuses, and the number of corpora lutea, live and stillboin fetuses, and early and late resorptions were recorded. Each fetus was weighed, measured, and examined for gross abnormalities. One-third of each litter was examined for visceral abnormalities by employing the slicing method of Wilson (1965). The remaining two-thirds were cleared and the bone structure stained with alizarin red S in order to define any skeletal abnormalities (Murphy, 1965)
No dose-related significant differences were observed in the parameters examined. The 616mg/kg /day (7800 ppm) dose group excreted blue-brown colour urine.No grossly abnormal pups were noted in the 97.5 mg/kg /day dose group (244 pups); there was one in control group (244 pups). One grossly abnormal pup was noted out of the 262 examined in the 616 mg/kg /day dose group.however, the average numbers of implantation sites, live pups, and early or late resorptions were not significantly different among the groups. HenceNo Observed Adverse Effect Level (NOAEL) for reproductive and developmental toxicity was considered to be 616 mg/kg/day (7800ppm.When male and femaleCFE-Srats were treated with test material orally.
Study 2
In a Teratology study,New Zealand White female rabbits were treated with test material in the concentration of0, 19.5 and 97.5 mg/kg/day orally by gavage fromday 6 to day 18 of gestation. Bluebrown colored urine were observed in all treated rabbits. No adverse effect onbody weight gain, Number of pregnancies, numbers of corpora lutea, implantations, resorptions, and live and stillborn fetuses were observed in treated female rabbits. No effect on fetusesweight were observed in treated female rabbits. In addition, No gross abnormalities, visceral and skeletal abnormalities were observed in fetusesof treated female rabbits. Therefore, NOAEL was considered to be 97.5 mg/kg/day for F0 and F1 geneartion when New Zealand White female rabbits were treated with test material orally by gavage for 13 days.
Study 3
The two-generation reproductive and developmental toxicity study of test material was performed on male and female Sprague Dawley rats . The test material in dose concentration 0.001418 mg/kg was applied The hair on the back of the rats (of both the treated and control groups) was clipped short to ensure maximum skin contact with the applied materials. The test materials, prepared fresh for each application by mixing equal volumes of the dye solution and 6% hydrogen peroxide, were topically applied to the shaved areas, (approximately 1 in. diameter) at a twice-weekly dose of 0.05 ml application. Successive applications were made to adjacent areas in order to minimize skin irritation. During the mating and lactation phase in the reproduction study, the dyes were allowed to dry on the skin before the rats were returned to their cages with their mates or offspring. After the first (F1a) litters had been weaned the number of F0 parents was reduced from 40 to 20 in each group. After a 10-day rest period the remaining animals were re-mated to produce the F1b litters, following the same procedure as described for the reproduction of the F1a litters. After weaning, 60 male and 60 female F1a pups were selected from each group.The remaining F1a pups were killed. The F0 parents were killed once the F1b litters had been weaned. Twenty male and 20 female rats per group were selected from the F1b litters to become the F0 parents Of the next generationAfter 100 days these rats were mated, avoiding brother/sister pairing, to produce the F2a and F2b litters. After the F2b litters had been weaned, five male and five female F1 parents were necropsied .The topical application of hair-dyeing formulations had no effect on the general health of anyof the animals in any of the generations tested.Body-weight gains, food consumption and survivalwere comparable among the test and control groups in each generationthe skin irritation seen in all of thetreated groups which consisted of mild dermatitisseen intermittently throughout the treatment period in each generation No pharmacotoxicological signswere observed to be related to the application ofthe dyes. Fertility, gestation, survival and live birthindices and the mean numbers weaned and meanweaning weights for each litter in each generationwere comparable among the test and control groups. Hence NOAEL was considered to be 0.001418 mg/kg as the frequent topical application of test material does not appear to have an adverse effect on reproductive performance or on the health and survival of the developing foetus and postnatal animal. When male and female rats were treated with test material for two generation .
