Registration Dossier
Registration Dossier
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EC number: 212-836-5 | CAS number: 873-32-5
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
Note: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
Personal protection for the First Aider.
After inhalation: Supply fresh air; consult doctor in case of symptoms.
After skin contact: Wash immediately with plenty of water and soap and rinse thoroughly. If skin irritation occurs, get medical attention.
After eye contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
After swallowing: IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Do not induce vomiting. Call a physician immediately. Administer activated charcoal (3 table spoons mixed in glass of water). Bring vomiting person into recovery position. Do not give anything by mouth to an unconscious person.
Most important symptoms and effects, both acute and delayed
Symptoms and effects are described in section 2 and 11 of the SDS.
No further relevant information available.
Note: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
Personal protection for the First Aider.
After inhalation: Supply fresh air; consult doctor in case of symptoms.
After skin contact: Wash immediately with plenty of water and soap and rinse thoroughly. If skin irritation occurs, get medical attention.
After eye contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
After swallowing: IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Do not induce vomiting. Call a physician immediately. Administer activated charcoal (3 table spoons mixed in glass of water). Bring vomiting person into recovery position. Do not give anything by mouth to an unconscious person.
Most important symptoms and effects, both acute and delayed
Symptoms and effects are described in section 2 and 11 of the SDS.
No further relevant information available.
Fire-fighting measures
Extinguishing media
Suitable extinguishing agents: Water spray jet, extinguishing powder, COâ‚‚, foam.
Unsuitable extinguishing agents for reasons of safety: None
Special hazards arising from the substance or mixture
In case of fire, toxic incineration products may be released such as: Carbon monoxide (CO)
Advice for firefighters
Protective equipment: Wear self-contained breathing apparatus.
Additional information: Collect contaminated fire fighting water separately. It must not enter drains. Dispose of fire debris and contaminated fire fighting water in
accordance with official regulations.
Suitable extinguishing agents: Water spray jet, extinguishing powder, COâ‚‚, foam.
Unsuitable extinguishing agents for reasons of safety: None
Special hazards arising from the substance or mixture
In case of fire, toxic incineration products may be released such as: Carbon monoxide (CO)
Advice for firefighters
Protective equipment: Wear self-contained breathing apparatus.
Additional information: Collect contaminated fire fighting water separately. It must not enter drains. Dispose of fire debris and contaminated fire fighting water in
accordance with official regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
When selecting the protective suit attention has to be paid to the complete and safe protection of
skin and mucous membranes. Impermeable protective clothes, protective boots made of neoprene,
complete face protection and nitrile-rubber-gloves with long tops should be worn.
Environmental precautions:
Inform authorities in case of contamination of water or sewage system.
Do not allow product to enter waters without treatment in a (biological) water treatment plant.
Methods and material for containment and cleaning up:
Collect large amounts in suitable container. Cover the rest with absorbent, mix intensively and collect mechanically.
Send for recovery or disposal in suitable containers. Dispose of contaminated material as waste according to item 13 of the SDS.
Wear protective equipment. Keep unprotected persons away.
When selecting the protective suit attention has to be paid to the complete and safe protection of
skin and mucous membranes. Impermeable protective clothes, protective boots made of neoprene,
complete face protection and nitrile-rubber-gloves with long tops should be worn.
Environmental precautions:
Inform authorities in case of contamination of water or sewage system.
Do not allow product to enter waters without treatment in a (biological) water treatment plant.
Methods and material for containment and cleaning up:
Collect large amounts in suitable container. Cover the rest with absorbent, mix intensively and collect mechanically.
Send for recovery or disposal in suitable containers. Dispose of contaminated material as waste according to item 13 of the SDS.
Handling and storage
Precautions for safe handling
Provide good room ventilation or local exhaust ventilation at the workplace. Undertake operation under enclosed conditions.
Clean contaminated work equipment immediately to avoid skin corrosion/-irritation and/or allergic skin reactions in case of unconscious skin contact.
Risks to the safety and health of workers may not only be created by work involving chemicals but, inter alia by work equipment and the fitting-out of work-places.
Those risks shall be identified and evaluated.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and containers: No special requirements.
Further information about storage conditions: Keep containers tightly sealed. Protect from humidity and keep away from water.
Provide good room ventilation or local exhaust ventilation at the workplace. Undertake operation under enclosed conditions.
Clean contaminated work equipment immediately to avoid skin corrosion/-irritation and/or allergic skin reactions in case of unconscious skin contact.
Risks to the safety and health of workers may not only be created by work involving chemicals but, inter alia by work equipment and the fitting-out of work-places.
