Registration Dossier
Registration Dossier
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EC number: 948-548-8 | CAS number: 1260592-86-6
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of necessary first-aid measures:
If inhaled
- If breathed in, move person into fresh air.
- Victim to lie down in the recovery position, cover and keep him warm.
- Oxygen or artificial respiration if needed.
- Immediate medical attention is required.
In case of eye contact
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- Immediate medical attention is required.
In case of skin contact
- Immediately apply calcium gluconate gel 2.5% and massage into the affected area using rubber gloves; continue to massage while repeatedly applying gel until 15 minutes after pain is relieved.
- Call a physician immediately.
If swallowed
- Drink 1 or 2 glasses of water.
- Do NOT induce vomiting.
- Call a physician immediately.
- Keep under medical supervision for at least 48 hours.
If inhaled
- If breathed in, move person into fresh air.
- Victim to lie down in the recovery position, cover and keep him warm.
- Oxygen or artificial respiration if needed.
- Immediate medical attention is required.
In case of eye contact
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- Immediate medical attention is required.
In case of skin contact
- Immediately apply calcium gluconate gel 2.5% and massage into the affected area using rubber gloves; continue to massage while repeatedly applying gel until 15 minutes after pain is relieved.
- Call a physician immediately.
If swallowed
- Drink 1 or 2 glasses of water.
- Do NOT induce vomiting.
- Call a physician immediately.
- Keep under medical supervision for at least 48 hours.
Fire-fighting measures
Suitable extinguishing media:
- Water
- powder
- Foam
- Dry chemical
- Carbon dioxide (CO2)
Specific hazards arising from the chemical
- The product is not flammable.
- Not explosive
- In case of fire hazardous decomposition products may be produced such as: Gaseous hydrogen fluoride (HF), Fluorophosgene
- Gaseous hydrogen chloride (HCl).
Special protective actions for fire-fighters
- Wear self-contained breathing apparatus and protective suit.
- When intervention in close proximity wear acid resistant over suit.
- Evacuate personnel to safe areas.
- Approach from upwind.
- Protect intervention team with a water spray as they approach the fire.
- Keep containers and surroundings cool with water spray.
- Keep product and empty container away from heat and sources of ignition.
- Water
- powder
- Foam
- Dry chemical
- Carbon dioxide (CO2)
Specific hazards arising from the chemical
- The product is not flammable.
- Not explosive
- In case of fire hazardous decomposition products may be produced such as: Gaseous hydrogen fluoride (HF), Fluorophosgene
- Gaseous hydrogen chloride (HCl).
Special protective actions for fire-fighters
- Wear self-contained breathing apparatus and protective suit.
- When intervention in close proximity wear acid resistant over suit.
- Evacuate personnel to safe areas.
- Approach from upwind.
- Protect intervention team with a water spray as they approach the fire.
- Keep containers and surroundings cool with water spray.
- Keep product and empty container away from heat and sources of ignition.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel
- Prevent further leakage or spillage if safe to do so.
Advice for emergency responders
- Ensure adequate ventilation.
- Evacuate personnel to safe areas.
- Wear self-contained breathing apparatus and protective suit.
- Keep away from open flames, hot surfaces and sources of ignition.
- take protective measures
Methods and materials for containment and cleaning up
- Suppress (knock down) gases/vapours/mists with a water spray jet.
- Soak up with inert absorbent material.
- Suitable material for picking up
- Earth
- Dry sand
- Shovel into suitable container for disposal
Advice for non-emergency personnel
- Prevent further leakage or spillage if safe to do so.
Advice for emergency responders
- Ensure adequate ventilation.
- Evacuate personnel to safe areas.
- Wear self-contained breathing apparatus and protective suit.
- Keep away from open flames, hot surfaces and sources of ignition.
- take protective measures
Methods and materials for containment and cleaning up
- Suppress (knock down) gases/vapours/mists with a water spray jet.
- Soak up with inert absorbent material.
- Suitable material for picking up
- Earth
- Dry sand
- Shovel into suitable container for disposal
Handling and storage
Precautions for safe handling
- Ensure adequate ventilation.
- Use personal protective equipment.
- Keep away from heat and sources of ignition.
- To avoid thermal decomposition, do not overheat.
- Take measures to prevent the build up of electrostatic charge.
- Clean and dry piping circuits and equipment before any operations.
- Purge piping circuits and equipment with nitrogen.
- Ensure all equipment is electrically grounded before beginning transfer operations.
Conditions for storage, including incompatibilities
* Storage
- Keep in a well-ventilated place.
- Keep in properly labelled containers.
- Keep container tightly closed.
- Keep in a dry place.
- Keep away from heat and sources of ignition.
- Keep away from combustible material.
- Keep away from Incompatible products.
- Provide tight electrical equipment well protected against corrosion.
- Refer to protective measures listed in sections 7 and 8.
* Packaging material
Suitable material : Plastic material
- Ensure adequate ventilation.
- Use personal protective equipment.
- Keep away from heat and sources of ignition.
- To avoid thermal decomposition, do not overheat.
- Take measures to prevent the build up of electrostatic charge.
- Clean and dry piping circuits and equipment before any operations.
- Purge piping circuits and equipment with nitrogen.
- Ensure all equipment is electrically grounded before beginning transfer operations.