Study 4
In a Teratology study, pregnent female CD rats were treated wtih test material in the concentration of 0 and 0.001418 mg/kg dermally in6% hydrogen peroxide on days 1, 4, 7, 10, 13, 16, and 19 of gestation. Acetylsalicylic acid were used as positive control. Changes in the color of the skin and hair at the site of dye application were observed in treated rats. No irritation or other changes were observed in treated rats.No effect on body weight and food consumption of treated rats was observed as compared to control. Similarly,No significant effects on number of corpora lutea, implantation sites, live fetuses, sex ratio, resorption sites or mean resorptions per pregnancy of treated female rats wereobserved as compared to control. In addition, No effect on body weight offetuseswas observedas compared to control. No significant soft-tissue anomalies were observed infetuses of treated female rats as compared to control.Normally occurring accessory ribs variations wereobserved infetuses of treated female rats as compared to control. Therefore, NOAEL was considered to be 0.001416 mg/kg for F0 and F1 geneartion when pregnent female CD rats were treated wtih test material dermallyon days 1, 4, 7, 10, 13, 16, and 19 of gestation.
Study 5
In a Reprodevelopmental toxicity study, CD male rats were treatre wtih test material l in the concentration of 0 and 20mg/kg intraperitoneally in sterile water3 times a week for 8 weeks. Male rats were treated and effect on female rats were observed.No effect on body weight gain of female rats was observed as compared to control.No effect on Implantation and resorption sites, dead and live fetuses and percentage of resorptions per litter of femalerats were observed as compared to control. Therefore, NOAEL was considered to be 20 mg/kg for F0 and F1 geneartion when male CD rats were treatre wtih test material for 8 weeks.
Based on the data available from different studies ,test material did not showedreproductive toxicityat dose concentration 616.0 mg/kg body weight/day,when male and female rats were treated with test material orally,Thus, comparing this value with the criteria ofCLP regulationtest materialis not likely to classify as reproductive toxicant.
Effects on developmental toxicity
Description of key information
Developmental toxicity study
Based on the various studies available for the test chemical were reviewed to determine the developmental toxicity, NOAELfor test chemical was considered to be 616.0 mg /kg bw/day .When rats were treated with test chemical orally. Thus, comparing this value with the criteria of CLP regulation test chemical is not likely to classify as reproductive and developmental toxicant.
Link to relevant study records
- Endpoint:
- developmental toxicity
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- data from handbook or collection of data
- Justification for type of information:
- Data from peer reviewed journal
- Qualifier:
- according to guideline
- Guideline:
- other: As mentioned below
- Principles of method if other than guideline:
- Developmental toxicity study of test material was performed on rabbits.
- GLP compliance:
- not specified
- Limit test:
- no
- Species:
- rabbit
- Strain:
- New Zealand White
- Details on test animals or test system and environmental conditions:
- No data available
- Route of administration:
- oral: gavage
- Type of inhalation exposure (if applicable):
- not specified
- Vehicle:
- other: 0.5 % aqueous methylcellulose
- Details on exposure:
- Details on exposure
PREPARATION OF DOSING SOLUTIONS:test material dissolved in 0.5 % aqueous methylcellulose
DIET PREPARATION
- Rate of preparation of diet (frequency):No data available
- Mixing appropriate amounts with (Type of food):No data available
- Storage temperature of food: No data available
VEHICLE
- Justification for use and choice of vehicle (if other than water): 0.5 % aqueous methylcellulose
- Concentration in vehicle:0, 19.5 and 97.5mg/kg/day)
- Amount of vehicle (if gavage):1 ml/kg.
- Lot/batch no. (if required): No data available
- Purity: No data available - Analytical verification of doses or concentrations:
- not specified
- Details on mating procedure:
- Female were artificially inseminated and day of insemination was designated day 0 of pregnancy.
- Duration of treatment / exposure:
- 13 days (on days 6 to 18 of gestation)
- Frequency of treatment:
- Daily
- Duration of test:
- 30 day
- Remarks:
- 0, 19.5 and 97.5mg/kg bw/day
- No. of animals per sex per dose:
- Total : 48
0 mg/kg bw/ day: 12 female
19.5 mg/kg bw/ day: 12 female
97.5 mg/kg bw/ day: 12 female
With omposite:
97.5 mg/kg bw/ day: 12 female - Control animals:
- not specified
- Details on study design:
- No data available
- Maternal examinations:
- CAGE SIDE OBSERVATIONS: Yes
- Time schedule:
- Cage side observations checked in table [No.?] were included.
