Registration Dossier

Administrative data

First-aid measures

General information:
Seek medical assistance if discomfort continues
After inhalation:
Remove the casualty into fresh air and keep him calm.
After contact with skin:
In case of contact with skin, clean with soap and water.
After contact with eyes:
Rinse the affected eye with plenty of water, at the same time keep the unaffected eye well
protected.
After ingestion:
If swallowed do not induce vomiting,seek medical advice and show safety datasheet or label
Symptoms
No symptoms known currently.
Hazards
No hazards known at this time.

Fire-fighting measures

Suitable extinguishing media:
water spray jet
foam
Extinguishing media that must not be used for safety reasons:
Full water jet
carbon dioxide
dry powder
Special hazards arising from the substance or mixture
In the event of fire the following can be released:
Carbon monoxide (CO)
Carbon dioxide (CO2)
Nitrous gases (NOx)
Advice for firefighters.
Special protective equipment for firefighting
Use self-contained breathing apparatus
Firefighting water may not spill into open rivers and ponds

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Wear suitable personal protective equipment.
Environmental precautions:
Do not allow entry to drains, water courses or soil
Methods and material for containment and cleaning up:
Take up mechanically
Avoid dust formation and electrical charging (sparking) because dust explosion might occur.
When picked up, treat material as prescribed under heading "Disposal considerations".

Handling and storage

Advice on safe handling:
When used and handled appropriately no special measures are needed
Avoid dust formation.
Advice on protection against fire and explosion:
Take precautionary measures against electrostatic charges - earthing necessary during
loading operations.
Keep away from sources of ignition
Dust can form an explosive mixture with air.
Conditions for safe storage, including any incompatibilities:
Keep container tightly closed in a cool, well-ventilated place, open and handle carefully. Keep away from sources of ignition.

Transport information

Land transport (ADR/RID)

UN number:
3077
Shippingopen allclose all
Class:
Class 9
Packaging group:
PG III
Labels:
9
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3077
Shippingopen allclose all
Class:
9
Packaging group:
PG III
Labels:
9
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3077
Proper shipping name and description:
3077 Environmentally hazardous substance, solid, n.o.s. (9-ethylcarbazole)
Class:
9
Packaging group:
PG III
Labels:
9
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3077
Proper shipping name and description:
3077 Environmentally hazardous substance, solid, n.o.s. (9-ethylcarbazole)
Class:
9
Packaging group:
PG III
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Exposure limit values
Exposure limit values are not available.
Exposure controls
General protective measures
Observe the usual precautions for handling chemicals.
Hygiene measures
Wash hands before breaks and after work.
Use barrier skin cream.
Remove soiled or soaked clothing immediately and clean thoroughly before using again.
Respiratory protection : Wear dust mask when handling large quantities
Hand protection : Nitrile rubber gloves.
Minimum breakthrough time (glove): not determined
Minimum thickness (glove): not determined
Observe the information of the glove manufacturers on
permeability and breakthrough times and other workplace
requirements
Eye protection: safety glasses
Body protection : working clothes

Stability and reactivity

Chemical stability
Stable.
Possibility of hazardous reactions
When handled and stored appropriately no dangerous reactions are known
Incompatible materials
not known
Hazardous decomposition products
When handled and stored appropriately, no dangerous decomposition products are known

Disposal considerations

Waste treatment methods
Product
Product should be be taken to a suitable and authorized waste disposal site in
accordance with relevant regulations and if necessary after consultation with the waste
disposal operator and/or the competent Authorities
Uncleaned packaging
Packaging that cannot be cleaned should be disposed of as product waste