Registration Dossier

Administrative data

First-aid measures

4.1 Description of first aid measures
· General information Remove contaminated clothing.
· After inhalation Supply fresh air; consult doctor in case of symptoms.
· After skin contact
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor.
· After swallowing Rinse out mouth and then drink plenty of water.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

Fire-fighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents Foam, carbon dioxide, dry powder, water spray.
· For safety reasons unsuitable extinguishing agents Water with a full water jet.
· 5.2 Special hazards arising from the substance or mixture
Can be released in case of fire :
- carbon dioxide, carbon monoxide
- Nitrogen oxides (NOx)
· 5.3 Advice for firefighters
· Protective equipment:
Wear self-contained breathing apparatus.
Do not inhale explosion gases or combustion gases.

Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective clothing.
· 6.2 Environmental precautions:
Do not allow to enter the ground/soil.
Dilute with much water.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
· 6.4 Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.

Handling and storage

· 7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about protection against explosions and fires: No special measures required.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage
· Requirements to be met by storerooms and containers: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed.
· Storage class LGK 10-13
· 7.3 Specific end use(s) No further relevant information available

Transport information

Land transport (ADR/RID)

UN number:
3265
Shippingopen allclose all
Class:
8 (C3) Corrosive substances.
Classification code:
8 (C3) Corrosive substances.
Packaging group:
III
Labels:
8
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3265
Shippingopen allclose all
Class:
8 (C3) Corrosive substances.
Classification code:
8 (C3) Corrosive substances.
Packaging group:
III
Labels:
8
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3265
Proper shipping name and description:
CORROSIVE LIQUID, ACIDIC,
ORGANIC, N.O.S.
Chemical name:
1-METHYLPYRIDINIO-3-
CARBOXYLAT
Class:
8 (C3) Corrosive substances.
Packaging group:
III
Labels:
8
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3265
Proper shipping name and description:
CORROSIVE LIQUID, ACIDIC,
ORGANIC, N.O.S.
Chemical name:
1-METHYLPYRIDINIO-3-
CARBOXYLAT
Class:
8 (C3) Corrosive substances.
Packaging group:
III
Labels:
8
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

· Additional information about design of technical systems: No further data; see item 7.
· 8.1 Control parameters
· Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
· Additional information: The lists that were valid during the compilation were used as basis.
· 8.2 Exposure controls
· Personal protective equipment
· General protective and hygienic measures
Do not eat, drink or smoke while working.
Keep away from foodstuffs, beverages and food.
Take off immediately all contaminated clothing
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Breathing equipment:
In case of formation of vapours/aerosols:
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or
longer exposure use breathing apparatus that is independent of circulating air.
· Recommended filter device for short term use: Combination filter A-P2
· Protection of hands:
PVC gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and
has to be observed.
· Eye protection: Tightly sealed safety glasses.
· Body protection: Light weight protective clothing

Stability and reactivity

· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Nitrogen oxides (NOx)

Disposal considerations

13.1 Waste treatment methods
· Recommendation Must be specially treated under adherence to official regulations.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
· Recommended cleaning agent: Water, if necessary with cleaning agent.