Registration Dossier

Diss Factsheets

Administrative data

Endpoint:
melting point/freezing point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
1991-01-23
Reliability:
1 (reliable without restriction)

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
1991
Report date:
1991

Materials and methods

Test guideline
Qualifier:
no guideline followed
Principles of method if other than guideline:
n-Hexyllithium is filled into a Schlenk tube which incorporates a thermic element. The sample preparation was done under inert gas. The sample was cooled down to -62°C in a cold bath with dry ice and toluene for two hours.
GLP compliance:
not specified

Test material

Constituent 1
Chemical structure
Reference substance name:
N-hexyllithium
EC Number:
404-950-0
EC Name:
N-hexyllithium
Cas Number:
21369-64-2
Molecular formula:
n-C6H13Li
IUPAC Name:
lithium(1+) hexan-1-ide

Results and discussion

Melting / freezing point
Melting / freezing pt.:
< -62 °C
Atm. press.:
1 013 hPa
Decomposition:
no

Applicant's summary and conclusion

Conclusions:
The melting point could not be determined as n-hexyl lithium is a liquid at room temperature and atmospheric pressure. The freezing point is below -62 °C.
Executive summary:

The melting point could not be determined as n-hexyl lithium is a liquid at room temperature and atmospheric pressure. The freezing point is below -62 °C.

According to column 2 of REACH Regulation (EC) No. 1272/2006 the study does not need to be conducted below a lower temperature limit of -20 °C.