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Diss Factsheets

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2019-11-11 to 2020-02-23
Reliability:
1 (reliable without restriction)
Qualifier:
according to guideline
Guideline:
other: UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Appendix 6: Screening Procedures.
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: OECD 113 (Screening test for thermal stability and stability in air)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Specific details on test material used for the study:
- Batch No.: 2019002
- Purity: 98.39 %
- Physical state: White solid
- Storage conditions: Ambient temperature (10–30 °C)
- Expiry date: 2020-10-21
Key result
Parameter:
other: DSC: exothermal effect starting at 365 °C
Value:
207
Remarks on result:
other: exothermal effect starting at 365 °C with an energy of up to 207 J/g

The test item showed an exothermal effect starting at 365 °C with an energy of up to 207 J/g in closed DSC-measurements.


Two DSC measurements in closed flask crucibles showed an endothermal effect. Details are provided in the table below.






























Ident-No.



Weight [mg]



Final temperature [°C]



Temperature range [°C]



Type of effect



Energy [J/g]



38917



11.10



500



210–235


365–435



Endothermal


Exothermal



Not relevant


182



38925



12.05



500



200–230


370–440



Endothermal


Exothermal



Not relevant


207



 

Interpretation of results:
GHS criteria not met
Conclusions:
The test item had no explosive properties in the sense of the UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Appendix 6: Screening Procedures.
Executive summary:

In a GLP study conducted according to OECD 113, a screening of explosive properties of the test item was performed. The test item showed an exothermal effect starting at 365 °C with an energy of up to 207 J/g in closed DSC measurements. As the heat of decomposition was below 500 J/g and due to the organic nature of the test item, the test item is not to be classified as a explosive substance in the sense of the UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Appendix 6: Screening Procedures.

Description of key information

N-(4-((4-(3-phenylureido)phenyl)sulfonyl)phenyl)benzenesulfonamide is not explosive.

Key value for chemical safety assessment

Explosiveness:
non explosive

Additional information

In a GLP study conducted according to OECD 113, a screening of explosive properties of the test item was performed. The test item showed an exothermal effect starting at 365 °C with an energy of up to 207 J/g in closed DSC measurements. As the heat of decomposition was below 500 J/g and due to the organic nature of the test item, the test item is not to be classified as a explosive substance in the sense of the UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Appendix 6: Screening Procedures.

Justification for classification or non-classification