Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
General advice
Take off contaminated clothing and shoes immediately.
Inhalation
Remove to fresh air. Oxygen, if needed.
Skin contact
Wash off immediately with soap and plenty of water.
Eye contact
Rinse immediately with plenty of water for at least 15 minutes. If eye irritation persists, consult a specialist.
Ingestion
Induce vomiting if person is conscious. Hold person's head low, to prevent aspiration (inhalation into
the windpipe) Rinse mouth. If conscious, give the victim plenty of water to drink. In case of accident or
if you feel unwell, seek medical advice immediately (show the label where possible).
Most important symptoms and effects, both acute and delayed
Lungs
Cough
Eyes
Inflammation
May cause sensitisation by skin contact.
Oral
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.
4.3 Indication of any immediate medical attention and special treatment needed
This ester can cause moderately serious poisoning effects.
Elimination is therefore the main aim of treatment.
Due to its non-corrosive nature, elimination can be achieved through immediate vomiting or irrigation
of the stomach if the chemical is ingested. It is helpful to give the person powdered carbon afterwards.
Take preventive measures against aspiration (intubation if necessary).
May cause sensitisation by skin contact.
Irritated areas of skin can be treated with corticosteroids.
Corticosteroids are effective following inhalation too.
Treat symptomatically.

Fire-fighting measures

Extinguishing media
Foam
Carbon dioxide (CO2)
Special hazards arising from the substance or mixture
Hazardous decomposition products formed under fire conditions.
Sulphur oxides
Carbon monoxide
Advice for firefighters
Special protective equipment for firefighters
In the event of fire, wear self-contained breathing apparatus.
Use personal protective equipment.
Additional advice
Prevent fire extinguishing water from contaminating surface water or the ground water system.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.
Use water spray to cool unopened containers.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Exposure controls
Ensure adequate ventilation.
Avoid contact with the skin and the eyes.
For personal protection see section 8.
Evacuate personnel to safe areas.
Keep people away from and upwind of spill/leak.
Environmental precautions
Do not allow contact with soil, surface or ground water.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and materials for containment and cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Treat recovered material as described in the section "Disposal considerations".

Handling and storage

Precautions for safe handling
Advice on safe handling : Limiting of employee, who are or who could exposed to this
dangerous substance
Limiting the mass of this dangerous substance at the place of
work on a required quantity
Periodical check, minimum three years, of effectivity an function of technical safty precautions.
Before a closed system is opened, purching and washing the
system are applied.
: Exposure controls
Handle and open container with care.
Ventilate the area.
Use only in area provided with appropriate exhaust ventilation.
Avoid contact with skin and eyes.
Ensure that eye flushing systems and safety showers are
located close to the working place.
Advice on protection against
fire and explosion
: Keep away from heat and sources of ignition.
To avoid thermal decomposition, do not overheat.
Conditions for safe storage, including any incompatibilities
Requirements for storage
areas and containers
: Keep container tightly closed in a dry and well-ventilated
place.
Store at room temperature in the original container.
Further information on storage conditions
: Store in accordance with the particular national regulations.
Advice on common storage : Keep away from oxidizing agents.
Keep away from food, drink and animal feedingstuffs.
German storage class : 10 Combustible liquids not in Storage Class 3
Other data : Stable under recommended storage conditions.

Transport information

Land transport (ADR/RID)

UN number:
3082
Shippingopen allclose all
Class:
9
Packaging group:
III
Labels:
9
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3082
Shippingopen allclose all
Class:
9
Packaging group:
III
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Chemical name:
trimethylolpropane tri(3-mercaptopropionate)
Class:
9
Packaging group:
III
EmS code:
EmS Number 1 : F-A
EmS Number 2 : S-F
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Chemical name:
trimethylolpropane tri(3-mercaptopropionate)
Class:
9
Packaging group:
III
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Control parameters: /
Exposure controls
Engineering measures
Use only in area provided with appropriate exhaust ventilation.
Occupational exposure controls
Personal protective equipment
a) Respiratory protection : In case of mist, spray or aerosol exposure wear suitable personal respiratory protection and protective suit.
Recommended Filter type: A
The filter class for the respirator must be suitable for the maximum expected contaminant concentration
(gas/vapour/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, selfcontained breathing apparatus must be used.
Follow the instructions for use issued by the producer.
b) Hand protection : Protective gloves
Polychloroprene / Layer thickness 0,5 - 0,7 mm / Break
through time > 480 min (level 6) / EN 374-3
Butyl-rubber / Layer thickness 0,6 - 0,8 mm / Break through
time > 480 min (level 6) / EN 374
Nitrile latex / Layer thickness 0,4 mm / Break through time >
480 min (level 6) / EN 374
General recommendation: the usage time for protective
gloves is approx. 50% of the breakthrough time measured in
the laboratory.
c) Eye protection : Wear eye/face protection.
Tightly fitting safety goggles
d) Skin and body protection
: Wear closed work/protective clothing. When working outside a
closed system, additionally put on aprons made of polyethylene (PE).
e) Hygiene measures : Provide sufficient air exchange and/or exhaust in work rooms.
Wash hands before breaks and at the end of workday.
Preventive skin protection
Avoid contact with the skin and the eyes.
Do not eat, drink or smoke when using this product.
Handle in accordance with good industrial hygiene and safety
practice.
Keep working clothes separately.
Take off contaminated clothing and wash before reuse.
Exposure controls
Environmental exposure controls
General advice : Do not allow contact with soil, surface or ground water.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Stability and reactivity

Reactivity
Chemical stability
Hazardous reactions
Conditions to avoid
Note Store between 5 and 25 °C in a dry, well ventilated place away from
sources of heat, ignition and direct sunlight.
Incompatible materials to avoid
Keep away from oxidizing agents

Disposal considerations

Waste treatment methods
Recommendations for the product
Avoid release to the environment.
Can be incinerated, when in compliance with local regulations.
This material and its container must be disposed of as hazardous waste-
Recommendations for packing
This material and its container must be disposed of as hazardous waste.
Recommended cleaning agent
industrial cleaning agent
Waste Key Number
16 05 08 : discarded organic chemicals consisting of or containing dangerous substances
Additional advice
The allocation of waste key numbers must be conducted according to specific industrial sectors and
processes.
Above-mentioned waste code number is valid for the unused product.
Obtain approval of the relevant authorities before discharging into a sewage treatment plant.
This material and its container must be disposed of as hazardous waste.