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Diss Factsheets

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
key study
Study period:
23. Jul. 2018 to 31. Jul. 2018
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
other: OECD Guidelines for the Testing of Chemicals, Method No. 113
Version / remarks:
OECD Guidelines for the Testing of Chemicals, Method No. 113, adopted 12. May 1981: “Screening Test for Thermal Stability and Stability in Air”
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: UN Handbook “Recommendations on the Transport of Dangerous Goods; Manual of Tests and Criteria”
Version / remarks:
UN Handbook “Recommendations on the Transport of Dangerous Goods; Manual of Tests and Criteria”; sixth revised edition, UN, 2015, Section 20.2.1, 20.3.3.3 und Appendix 6
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Specific details on test material used for the study:
No further details specified in the study report.
Key result
Parameter:
other: DSC Screening Test
Remarks on result:
other: no exothermal event was observed till 500 °C

RESULTS

Safety pre-test 1

Heating on a magnesia groove

When heated on a magnesia groove over a Bunsen burner, the test item burned with an orange sooting flame.

Beaten with a hammer

When the test item was beaten with a hammer on the anvil, no reaction occurs.

 

Safety pre-test 2

After reaching a temperature of 520 °C and cooling down the weight of the crucible was recorded with 623.12 mg, the gold sealing of the crucible was purple and bulged outwards.

Then the crucible was opened, the test item was black, hard and bloated.

 

Observations

Values Observations

 

Mass test item

Mass crucible (before measurement):

Mass crucible (after measurement):

Observations

First Measurement

2.81 mg

621.56 mg

619.55 mg

The gold sealing of the crucible was bulged outwards. After the measurement the crucible was opened, the test item was black, oily and smelled carbonized.

 

Interpretation of results:
GHS criteria not met
Conclusions:
A screening test via DSC (differential scanning calorimetry) was conducted from 0°C to 520 °C.
During the DSC no exothermal event was observed till 500 °C
- the test item is no subject to the classification procedures for self-reactive substances.
- the acceptance procedures for Class 1 explosives need not to be applied.
according to the UN Handbook “Recommendations on the Transport of Dangerous Goods; Manual of Tests and Criteria sixth revised edition, UN, 2015, Section 20.2.1, 20.3.3.3 and Appendix 6.
The measurement of indium after calibration met the validity criteria. Therefore, the result of the study is considered valid.
Executive summary:

Determination of the thermal stability of Trixene AS according to OECD 113

 

Findings and Results:

A screening test via DSC (differential scanning calorimetry) was conducted from 0°C to 520 °C.

During the DSC no exothermal event was observed till 500 °C

- the test item is no subject to the classification procedures for self-reactive substances.

- the acceptance procedures for Class 1 explosives need not to be applied.

 

According to the UN Handbook “Recommendations on the Transport of Dangerous Goods; Manual of Tests and Criteria sixth revised edition, UN, 2015, Section 20.2.1, 20.3.3.3 and Appendix 6

Description of key information

During the DSC no exothermal event was observed till 500 °C

Key value for chemical safety assessment

Explosiveness:
non explosive

Additional information

A screening test via DSC (differential scanning calorimetry) was conducted from 0°C to 520 °C.

During the DSC no exothermal event was observed till 500 °C

- the test item is no subject to the classification procedures for self-reactive substances.

- the acceptance procedures for Class 1 explosives need not to be applied.

Justification for classification or non-classification

- the test item is no subject to the classification procedures for self-reactive substances.

- the acceptance procedures for Class 1 explosives need not to be applied.

 

according to the UN Handbook “Recommendations on the Transport of Dangerous Goods; Manual of Tests and Criteria sixth revised edition, UN, 2015, Section 20.2.1, 20.3.3.3 and Appendix 6