DETAILED CLINICAL OBSERVATIONS: Yes / No / No data
- Time schedule:
BODY WEIGHT: Yes
- Time schedule for examinations:
FOOD CONSUMPTION AND COMPOUND INTAKE (if feeding study): Yes / No / No data
- Food consumption for each animal determined and mean daily diet consumption calculated as g food/kg body weight/day: Yes / No / No data
- Compound intake calculated as time-weighted averages from the consumption and body weight gain data: Yes / No / No data
WATER CONSUMPTION AND COMPOUND INTAKE (if drinking water study): Yes / No / No data
- Time schedule for examinations:
POST-MORTEM EXAMINATIONS: Yes / No / No data
- Sacrifice on gestation day #
- Organs examined:
OTHER: - Ovaries and uterine content:
- The ovaries and uterine content was examined after termination: Yes
Examinations included:
- Gravid uterus weight: No data
- Number of corpora lutea: Yes
- Number of implantations: Yes
- Number of early resorptions: Yes
- Number of late resorptions: Yes
- Other: - Fetal examinations:
- - External examinations: Yes: all per litter
- Soft tissue examinations: Yes
- Skeletal examinations: Yes
- Head examinations: No data - Statistics:
- Statistical analysis were performed by using the 95 % confidence level. The methods used included square test, analysis of variance and
t test, and the Fisher exact probability test (Snedecor, 1962). - Indices:
- No data available
- Historical control data:
- No data available
- Clinical signs:
- effects observed, treatment-related
- Description (incidence and severity):
- Bluebrown colored urine were observed in all treated rabbits.
- Dermal irritation (if dermal study):
- not specified
- Mortality:
- not specified
- Body weight and weight changes:
- no effects observed
- Description (incidence and severity):
- No adverse effect on body weight gain of treated rabbits were observed as compared to control.
- Food consumption and compound intake (if feeding study):
- not specified
- Food efficiency:
- not specified
- Water consumption and compound intake (if drinking water study):
- not specified
- Ophthalmological findings:
- not specified
- Haematological findings:
- not specified
- Clinical biochemistry findings:
- not specified
- Urinalysis findings:
- not specified
- Behaviour (functional findings):
- not specified
- Immunological findings:
- not specified
- Organ weight findings including organ / body weight ratios:
- not specified
- Gross pathological findings:
- not specified
- Neuropathological findings:
- not specified
- Histopathological findings: non-neoplastic:
- not specified
- Histopathological findings: neoplastic:
- not specified
- Other effects:
- not specified
- Number of abortions:
- not specified
- Pre- and post-implantation loss:
- no effects observed
- Total litter losses by resorption:
- no effects observed
- Early or late resorptions:
- no effects observed
- Dead fetuses:
- no effects observed
- Changes in pregnancy duration:
- not specified
- Description (incidence and severity):
- Migrated Data from removed field(s)
Field "Effects on pregnancy duration" (Path: ENDPOINT_STUDY_RECORD.DevelopmentalToxicityTeratogenicity.ResultsAndDiscussion.ResultsMaternalAnimals.MaternalDevelopmentalToxicity.EffectsOnPregnancyDuration): not specified - Changes in number of pregnant:
- no effects observed
- Description (incidence and severity):
- No adverse effect onNumber of pregnancies,
- Other effects:
- not specified
- Dose descriptor:
- NOAEL
- Effect level:
- 97.5 mg/kg bw/day (nominal)
- Based on:
- test mat.
- Basis for effect level:
- body weight and weight gain
- changes in number of pregnant
- clinical signs
- dead fetuses
- early or late resorptions
- pre and post implantation loss
- total litter losses by resorption
- Remarks on result:
- other: No effects on reproductive performance was observed
- Abnormalities:
- not specified
- Localisation:
- not specified
- Fetal body weight changes:
- no effects observed
- Description (incidence and severity):
- No effect on fetusesweight were observed in treated female rabbits.
Migrated Data from removed field(s)
Field "Fetal/pup body weight changes" (Path: ENDPOINT_STUDY_RECORD.DevelopmentalToxicityTeratogenicity.ResultsAndDiscussion.ResultsFetuses.FetalPupBodyWeightChanges): not specified - Reduction in number of live offspring:
- not specified
- Changes in sex ratio:
- not specified
- Changes in litter size and weights:
- not specified
- Changes in postnatal survival:
- not specified
- External malformations:
- no effects observed
- Skeletal malformations:
- no effects observed
- Visceral malformations:
- no effects observed
- Other effects:
- not specified
- Dose descriptor:
- NOAEL
- Effect level:
- 97.5 mg/kg bw/day
- Based on:
- test mat.
