Registration Dossier
Registration Dossier
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EC number: 476-720-8 | CAS number: 768-35-4
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
General advice:
First aider needs to protect himself.
If inhaled:
fresh air. Call in physician.
In case of skin contact:
Take off immediately all contaminated clothing. Rinse skin with water/ shower.
Call a physician immediately.
In case of eye contact:
rinse out with plenty of water.
Immediately call in ophthalmologist.
Remove contact lenses.
If swallowed:
make victim drink water (two glasses at most), avoid vomiting (risk of perforation).
Call a physician immediately.
Do not attempt to neutralise.
Most important symptoms and effects, both acute and delayed
Symptoms:
Irritation and corrosion
Cough
Shortness of breath
Risk of blindness!
The following applies to boron compounds in general: resorption is followed by nausea and vomiting, agitation, spasms, CNS disorders, cardiovascular disorders.
Indication of any immediate medical attention and special treatment needed
Treatment:
No information available.
General advice:
First aider needs to protect himself.
If inhaled:
fresh air. Call in physician.
In case of skin contact:
Take off immediately all contaminated clothing. Rinse skin with water/ shower.
Call a physician immediately.
In case of eye contact:
rinse out with plenty of water.
Immediately call in ophthalmologist.
Remove contact lenses.
If swallowed:
make victim drink water (two glasses at most), avoid vomiting (risk of perforation).
Call a physician immediately.
Do not attempt to neutralise.
Most important symptoms and effects, both acute and delayed
Symptoms:
Irritation and corrosion
Cough
Shortness of breath
Risk of blindness!
The following applies to boron compounds in general: resorption is followed by nausea and vomiting, agitation, spasms, CNS disorders, cardiovascular disorders.
Indication of any immediate medical attention and special treatment needed
Treatment:
No information available.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
Water
Foam
Carbon dioxide (CO2)
Dry powder
Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
Special hazards arising from the substance or mixture
Specific hazards during firefighting:
Combustible.
Development of hazardous combustion gases or vapours possible in the event of fire.
Fire may cause evolution of:
Hydrogen fluoride
Advice for firefighters
Special protective equipment for firefighters:
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Further information:
Suppress (knock down) gases/vapours/mists with a water spray jet.
Prevent fire extinguishing water from contaminating surface water or the ground water system.
Suitable extinguishing media:
Water
Foam
Carbon dioxide (CO2)
Dry powder
Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
Special hazards arising from the substance or mixture
Specific hazards during firefighting:
Combustible.
Development of hazardous combustion gases or vapours possible in the event of fire.
Fire may cause evolution of:
Hydrogen fluoride
Advice for firefighters
Special protective equipment for firefighters:
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Further information:
Suppress (knock down) gases/vapours/mists with a water spray jet.
Prevent fire extinguishing water from contaminating surface water or the ground water system.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Personal precautions:
Advice for non-emergency personnel:
Avoid inhalation of dusts.
Avoid substance contact.
Ensure adequate ventilation.
Evacuate the danger area, observe emergency procedures, consult an expert.
Advice for emergency responders:
Protective equipment see SDS section 8.
Environmental precautions
Environmental precautions:
Do not flush into surface water or sanitary sewer system.
Methods and material for containment and cleaning up
Methods for cleaning up:
Cover drains. Collect, bind, and pump off spills.
Observe possible material restrictions (see SDS sections 7 and 10).
Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts.
Personal precautions:
Advice for non-emergency personnel:
Avoid inhalation of dusts.
Avoid substance contact.
Ensure adequate ventilation.
Evacuate the danger area, observe emergency procedures, consult an expert.
Advice for emergency responders:
Protective equipment see SDS section 8.
Environmental precautions
Environmental precautions:
Do not flush into surface water or sanitary sewer system.
Methods and material for containment and cleaning up
Methods for cleaning up:
Cover drains. Collect, bind, and pump off spills.
Observe possible material restrictions (see SDS sections 7 and 10).
Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts.
Handling and storage
Precautions for safe handling
Advice on safe handling:
Observe label precautions.
