Registration Dossier

Administrative data

First-aid measures

In case of inhalation
- Move to fresh air.
- Keep warm and in a quiet place.
- Oxygen or artificial respiration if needed.
- Call a physician immediately.
In case of skin contact
- Wash off with soap and water.
In case of eye contact
- Keep eyelids open to allow evaporation of product.
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- If eye irritation persists, consult a specialist.
In case of ingestion
- Drink 1 or 2 glasses of water.
- Do NOT induce vomiting.
- Consult a physician.
Most important symptoms and effects, both acute and delayed
In case of inhalation
Symptoms
- Dizziness
- Asphyxia
- narcosis
In case of skin contact
Symptoms
- Redness
In case of eye contact
Symptoms
- Redness
In case of ingestion
Symptoms
- Abdominal pain
- Nausea
- Vomiting
Indication of any immediate medical attention and special treatment needed
Notes to physician
- None

Fire-fighting measures

Extinguishing media
Suitable extinguishing media
- Water
- powder
- Foam
- Dry chemical
- Carbon dioxide (CO2)
Unsuitable extinguishing media
- None
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Special hazards arising from the substance or mixture
- Flammable liquid and vapour.
- The pressure in sealed containers can increase under the influence of heat.
- Explosive reaction may occur on heating or burning.
- In case of fire hazardous decomposition products may be produced such as: Gaseous hydrogen fluoride (HF), Fluorophosgene
- Gaseous hydrogen chloride (HCl).
Advice for firefighters
Special protective equipment for firefighters
- Wear self-contained breathing apparatus and protective suit.
- When intervention in close proximity wear acid resistant over suit.
Further information
Evacuate personnel to safe areas.
Approach from upwind.
- Protect intervention team with a water spray as they approach the fire.
- Keep containers and surroundings cool with water spray.
--- D R A F T ---

SAFETY DATA SHEET

DICHLORO VINYL ETHER

Revision Date 11.04.2018

P00000027499
Version : . / GB ( EN )
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5.2 Special hazards arising from the substance or mixture
- Flammable liquid and vapour.
- The pressure in sealed containers can increase under the influence of heat.
- Explosive reaction may occur on heating or burning.
- In case of fire hazardous decomposition products may be produced such as: Gaseous hydrogen fluoride (HF),
Fluorophosgene
- Gaseous hydrogen chloride (HCl).
5.3 Advice for firefighters
Special protective equipment for firefighters
- Wear self-contained breathing apparatus and protective suit.
- When intervention in close proximity wear acid resistant over suit.
Further information
- Evacuate personnel to safe areas.
- Approach from upwind.
- Protect intervention team with a water spray as they approach the fire.
- Keep containers and surroundings cool with water spray.
- Keep product and empty container away from heat and sources of ignition.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel
- Prevent further leakage or spillage if safe to do so.
Advice for emergency responders
- The product evaporates readily.
- Ensure adequate ventilation.
- Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing.
- Keep away from open flames, hot surfaces and sources of ignition.
Environmental precautions
- Should not be released into the environment.
- Do not flush into surface water or sanitary sewer system.
Methods and materials for containment and cleaning up
- Suppress (knock down) gases/vapours/mists with a water spray jet.
- Soak up with inert absorbent material.
- Suitable material for picking up.
- Earth
- Dry sand
- Shovel into suitable container for disposal.
Reference to other sections
- Refer to protective measures listed in sections 7 and 8.

Handling and storage

Precautions for safe handling
- Ensure adequate ventilation.
- Use personal protective equipment.
- Keep away from heat and sources of ignition.
-To avoid thermal decomposition, do not overheat.
-Ground/bond container and receiving equipment.
-Ensure all equipment is electrically grounded before beginning transfer operations.
-Use explosion-proof electrical/ ventilating/ lighting equipment.
-Use only non-sparking tools.
-Take precautionary measures against static discharge.
-Clean and dry piping circuits and equipment before any operations.
Hygiene measures
-Ensure that eyewash stations and safety showers are close to the workstation location.
-When using do not eat, drink or smoke.
-Wash hands before breaks and at the end of workday.
-Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
Technical measures/Storage conditions
-Keep in properly labelled containers.
- Keep in container fitted with safety valve or vent.
- Vapours are heavier than air and may spread along floors.
- Keep away from heat and sources of ignition.
- Keep away from direct sunlight.
- Store in a well-ventilated place. Keep cool.
- Keep away from combustible material.- K
-Keep away from incompatible products
-Provide tight electrical equipment well protected against corrosion.
-Refer to protective measures listed in sections 7 and 8.
Packaging material
Suitable material
-Metals
Specific end use(s)
-Contact your supplier for additional information

Transport information

Land transport (ADR/RID)

UN number:
UN 1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S. (Ethene,1,2-dichloro-1-fluoro-2-(trifluoromethoxy)-)
Class:
3
Classification code:
F1
Packaging group:
III
Labels:
3
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S. (Ethene,1,2-dichloro-1-fluoro-2-(trifluoromethoxy)-)
Class:
3
Classification code:
F1
Packaging group:
III
Labels:
3
Remarks
Special precautions for user
Hazard Identification Number: 30

Marine transport (IMDG)

UN number:
UN 1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S. (Ethene,1,2-dichloro-1-fluoro-2-(trifluoromethoxy)-)
Class:
3
Packaging group:
III
EmS code:
F-E , S-E
Labels:
3
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S. (Ethene,1,2-dichloro-1-fluoro-2-(trifluoromethoxy)-)
Class:
3
Packaging group:
III
Labels:
3
Remarks
Special precautions for user
Packing instruction (cargo aircraft) 366
Max net qty/pkg 220.00 L
Packing instruction (passenger aircraft) 355
Max net qty/pkg 60.00 L
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Control measures
Engineering measures
- Ensure adequate ventilation.
- Refer to protective measures listed in sections 7 and 8.
- Apply technical measures to comply with the occupational exposure limits.
Individual protection measures
Respiratory protection
- In case of decomposition (see section 10), use an air breathing apparatus with face mask.
- Use only respiratory protection that conforms to international/ national standards.
Hand protection
- Wear protective gloves.
Suitable material
- Neoprene gloves
- Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
Eye protection
- Tightly fitting safety goggles
Skin and body protection
- Wear work overall and safety shoes.
Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls
- Dispose of rinse water in accordance with local and national regulations.

Stability and reactivity

Reactivity
- No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
-Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
-No dangerous reaction known under conditions of normal use.
10.4 Conditions to avoid
-To avoid thermal decomposition, do not overheat.
-Keep away from flames and sparks.
10.5 Incompatible materials
-Alcohol
-Amines
10.6 Hazardous decomposition products
-Gaseous hydrogen fluoride (HF).
-Fluorophosgene
-Gaseous hydrogen chloride (HCl).

Disposal considerations

Waste treatment methods
Product Disposal
- Can be incinerated, when in compliance with local regulations.
- The incinerator must be equipped with a system for the neutralisation or recovery of HF.
- Dispose of in accordance with local regulations.
Advice on cleaning and disposal of packaging
- Purge the container with nitrogen and direct the gas to a treatment plant.
- Empty containers can be landfilled, when in accordance with the local regulations.