- Sex:
- not specified
- Basis for effect level:
- external malformations
- skeletal malformations
- visceral malformations
- Remarks on result:
- other: no developmental toxicity was observed
- Abnormalities:
- not specified
- Localisation:
- other: not specified
- Developmental effects observed:
- not specified
- Treatment related:
- not specified
- Relation to maternal toxicity:
- not specified
- Dose response relationship:
- not specified
- Relevant for humans:
- not specified
- Conclusions:
- NOAEL was considered to be 97.5 mg/kg/day for F0 and F1 geneartion when New Zealand Whitefemale rabbits were treated with test material orally.
- Executive summary:
In a Teratology study,New Zealand White female rabbits were treated with test material in the concentration of 0, 19.5 and 97.5 mg/kg/day orally by gavage fromday 6 to day 18 of gestation. Bluebrown colored urine were observed in all treated rabbits.
No adverse effect onbody weight gain, Number of pregnancies, numbers of corpora lutea, implantations, resorptions, and live and stillborn fetuses were observed in treated female rabbits. No effect on fetusesweight were observed in treated female rabbits. In addition, No gross abnormalities, visceral and skeletal abnormalities were observed in fetusesoftreated female rabbits. Therefore, NOAEL was considered to be 97.5 mg/kg/day for F0 and F1 geneartion when New Zealand White female rabbits were treated with test material orally by gavage for 13 days.
- Endpoint:
- developmental toxicity
- Type of information:
- experimental study
- Adequacy of study:
- supporting study
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- data from handbook or collection of data
- Justification for type of information:
- Data from peer reviewed journal
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- other: As mentioned below
- Principles of method if other than guideline:
- Teratology and percutaneous toxicity of test material was performed on rats
- GLP compliance:
- not specified
- Limit test:
- no
- Species:
- rat
- Strain:
- CD-1
- Details on test animals or test system and environmental conditions:
- No data available
- Route of administration:
- dermal
- Vehicle:
- other: 6% hydrogen peroxide
- Details on exposure:
- Details on exposure
PREPARATION OF DOSING SOLUTIONS: test material with ammoniacal soap base mixed with an equal volume of 6% hydrogen peroxide just prior to use.
DIET PREPARATION
- Rate of preparation of diet (frequency):No data available
- Mixing appropriate amounts with (Type of food):No data available
- Storage temperature of food: No data available
VEHICLE
- Justification for use and choice of vehicle (if other than water):No data available
- Concentration in vehicle:0 and 0.4 % (0 and 0.001418 mg/kg)
- Amount of vehicle (if gavage):1 ml/kg (1 ml day formulations which contine 0.4 % of test substance and 1 ml vehicle)
- Lot/batch no. (if required): No data available
- Purity: No data available - Analytical verification of doses or concentrations:
- not specified
- Details on mating procedure:
- Pregnant female rats were used.Presence of sperm in the vagina considered day 0 of gestation
- Duration of treatment / exposure:
- 7 days
- Frequency of treatment:
- Every 3 day (On days 1, 4, 7, 10, 13, 16, and 19 of gestation)
- Duration of test:
- 20 day
- Remarks:
- 0 and 0.4 % (0 and 0.001418 mg/kg)
- No. of animals per sex per dose:
- Total: 100
Control 1: 20 female
Control 1: 20 female
Control 1: 20 female
0.001418 mg/kg : 20 female
Positive Control : 20 female - Control animals:
- yes
- Details on study design:
- No data available
- Maternal examinations:
- Clinicl sign, body weight and food consumption were observed.