Conditions for storage, including incompatibilities
* Storage
- Keep in a well-ventilated place.
- Keep in properly labelled containers.
- Keep container tightly closed.
- Keep in a dry place.
- Keep away from heat and sources of ignition.
- Keep away from combustible material.
- Keep away from Incompatible products.
- Provide tight electrical equipment well protected against corrosion.
- Refer to protective measures listed in sections 7 and 8.
* Packaging material
Suitable material : Plastic material
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN2922
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, TOXIC, N.O.S. (F-Diox acylfluoride)
- Language:
- English
- Labels:
- 8 - corrosive
6.1- toxic
Special provisions / remarks
- Special provisions:
- Hazard Identification Number: 86
Tunnel restriction code (E)
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 2922
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, TOXIC, N.O.S. (F-Diox acylfluoride)
- Language:
- English
- Labels:
- 8 - Corrosive
6.1 - Toxic
Special provisions / remarks
- Remarks:
- Hazard Identification Number: 86
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 2922
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, TOXIC, N.O.S. (F-Diox acylfluoride)
- Labels:
- 8 - Corrosive
6.1 - Toxic
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 2922
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, TOXIC, N.O.S. (F-Diox acylfluoride)
- Labels:
- 8 - Corrosive
6.1 - Toxic
Special provisions / remarks
- Remarks:
- Special precautions for user
Packing instruction (cargo aircraft) 855
Max net qty/pkg 30.00 L
Packing instruction (passenger aircraft) 855
Max net qty/pkg 30.00 L
SpecialProvisionsopen allclose all
Exposure controls / personal protection
1. Technical protection measures
- Provide local ventilation appropriate to the product decomposition risk.
- Refer to protective measures listed below.
- Apply technical measures to comply with the occupational exposure limits.
2. Organisational protection measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
3. Hand protection
- Neoprene gloves
- Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
4. Feet protection
- safety shoes
5. Body protection
- Lab coat
6. Eye protection
- Tightly fitting safety goggles
- If splashes are likely to occur, wear: Face-shield
7. Respiratory protection
- Use respirator when performing operations involving potential exposure to vapour of the product.
- The filter class for the respirator must be suitable for the maximum expected contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, selfcontained breathing apparatus must be used.
- Remove respiratory and skin/eye protection only after vapours have been cleared from the area.
- Use only respiratory protection that conforms to international/ national standards.
- Provide local ventilation appropriate to the product decomposition risk.
- Refer to protective measures listed below.
- Apply technical measures to comply with the occupational exposure limits.
2. Organisational protection measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
3. Hand protection
- Neoprene gloves
- Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
4. Feet protection
- safety shoes
5. Body protection
- Lab coat
6. Eye protection
- Tightly fitting safety goggles
- If splashes are likely to occur, wear: Face-shield
7. Respiratory protection
- Use respirator when performing operations involving potential exposure to vapour of the product.
- The filter class for the respirator must be suitable for the maximum expected contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, selfcontained breathing apparatus must be used.
- Remove respiratory and skin/eye protection only after vapours have been cleared from the area.
- Use only respiratory protection that conforms to international/ national standards.
Stability and reactivity
Reactivity
- Reacts on contact with humidity in the air or with water to release of hydrofluoric acid.
Chemical stability
- Reacts violently with water
Possibility of hazardous reactions
- No dangerous reaction known under conditions of normal use.
Conditions to avoid
- Exposure to moisture.
- Keep away from flames and sparks.
- To avoid thermal decomposition, do not overheat.
Materials to avoid
- Flammable materials, Combustible material
- Alkali metals, Alkaline earth metals
- Zinc, Aluminum and magnesium in powder form
Hazardous decomposition products
- Fluorophosgene, Gaseous hydrogen chloride (HCl)., Gaseous hydrogen fluoride (HF).
- Reacts on contact with humidity in the air or with water to release of hydrofluoric acid.
Chemical stability
- Reacts violently with water
Possibility of hazardous reactions
- No dangerous reaction known under conditions of normal use.
Conditions to avoid
- Exposure to moisture.
- Keep away from flames and sparks.
- To avoid thermal decomposition, do not overheat.
Materials to avoid
- Flammable materials, Combustible material
- Alkali metals, Alkaline earth metals
- Zinc, Aluminum and magnesium in powder form
Hazardous decomposition products
- Fluorophosgene, Gaseous hydrogen chloride (HCl)., Gaseous hydrogen fluoride (HF).
Disposal considerations
Environmental precautions
- Should not be released into the environment.
- Do not flush into surface water or sanitary sewer system.
- Dispose of rinse water in accordance with local and national regulations
Waste disposal methods
- Can be incinerated, when in compliance with local regulations.
- The incinerator must be equipped with a system for the neutralisation or recovery of HF.
- In accordance with local and national regulations.
Contaminated packaging
- Empty containers can be landfilled, when in accordance with the local regulations.
- Should not be released into the environment.
- Do not flush into surface water or sanitary sewer system.
- Dispose of rinse water in accordance with local and national regulations
Waste disposal methods
- Can be incinerated, when in compliance with local regulations.
- The incinerator must be equipped with a system for the neutralisation or recovery of HF.
- In accordance with local and national regulations.
Contaminated packaging
- Empty containers can be landfilled, when in accordance with the local regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
