Registration Dossier

Administrative data

First-aid measures

Description of necessary first-aid measures:

If inhaled
- If breathed in, move person into fresh air.
- Victim to lie down in the recovery position, cover and keep him warm.
- Oxygen or artificial respiration if needed.
- Immediate medical attention is required.

In case of eye contact
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- Immediate medical attention is required.

In case of skin contact
- Immediately apply calcium gluconate gel 2.5% and massage into the affected area using rubber gloves; continue to massage while repeatedly applying gel until 15 minutes after pain is relieved.
- Call a physician immediately.

If swallowed
- Drink 1 or 2 glasses of water.
- Do NOT induce vomiting.
- Call a physician immediately.
- Keep under medical supervision for at least 48 hours.

Fire-fighting measures

Suitable extinguishing media:
- Water
- powder
- Foam
- Dry chemical
- Carbon dioxide (CO2)

Specific hazards arising from the chemical
- The product is not flammable.
- Not explosive
- In case of fire hazardous decomposition products may be produced such as: Gaseous hydrogen fluoride (HF), Fluorophosgene
- Gaseous hydrogen chloride (HCl).

Special protective actions for fire-fighters
- Wear self-contained breathing apparatus and protective suit.
- When intervention in close proximity wear acid resistant over suit.
- Evacuate personnel to safe areas.
- Approach from upwind.
- Protect intervention team with a water spray as they approach the fire.
- Keep containers and surroundings cool with water spray.
- Keep product and empty container away from heat and sources of ignition.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel
- Prevent further leakage or spillage if safe to do so.

Advice for emergency responders
- Ensure adequate ventilation.
- Evacuate personnel to safe areas.
- Wear self-contained breathing apparatus and protective suit.
- Keep away from open flames, hot surfaces and sources of ignition.
- take protective measures

Methods and materials for containment and cleaning up
- Suppress (knock down) gases/vapours/mists with a water spray jet.
- Soak up with inert absorbent material.
- Suitable material for picking up
- Earth
- Dry sand
- Shovel into suitable container for disposal

Handling and storage

Precautions for safe handling
- Ensure adequate ventilation.
- Use personal protective equipment.
- Keep away from heat and sources of ignition.
- To avoid thermal decomposition, do not overheat.
- Take measures to prevent the build up of electrostatic charge.
- Clean and dry piping circuits and equipment before any operations.
- Purge piping circuits and equipment with nitrogen.
- Ensure all equipment is electrically grounded before beginning transfer operations.


Conditions for storage, including incompatibilities
* Storage
- Keep in a well-ventilated place.
- Keep in properly labelled containers.
- Keep container tightly closed.
- Keep in a dry place.
- Keep away from heat and sources of ignition.
- Keep away from combustible material.
- Keep away from Incompatible products.
- Provide tight electrical equipment well protected against corrosion.
- Refer to protective measures listed in sections 7 and 8.

* Packaging material
Suitable material : Plastic material

Transport information

Land transport (ADR/RID)

UN number:
UN2922
Proper shipping name and description:
CORROSIVE LIQUID, TOXIC, N.O.S. (F-Diox acylfluoride)
Language:
English
Class:
8
Packaging group:
II
Labels:
8 - corrosive
6.1- toxic
Special Provisions:
Hazard Identification Number: 86
Tunnel restriction code (E)

Inland waterway transport (ADN(R))

UN number:
UN 2922
Proper shipping name and description:
CORROSIVE LIQUID, TOXIC, N.O.S. (F-Diox acylfluoride)
Language:
English
Class:
8
Packaging group:
II
Labels:
8 - Corrosive
6.1 - Toxic
Remarks
Hazard Identification Number: 86

Marine transport (IMDG)

UN number:
UN 2922
Proper shipping name and description:
CORROSIVE LIQUID, TOXIC, N.O.S. (F-Diox acylfluoride)
Class:
8
Packaging group:
II
EmS code:
F-A
S-B
Labels:
8 - Corrosive
6.1 - Toxic
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 2922
Proper shipping name and description:
CORROSIVE LIQUID, TOXIC, N.O.S. (F-Diox acylfluoride)
Class:
8
Packaging group:
II
Labels:
8 - Corrosive
6.1 - Toxic
Remarks
Special precautions for user
Packing instruction (cargo aircraft) 855
Max net qty/pkg 30.00 L
Packing instruction (passenger aircraft) 855
Max net qty/pkg 30.00 L
SpecialProvisionsopen allclose all

Exposure controls / personal protection

1. Technical protection measures
- Provide local ventilation appropriate to the product decomposition risk.
- Refer to protective measures listed below.
- Apply technical measures to comply with the occupational exposure limits.

2. Organisational protection measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.

3. Hand protection
- Neoprene gloves
- Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).

4. Feet protection
- safety shoes

5. Body protection
- Lab coat

6. Eye protection
- Tightly fitting safety goggles
- If splashes are likely to occur, wear: Face-shield

7. Respiratory protection
- Use respirator when performing operations involving potential exposure to vapour of the product.
- The filter class for the respirator must be suitable for the maximum expected contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, selfcontained breathing apparatus must be used.
- Remove respiratory and skin/eye protection only after vapours have been cleared from the area.
- Use only respiratory protection that conforms to international/ national standards.

Stability and reactivity

Reactivity
- Reacts on contact with humidity in the air or with water to release of hydrofluoric acid.

Chemical stability
- Reacts violently with water

Possibility of hazardous reactions
- No dangerous reaction known under conditions of normal use.

Conditions to avoid
- Exposure to moisture.
- Keep away from flames and sparks.
- To avoid thermal decomposition, do not overheat.

Materials to avoid
- Flammable materials, Combustible material
- Alkali metals, Alkaline earth metals
- Zinc, Aluminum and magnesium in powder form

Hazardous decomposition products
- Fluorophosgene, Gaseous hydrogen chloride (HCl)., Gaseous hydrogen fluoride (HF).

Disposal considerations

Environmental precautions
- Should not be released into the environment.
- Do not flush into surface water or sanitary sewer system.
- Dispose of rinse water in accordance with local and national regulations

Waste disposal methods
- Can be incinerated, when in compliance with local regulations.
- The incinerator must be equipped with a system for the neutralisation or recovery of HF.
- In accordance with local and national regulations.

Contaminated packaging
- Empty containers can be landfilled, when in accordance with the local regulations.