- Ovaries and uterine content:
- The ovaries and uterine content was examined after termination: Yes
Examinations included:
- Gravid uterus weight: Yes / No / No data
- Number of corpora lutea: Yes
- Number of implantations: Yes
- Number of early resorptions: Yes
- Number of late resorptions: Yes
- Other: - Fetal examinations:
- - External examinations: Yes: all per litter
- Soft tissue examinations: Yes
- Skeletal examinations: Yes
- Head examinations: No data - Statistics:
- The number of females exhibiting resorption sites, number of females exhibiting two or more resorptions, number of dead or resorbed fetuses, and the number of fetuses with soft-tissue or skeletal anomalies and accessory ribs was compared using chi-square test criterion with Yates' 2x2 contingency tables or Fisher's exact probability test.
The mean number of corpora lutea, implantation sites, live fetuses, and resorption sites was compared by analysis of variance (one-way classification) as described by Steel and Torrie using Dunnett's multiple comparison tables.
The live fetal weights were compared by analysis of variance as described by Steel and Torrie using Dunnett's multiple comparison tables.
Statistically significant differences between groups were judged valid only when there were significant differences between any one of the dye treated groups and each of the three untreated control groups. - Indices:
- No data available
- Historical control data:
- No data available
- Clinical signs:
- effects observed, treatment-related
- Description (incidence and severity):
- Changes in the color of the skin and hair at the site of dye application were observed in treated rats.
- Dermal irritation (if dermal study):
- no effects observed
- Description (incidence and severity):
- No irritation or other changes were observed in treated rats.
- Mortality:
- not specified
- Body weight and weight changes:
- no effects observed
- Description (incidence and severity):
- No effect on body weight of treated rats was observed as compared to control.
- Food consumption and compound intake (if feeding study):
- no effects observed
- Description (incidence and severity):
- No effect on food consumption of treated rats was observed as compared to control
- Food efficiency:
- not specified
- Water consumption and compound intake (if drinking water study):
- not specified
- Ophthalmological findings:
- not specified
- Haematological findings:
- not specified
- Clinical biochemistry findings:
- not specified
- Urinalysis findings:
- not specified
- Behaviour (functional findings):
- not specified
- Immunological findings:
- not specified
- Organ weight findings including organ / body weight ratios:
- not specified
- Gross pathological findings:
- not specified
- Neuropathological findings:
- not specified
- Histopathological findings: non-neoplastic:
- not specified
- Histopathological findings: neoplastic:
- not specified
- Other effects:
- not specified
- Number of abortions:
- not specified
- Pre- and post-implantation loss:
- no effects observed
- Total litter losses by resorption:
- no effects observed
- Early or late resorptions:
- no effects observed
- Dead fetuses:
- not specified
- Changes in pregnancy duration:
- not specified
- Description (incidence and severity):
- Migrated Data from removed field(s)
Field "Effects on pregnancy duration" (Path: ENDPOINT_STUDY_RECORD.DevelopmentalToxicityTeratogenicity.ResultsAndDiscussion.ResultsMaternalAnimals.MaternalDevelopmentalToxicity.EffectsOnPregnancyDuration): not specified - Changes in number of pregnant:
- not specified
- Other effects:
- not specified
- Details on maternal toxic effects:
- No significant effect on number of corpora lutea and implantation sites oftreated rats was observed as compared to control.No significant effect on live fetuses, sex ratio, resorption sites or mean resorptions per pregnancy oftreated rats was observed as compared to control.
- Dose descriptor:
- NOAEL
- Effect level:
- 0.001 mg/kg bw/day (nominal)
- Based on:
- test mat.
- Basis for effect level:
- body weight and weight gain
- clinical signs
- early or late resorptions
- food consumption and compound intake
- pre and post implantation loss
- total litter losses by resorption
- Remarks on result:
- other: No effects on reproductive performance was observed
- Abnormalities:
- not specified
- Localisation:
- not specified
- Fetal body weight changes:
- no effects observed
- Description (incidence and severity):
- No effect on body weight of fetuses was observed in treated female rats as compared to control.
Migrated Data from removed field(s)
Field "Fetal/pup body weight changes" (Path: ENDPOINT_STUDY_RECORD.DevelopmentalToxicityTeratogenicity.ResultsAndDiscussion.ResultsFetuses.FetalPupBodyWeightChanges): not specified - Reduction in number of live offspring:
- no effects observed
- Description (incidence and severity):
- No effect on Live fetuses was observed in treated female rats as compared to control
- Changes in sex ratio:
- no effects observed
- Changes in litter size and weights:
- not specified
- Changes in postnatal survival:
- not specified
- External malformations:
- no effects observed
- Skeletal malformations:
- no effects observed
- Visceral malformations:
- no effects observed
- Description (incidence and severity):
- No significant soft-tissue anomalies were observed infetuses of treated female rats as compared to control.
