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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Partition coefficient

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
partition coefficient
Data waiving:
study technically not feasible
Justification for data waiving:
the study does not need to be conducted because the substance decomposes

Description of key information

Triethoxysilyl-(1,3-dimethylbutylidene)propylamine hydrolysis very fast into ethanol and the (1,3-dimethylbutylidene)propylamine-silanol. The determination of the partitions coefficient is technically not feasible with Triethoxysilyl-(1,3-dimethylbutylidene)propylamine and the endpoint is waived.

The average half-lives for the hydrolysis of alkoxysilanes are very short:

Hydrolysis of alkoxysilanes is both acid and base-catalyzed (Osterholtz

and Pohl, 1992; Mill and Tse, 1989). Rates are slowest near pH7.

Experimental hydrolysis half-lives for various alkoxysilanes are as

follows (25 deg C)(Osterholtz and Pohl, 1992; Mill and Tse, 1989):

pH4: 1.1 to 24 min

pH5: 13 to 155 min

pH7: 28 to 504 min

pH9: 0.04 to 340 min

A theoretical partition coefficient of Triethoxysilyl-(1,3-dimethylbutylidene)propylamine was predicted by QSAR according to EPI Suite 4.11 (KOWWIN v. 1.68) and the data are used as supporting data (Log Kow = 5.19).

Key value for chemical safety assessment

Additional information