Registration Dossier

Administrative data

First-aid measures

Inhalation
After inhalation move to fresh air. If shortness of breath occurs, support respiration and consult a physician.
Bring patient immediately to fresh air. If breathing is heavily give oxygen; if necessary respirate artificially. Call physician.
Consult a physician if irritating symptoms develop and persist.
Skin Contact
Remove contaminated clothing. Rinse contaminated skin immediately with plenty of water and soap and seek medical advice.
Eye Contact
Immediately rinse eyes thoroughly with running water as long as possible (approx. 15 min).
Take injured quickly to factory medical center or call an ambulance (code word: eye accident).
Ingestion
Do not induce vomiting. In case of consciousness wash mouth with water and let drink some of water. Seek medical advice. Keep patient at rest. If swallowed, seek medical advice immediately and show this container or label.

Indication of any immediate medical attention and special treatment needed
Notes to Physician Apply general supportive and symptomatic treatment.

Fire-fighting measures

Suitable Extinguishing Media
Water spray or fog, foam, dry chemical powder, CO2, dry sand
Unsuitable Extinguishing Media
No restrictions

Special hazards arising from the substance or mixture
Dangerous Combustion Products
hydrogen bromide
carbon oxides
nitrogen oxides

Advice for firefighters
Protective equipment for firefighters
Wear self-contained breathing apparatus and fire protective suite.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Personal precautions Avoid contact with skin, eyes and clothing.

Environmental precautions
Must not be released into sewers, drains or wells.

Methods and material for containment and cleaning up
Methods for cleaning
Transfer large quantities into a container, rinse the rest with plenty of water.

Handling and storage

Precautions for safe handling
Storage and Handling Precautions
Open handling without suitable personal protective equipment must be avoided. Keep container tightly closed in a dry, cool and well-ventilated place. Ensure efficient exhaust ventilation when using this product

Conditions for safe storage, including any incompatibilities
Technical measures/ Precautions
Handle product only in closed system or provide appropriate exhaust ventilation at machinery.

Preventive Precautions (fire/explosion)
Take precautionary measures against static discharges. Avoid formation of dust. Keep away from sources of ignition. Observe the usual precautionary measures required for chemicals with dust explosive properties (Observe national regulations).

Transport information

Land transport (ADR/RID)

UN number:
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Marine transport (IMDG)

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Air transport ICAO/IATA

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Exposure controls / personal protection

Industrial Hygiene
The personal protective measure may be adapted appropriately when working in closed systems or under laboratory conditions.
Regular cleaning of equipment, work area and clothing.
No open handling without using reliable equipment. One technical barrier between substance and employee resp. environment.
Restricted and controlled access for trained personnel only.
Designated washing, changing and shower facilities must be available.
Internal working procedures available to personnel covering personal hygiene, decontamination /cleaning, consideration of worst case incidents, spills, emergency, alarms, waste disposal and maintenance.
Personnel comprehensively instructed, highly trained and experienced. Regular refresher training established including appropriate record keeping.
Equipment and protective garments must either be decontaminated or properly contained for disposal before leaving the area.
Disposable protective equipment is to be decontaminated before removal (decontamination shower).

Open Handling
Respiration : Full face mask (EN136)
Filter : P3 (EN143)
Eye : Yes, by face mask
Hand : Normal length chemical-mechanical-resistant gloves (EN374/EN388) worn over disposable gloves
Glove Material : Nitrile
Breakthrough time: 240 min
Thickness: 0.4 mm
Additional protection : Disposable dust-proof suit (EN465, type 4) worn over long underwear. Disposable boot covers, conductive

These values are derived from experiments, literature and information from the glove manufacturer.
They can also be derived from similar materials. In daily work please be aware that the using time depends on several factors and can be shorter than the oficially tested permeation time.

Stability and reactivity

Reactivity
Reaction products with water
None known
Chemical stability
Hydrolysis : no data available
Possibility of hazardous reactions
Materials to avoid
strong acids
strong bases
Conditions to avoid
Stable at normal conditions

Disposal considerations

Waste treatment methods
Disposal Requirements Incineration in an approved, controlled furnace with combustion gas scrubbing and emission gas control.
Container Disposal
For disposal local regulation is binding.
Special Precaution for User
Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.