- Other effects:
- not specified
- Dose descriptor:
- NOAEL
- Effect level:
- 0.001 mg/kg bw/day (nominal)
- Based on:
- test mat.
- Sex:
- not specified
- Basis for effect level:
- reduction in number of live offspring
- changes in sex ratio
- fetal/pup body weight changes
- external malformations
- skeletal malformations
- visceral malformations
- Remarks on result:
- other: No effects on developmental parameters was observed
- Abnormalities:
- not specified
- Localisation:
- other: not specified
- Developmental effects observed:
- not specified
- Treatment related:
- not specified
- Relation to maternal toxicity:
- not specified
- Dose response relationship:
- not specified
- Relevant for humans:
- not specified
- Conclusions:
- NOAEL was considered to be 0.001418 mg/kg for F0 and F1 geneartion when pregnent female CD rats were treated wtih test material .
- Executive summary:
In a Teratology study, pregnent female CD rats were treated wtih test material in the concentration of 0 and 0.001418 mg/kg dermally in6% hydrogen peroxide on days 1, 4, 7, 10, 13, 16, and 19 of gestation. Acetylsalicylic acid were used as positive control. Changes in the color of the skin and hair at the site of dye application were observed in treated rats. No irritation or other changes were observed in treated rats.No effects on body weight and food consumption of treated rats were observed as compared to control. Similarly,No significant effects on number of corpora lutea, implantation sites, live fetuses, sex ratio, resorption sites or mean resorptions per pregnancy of treated female rats wereobserved as compared to control. In addition, No effect on body weight offetuseswas observedas compared to control. No significant soft-tissue anomalies were observed infetuses of treated female rats were observed as compared to control. Normally occurring accessory ribs variations wereobserved infetuses of treated female rats as compared to control. Therefore, NOAEL was considered to be 0.001416 mg/kg for F0 and F1 geneartion when pregnent female CD rats were treated wtih test material dermally on days 1, 4, 7, 10, 13, 16, and 19 of gestation.
Referenceopen allclose all
Summary of Teratology Study in Rats Receiving 7405
Observations |
Control I Untreated |
Control II Untreated |
Control III Untreated |
Acetylsalicylic acid (250 mg/kg-day) |
7405 (2 ml/kg) |
Maternal parameters |
|
|
|
|
|
Total no. females |
20 |
20 |
20 |
20 |
20 |
Mean no. corpora lutea |
15.35 |
13.55 |
15.25 |
16.15d |
15.55 |
Mean no. implantation sites |
12.40 |
12.10c |
13.90 |
13.25 |
14.30a,b |
No. females exhibiting resorption Sites |
13 |
14 |
12 |
15 |
11 |
No. females exhibiting 2 or more resorption sites |
9 |
7 |
6 |
15d |
7 |
No. females aborting |
0 |
0 |
0 |
0 |
0 |
Fetal parameters |
|
|
|
|
|
Mean no. live fetuses/group |
10.65 |
10.85 |
12.50 |
8.70c |
12.95 |
Mean live fetal weight (g) |
3.38 |
3.58 |
3.62 |
2.89e |
3.799 |
No. dead or resorbed fetuses (%) |
35(14.11) |
25(10.33) |
28 (10.07) |
91 (34.34)e |
27 (9.44) |
Mean no. resorptions/pregnancy |
1.75 |
1.25 |
1.40 |
4.5 5h,i |
1.35 |
Sex ratio, M:F |
106:107 |
102:115 |
119:131 |
100:75 |
117:142 |
No. fetuses with soft-tissue anomalies (%) |
4(6.35) |
4(6.06) |
6(7.79) |
21 (36.84)e |
4 (5.00) |
No. fetuses with skeletal anomalies (%) |
0(0.00) |
1 (0.67) |
2(1.16) |
40(34.19)e |
1 (0.56) |
No. fetuses with accessory ribs only (%) |
75 (50.00) |
56(37.09) |
72 (41.62) |
32 (27.35) |
72 (40.22) |
aSignificantly different from control II at p < 0.05.
bSignificantly different from control III at p < 0.05.
cSignificantly different from control III at p < 0.01.
dSignificantly different from controls II, III atp < 0.05.
eSignificantly different from controls I, I I , III atp < 0.01.
fSignificantly different from control I at p < 0.01.
gSignificantly different from control I atp < 0.05.