Hygiene measures:
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Conditions for safe storage, including any incompatibilities
Further information on storage conditions:
Tightly closed. Dry.
Risks from decomposition products: see SDS section 10.3
Recommended storage temperature:
Recommended storage temperature see product label.
Specific end use(s)
Apart from the uses mentioned in SDS section 1.2 no other specific uses are stipulated.
Advice on safe handling:
Observe label precautions.
Hygiene measures:
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Conditions for safe storage, including any incompatibilities
Further information on storage conditions:
Tightly closed. Dry.
Risks from decomposition products: see SDS section 10.3
Recommended storage temperature:
Recommended storage temperature see product label.
Specific end use(s)
Apart from the uses mentioned in SDS section 1.2 no other specific uses are stipulated.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 3261
Shipping information
- Proper shipping name and description:
- CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
( (3-fluorophenyl)boronic acid)
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 3261
Shipping information
- Proper shipping name and description:
- CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
( (3-fluorophenyl)boronic acid)
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 3261
Shipping information
- Proper shipping name and description:
- Corrosive solid, acidic, organic, n.o.s.
( (3-fluorophenyl)boronic acid)
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Control parameters
Exposure controls
Engineering measures
Technical measures and appropriate working operations should be given priority over the use of personal protective equipment.
See SDS section 7.1.
Personal protective equipment
Protective clothing needs to be selected specifically for the workplace, depending on concentrations and quantities of the hazardous substances handled. The chemical resistance of the protective equipment should be enquired at the respective supplier.
Eye protection: Tightly fitting safety goggles
Hand protection: full contact
Glove material: Nitrile rubber
Glove thickness: 0.11 mm
Break through time: > 480 min
splash contact
Glove material: Nitrile rubber
Glove thickness: 0.11 mm
Break through time: > 480 min
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example: KCL 741 Dermatril® L(full contact); KCL 741 Dermatril® L(splash contact).
The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374 with samples of the recommended glove types.
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves.
Protective measures:
protective clothing
Respiratory protection:
required when dusts are generated.
Recommended Filter type::
Filter P 2 (acc. to DIN 3181) for solid and liquid particles of harmful substances
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Environmental exposure controls
General advice:
Do not flush into surface water or sanitary sewer system.
Exposure controls
Engineering measures
Technical measures and appropriate working operations should be given priority over the use of personal protective equipment.
See SDS section 7.1.
Personal protective equipment
Protective clothing needs to be selected specifically for the workplace, depending on concentrations and quantities of the hazardous substances handled. The chemical resistance of the protective equipment should be enquired at the respective supplier.
Eye protection: Tightly fitting safety goggles
Hand protection: full contact
Glove material: Nitrile rubber
Glove thickness: 0.11 mm
Break through time: > 480 min
splash contact
Glove material: Nitrile rubber
Glove thickness: 0.11 mm
Break through time: > 480 min
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example: KCL 741 Dermatril® L(full contact); KCL 741 Dermatril® L(splash contact).
The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374 with samples of the recommended glove types.
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves.
Protective measures:
protective clothing
Respiratory protection:
required when dusts are generated.
Recommended Filter type::
Filter P 2 (acc. to DIN 3181) for solid and liquid particles of harmful substances
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Environmental exposure controls
General advice:
Do not flush into surface water or sanitary sewer system.
Stability and reactivity
Reactivity
The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.
Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
Possibility of hazardous reactions
Hazardous reactions:
Violent reactions possible with:
Strong acids
Strong oxidizing agents
Conditions to avoid
Conditions to avoid:
no information available
Incompatible materials
Materials to avoid:
no information available
Hazardous decomposition products
in the event of fire: See SDS section 5.
The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.
Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
Possibility of hazardous reactions
Hazardous reactions:
Violent reactions possible with:
Strong acids
Strong oxidizing agents
Conditions to avoid
Conditions to avoid:
no information available
Incompatible materials
Materials to avoid:
no information available
Hazardous decomposition products
in the event of fire: See SDS section 5.
Disposal considerations
According to national regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
