Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Inhalation: keep patient at rest and maintain body temperature. Remove the victim to a ventilated area. Get medical attention. Give symptomatic and supportive treatment, if required.

Skin contact: after contact with skin, remove contaminated clothing and wash immediately with plenty of water and soap. If irritation develops, seek medical attention.

Eye contact: immediately wash affected eyes for at least 15 minutes, taking care to rinse under eyelids. Consut an eye specialist.

Ingestion: Rise mouth with water. Get medical attention and show the label or packaging. Do not induce vomiting. If vomit occurs, keep victim's head below hips to prevent aspiration.

Most important symptoms and effects, both acute and delayed:
skin contact: not irritating.
eye contact: risk of serious damage to eyes.

Indication of any immediate medical attention and special treatment needed:
all treatments should be based on observed signs and symptoms.

Fire-fighting measures

Extinguishing media:
avoid contact with product. Use safety gloves, goggles, rubber footwar, face mask and anti-acid suit. Unsuitable extinguishing media: direct water spurt (water jet).

Special hazards arising from the substance or mixture.
Possibility of exposure to toxic combustion products.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Advice for fire-fighters:
special protective equipment for fire-fighters: In the event of fire, wear self-contained breathing apparatus and personal protective equipment.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Isolate and delimit the affected area.
Avoid contact with the product. Use safety gloves, goggles, rubber footwear, face mask and anti-acid suit.
Use personal protective equipment and respiratory protection.
Eliminate all sources of ignition.
Evacuate personnel to safe areas.
Ensure adequate ventilation.

Environmental precautions

Prevent the product reaches the sewer.
Prevent soil contamination.


Methods and material for containment and cleaning up

Prevent further leakage or spillage if safe to do so.
Clean up with absorbent materials (eg. soil, sand, diatomaceous earth or any non-flammable absorbent).
To dilute the remains that stay of the products with three water parts for one of product and later to neutralize it with sodium bicarbonate or carbonate. Do not try to neutralize it before it has not been diluted.
Store collected material in adequate containers for disposal. Label these containers and manage in accordance with local regulations.
Do not mix with other waste materials.
If there are spills or uncontrolled discharges on surface waters (or water for public use), immediately inform the local authorities.

Handling and storage

Precautions for safe handling

Use personal protective equipment (PPE). Avoid contact with skin, eyes and clothing.
Ensure adequate ventilation.
Do not handle the product near a source of ignition or near open flame.
Do not smoke, drink or eat while handling the product.
Wash hands with soap after handling and before eating, drinking, smoking or using the toilet.
Remove clothing immediately if the product is inside. Wash skin thoroughly with mild soap and dress clean clothes.

Conditions for safe storage, including any incompatibilities

Do not store near or with any of the incompatible materials listed in Section 10.
Do not store with food, beverages, feed and water supplies.
Do not store near flame, heat sources or near strong oxidizing agents.
Avoid extreme temperatures.
Store the product in the original container.
Keep tightly closed containers in a dry, cool and well ventilated sheltered from the sun.
Keep out of reach of unauthorized persons, children and animals.

Transport information

Land transport (ADR/RID)

UN number:
1760
Shippingopen allclose all
Class:
8
Classification code:
C9
Packaging group:
III
Labels:
8
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
1760
Shippingopen allclose all
Class:
8
Classification code:
C9
Packaging group:
III
Labels:
8
Remarksopen allclose all

Marine transport (IMDG)

UN number:
1760
Class:
8
Packaging group:
III
Labels:
8
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
1760
Class:
8
Packaging group:
III
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Control parameters

No national occupational exposure limit values have been established.
Derived No Effect Level (DNEL):

DNELs for workers: 3.059 mg/kg bw/day (dermal exposure)
2.697 mg/m³ (inhalation)

DNELs for general population: 1.53 mg/kg bw/day (dermal exposure)
0.665 mg/m³ (inhalation)
1.53 mg/kg bw/day (oral exposure)

Predicted No Effect Concentration (PNEC):

PNEC aqua: Aquatic toxicity unlikely.

PNEC sediment: No exposure of sediment expected.

PNEC soil: No exposure of soil expected.

PNEC sewage treatment plant: 92 mg/L.

PNEC oral (secondary poisoning): No potential for bioaccumulation.

Exposure controls

Proper technical controls

Ensure adequate ventilation and/or exhaust ventilation.

Individual protective measures

Respiratory protection: If the ventilation is not suitable, use a gas mask with the cassettes and chemical appropriate filters or equipment of air supply.
Hand protection: Use anti-acid /chemical resistant impervious gloves.
Eye protection: Wear safety glasses or facial protection screen.
Skin and body protection: Use gloves, boot and anti-acid/ chemical resistant suit.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Have eye wash bottle with distilled water. Remove and wash contaminated clothing before reuse. Wash hands before breaks and immediately after handling.

Environmental exposure controls

Do not flush into surface waters or sanitary drain systems.

Stability and reactivity

Reactivity

The product is not reactive under normal conditions.

Chemical stability

The product is stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.

Possibility of hazardous reactions

No hazard reactions are expected under normal processing.

Conditions to avoid

Keep away from open flames, hot surfaces and sources of ignition.

Incompatible materials

- Strong acids
- Strong bases
- Carbonates
- Oxidising agents

Hazardous decomposition products

No data available.

Disposal considerations

Waste treatment methods

Dispose of waste materials at a licensed site.
Rinse with water the used containers three times and empty the water into the application tank.
Do not burn containers, even after use. Disable the used packaging and dispose of content and/or empty containers in accordance with local, regional, national, and/or international regulations.