^Significantly different from control II atp <0.01.
'Significantly different from controls I, III atp < 0.05.
Effect on developmental toxicity: via oral route
- Endpoint conclusion:
- no adverse effect observed
- Dose descriptor:
- NOAEL
- 616 mg/kg bw/day
- Study duration:
- subacute
- Species:
- rat
- Quality of whole database:
- Data is Klimicsh 2 and from authoritative database
Effect on developmental toxicity: via inhalation route
- Endpoint conclusion:
- no study available
Effect on developmental toxicity: via dermal route
- Endpoint conclusion:
- no adverse effect observed
- Dose descriptor:
- NOAEL
- 0.001 mg/kg bw/day
- Study duration:
- chronic
- Species:
- rat
- Quality of whole database:
- Data is Klimicsh 2 and from authoritative database
Additional information
Developmental toxicity study
Data available from different studies for test chemicals were reviewed to determine the developmental toxicity of test chemical. The studies are as mentioned below:
Study 1
In a Teratology study,New Zealand White female rabbits were treated with test materialin the concentration of0, 19.5 and 97.5 mg/kg/day orally by gavage fromday 6 to day 18 of gestation. Bluebrown colored urine were observed in all treated rabbits.
No adverse effect onbody weight gain, Number of pregnancies, numbers of corpora lutea, implantations, resorptions, and live and stillborn fetuses were observed in treated female rabbits. No effect on fetusesweight were observed in treated female rabbits. In addition, No gross abnormalities, visceral and skeletal abnormalities were observed in fetusesoftreated female rabbits. Therefore, NOAEL was considered to be 97.5 mg/kg/day for F0 and F1 geneartion when New Zealand White female rabbits were treated with test materialorally by gavage for 13 days.
Study 2
In a Teratology study,CFE-S female rats were treated with test material in the concentration of 0, 195 and 616 mg/kg/day orally in diet fromday 6 to day 15 of gestation. No adverse effect onaverage number of implantation sites, live pups or in the number of females with one or more resorption sites were observed in treated female rats. No effect on fetuses weight were observed in treated female rats. In addition, No were gross abnormalities, visceral and skeletal abnormalities were observed in fetusesoftreated female rats. Therefore, NOAEL was considered to be 616mg/kg/day for F0 and F1 geneartion when CFE-S female rats were treated with test material orally in diet for 10 days.
Study 3
In a Teratology study, pregnent female CD rats were treated wtih test materialin the concentration of 0 and 0.001418 mg/kg dermally in6% hydrogen peroxide on days 1, 4, 7, 10, 13, 16, and 19 of gestation. Acetylsalicylic acid were used as positive control. Changes in the color of the skin and hair at the site of dye application were observed in treated rats. No irritation or other changes were observed in treated rats.No effects on body weight and food consumption of treated rats were observed as compared to control. Similarly,No significant effects on number of corpora lutea, implantation sites, live fetuses, sex ratio, resorption sites or mean resorptions per pregnancy of treated female rats wereobserved as compared to control. In addition, No effect on body weight offetuseswas observedas compared to control. No significant soft-tissue anomalies were observed infetuses of treated female rats were observed as compared to control. Normally occurring accessory ribs variations wereobserved infetuses of treated female rats as compared to control. Therefore, NOAEL was considered to be 0.001416 mg/kg for F0 and F1 geneartion when pregnent female CD rats were treated wtih test materialdermallyon days 1, 4, 7, 10, 13, 16, and 19 of gestation.
Thus, based on the data available fortest chemical,No Observed Adverse Effect Level (NOAEL) was considered to be 616mg /kg bw .When rats were treated with test chemical orally. Thus, comparing this value with the criteria of CLP regulationtest chemical is not likely to classify as reproductive and developmental toxicant.
Justification for classification or non-classification
Thus, comparing this value with the criteria of CLP regulation test chemical is not likely to classify as reproductive and developmental toxicant.
Additional information
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