Those risks shall be identified and evaluated.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and containers: No special requirements.
Further information about storage conditions: Keep containers tightly sealed. Protect from humidity and keep away from water.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- None
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Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- None
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Marine transport (UN RTDG/IMDG)
- UN number:
- None
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- None
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Exposure controls / personal protection
Control parameters
Components with critical values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
Additional information: Information valid at the time of review of safety data sheet.
Exposure controls
Technical protective equipment: In case of contamination devices to rinse eyes or skin immediately under running water must be available.
Personal protective equipment
General protective and hygienic measures: Avoid contact with the eyes and the skin. Wash hands during work breaks and at the end of the shift. Use skin cream for skin protection.
Provide skin protection plan. Immediately remove any soiled and impregnated garments.
Respiratory protection: Not required
Hand protection: Chemical protective gloves (EN ISO 374-1:2016)
Check the condition of protective gloves after each use for any damages like holes, cuts or tears. Do not wear protective gloves longer than necessary.
After use of gloves apply skin-cleaning agents and skin cosmetics. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves Nitrile rubber, NBR
Penetration time of glove material: Thickness: 0.4 mm; break-through time: 480 min; material: Nitrile; permeation: level 6
Gloves made of the following materials are not suitable: Gloves for mechanical protection do not provide protection against chemicals.
Eye protection: Use visor in combination with goggle.
Body protection: Protective clothing (EN ISO 13688:2013)
Risk management measures
The operators shall be instructed adequately. The workplace shall be inspected regularly by competent personnel e.g. the safety representative.
Components with critical values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
Additional information: Information valid at the time of review of safety data sheet.
Exposure controls
Technical protective equipment: In case of contamination devices to rinse eyes or skin immediately under running water must be available.
Personal protective equipment
General protective and hygienic measures: Avoid contact with the eyes and the skin. Wash hands during work breaks and at the end of the shift. Use skin cream for skin protection.
Provide skin protection plan. Immediately remove any soiled and impregnated garments.
Respiratory protection: Not required
Hand protection: Chemical protective gloves (EN ISO 374-1:2016)
Check the condition of protective gloves after each use for any damages like holes, cuts or tears. Do not wear protective gloves longer than necessary.
After use of gloves apply skin-cleaning agents and skin cosmetics. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves Nitrile rubber, NBR
Penetration time of glove material: Thickness: 0.4 mm; break-through time: 480 min; material: Nitrile; permeation: level 6
Gloves made of the following materials are not suitable: Gloves for mechanical protection do not provide protection against chemicals.
Eye protection: Use visor in combination with goggle.
Body protection: Protective clothing (EN ISO 13688:2013)
Risk management measures
The operators shall be instructed adequately. The workplace shall be inspected regularly by competent personnel e.g. the safety representative.
Stability and reactivity
Reactivity
The evaluation of the relevant available information does not show an indication of any metal corrosive property.
Chemical stability
Conditions to be avoided: Before handling, the product should not be diluted or mixed with other chemicals, in order to avoid any negative influences
on the ingredient(s).
Possibility of hazardous reactions No dangerous reactions known.
Incompatible materials:
Reducing agents
Oxidizing agents
Acids
Alkalis (lyes)
Hazardous decomposition products: None, if storage and handling is done according to specification.
The evaluation of the relevant available information does not show an indication of any metal corrosive property.
Chemical stability
Conditions to be avoided: Before handling, the product should not be diluted or mixed with other chemicals, in order to avoid any negative influences
on the ingredient(s).
Possibility of hazardous reactions No dangerous reactions known.
Incompatible materials:
Reducing agents
Oxidizing agents
Acids
Alkalis (lyes)
Hazardous decomposition products: None, if storage and handling is done according to specification.
Disposal considerations
Waste treatment methods
Recommendation: Hazardous waste. Separate waste disposal to be applied.
Appropriate disposal operations according to Directive 2008/98/EC on waste: D 10 Incineration on land
Contaminated packaging:
Recommendation: Packaging can be reused or recycled after cleaning. Cleaning liquid can be fed to a biological wastewater treatment plant.
Recommended cleaning agent: Water, if necessary with cleaning agent.
Recommendation: Hazardous waste. Separate waste disposal to be applied.
Appropriate disposal operations according to Directive 2008/98/EC on waste: D 10 Incineration on land
Contaminated packaging:
Recommendation: Packaging can be reused or recycled after cleaning. Cleaning liquid can be fed to a biological wastewater treatment plant.
Recommended cleaning agent: Water, if necessary with cleaning agent.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
