Registration Dossier
Registration Dossier
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EC number: 240-462-2 | CAS number: 16411-33-9
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
General information:
Take persons to a safe place. Observe self-protection for first aid. Always seek medical advice in the event of contact with this
substance.
After contact with the eyes:
Rinse immediately with plenty of water for 10-15 minutes. Keep eyelids well open to rinse the whole eye surface and eyelids with
water. Seek medical advice immediately and clearly identify substance. Continue to bathe eyes during transport to medical
practitioner.
After contact with the skin:
Remove contaminated clothes at once. Wash off with plenty of water or water and soap immediately for 10-15 minutes. In serious
cases, use emergency shower immediately. Seek medical advice immediately and clearly identify substance.
After inhalation:
Keep the patient calm. If unconscious place in stable sideways position. Protect against loss of body heat. If breathing stops,
administer artificial respiration. Seek medical advice immediately and clearly identify substance.
After swallowing:
If conscious, give several small portions of water to drink. Do not induce vomiting. Seek medical advice immediately and clearly
identify substance.
Most important symptoms and effects, both acute and delayed
Any relevant information can be found in other parts of this section.
Indication of any immediate medical attention and special treatment needed
After inhalation: treat as early as possible using cortisone spray. Medical checks necessary up to a latency period of at least 24
hours. In the event of 1st degree burns use corticoid-externa. In the case of 2nd degree burns, use symptomatic treatment.
Further toxicology information must be observed.
General information:
Take persons to a safe place. Observe self-protection for first aid. Always seek medical advice in the event of contact with this
substance.
After contact with the eyes:
Rinse immediately with plenty of water for 10-15 minutes. Keep eyelids well open to rinse the whole eye surface and eyelids with
water. Seek medical advice immediately and clearly identify substance. Continue to bathe eyes during transport to medical
practitioner.
After contact with the skin:
Remove contaminated clothes at once. Wash off with plenty of water or water and soap immediately for 10-15 minutes. In serious
cases, use emergency shower immediately. Seek medical advice immediately and clearly identify substance.
After inhalation:
Keep the patient calm. If unconscious place in stable sideways position. Protect against loss of body heat. If breathing stops,
administer artificial respiration. Seek medical advice immediately and clearly identify substance.
After swallowing:
If conscious, give several small portions of water to drink. Do not induce vomiting. Seek medical advice immediately and clearly
identify substance.
Most important symptoms and effects, both acute and delayed
Any relevant information can be found in other parts of this section.
Indication of any immediate medical attention and special treatment needed
After inhalation: treat as early as possible using cortisone spray. Medical checks necessary up to a latency period of at least 24
hours. In the event of 1st degree burns use corticoid-externa. In the case of 2nd degree burns, use symptomatic treatment.
Further toxicology information must be observed.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
extinguishing powder , foam , carbon dioxide .
Extinguishing media which must not be used for safety reasons:
water .
Special hazards arising from the substance or mixture
Hazardous combustion products: nitrous gases .
Advice for firefighters
Special protective equipment for fire fighting:
Use respiratory protection independent of recirculated air.
Suitable extinguishing media:
extinguishing powder , foam , carbon dioxide .
Extinguishing media which must not be used for safety reasons:
water .
Special hazards arising from the substance or mixture
Hazardous combustion products: nitrous gases .
Advice for firefighters
Special protective equipment for fire fighting:
Use respiratory protection independent of recirculated air.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Environmental precautions
Prevent material from entering sewers or surface waters. Contain any fluid that runs out using suitable material (e.g. earth).
6.3 Methods and material for containment and cleaning up
Absorb with a liquid binding material such as diatomaceous earth and dispose of according to local/state/federal regulations.
Further information:
Eliminate all sources of ignition.
Reference to other sections
Relevant information in other sections has to be considered. This applies in particular for information given on personal protective
equipment and on disposal.
Wear personal protection equipment.
Environmental precautions
Prevent material from entering sewers or surface waters. Contain any fluid that runs out using suitable material (e.g. earth).
6.3 Methods and material for containment and cleaning up
Absorb with a liquid binding material such as diatomaceous earth and dispose of according to local/state/federal regulations.
Further information:
Eliminate all sources of ignition.
Reference to other sections
Relevant information in other sections has to be considered. This applies in particular for information given on personal protective
equipment and on disposal.
Handling and storage
Precautions for safe handling
Precautions for safe handling:
Ensure adequate ventilation. Avoid contact with acids.
Precautions against fire and explosion:
Cool endangered containers with water. Flammable vapors may accumulate and form explosive mixtures with air in containers,
process vessels, including partial, empty and uncleaned containers and vessels, or other enclosed spaces. Keep away from open
flames, heat and sparks.
Conditions for safe storage, including any incompatibilities
Conditions for storage rooms and vessels:
none known
Advice for storage of incompatible materials:
not applicable
Further information for storage:
Protect against moisture. Keep container tightly closed and store in a cool, well ventilated place.
Precautions for safe handling:
Ensure adequate ventilation. Avoid contact with acids.
Precautions against fire and explosion:
Cool endangered containers with water. Flammable vapors may accumulate and form explosive mixtures with air in containers,
process vessels, including partial, empty and uncleaned containers and vessels, or other enclosed spaces. Keep away from open
flames, heat and sparks.
Conditions for safe storage, including any incompatibilities
Conditions for storage rooms and vessels:
none known
Advice for storage of incompatible materials:
not applicable
Further information for storage:
Protect against moisture. Keep container tightly closed and store in a cool, well ventilated place.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 2733
Shipping information
- Proper shipping name and description:
- Amine, entzündbar, ätzend, n.a.g. (enthält N,N',N''-Tributyl-1-methylsilantriamin und
Toluen)
AMINES, FLAMMABLE, CORROSIVE, N.O.S. (contains N,N',N''-tributyl-1-methyl
silane triamine and toluene)
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 2733
Shipping information
- Proper shipping name and description:
- Amine, entzündbar, ätzend, n.a.g. (enthält N,N',N''-Tributyl-1-methylsilantriamin und
Toluen)
AMINES, FLAMMABLE, CORROSIVE, N.O.S. (contains N,N',N''-tributyl-1-methyl
silane triamine and toluene)
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 2733
Shipping information
- Proper shipping name and description:
- Amines, flammable, corrosive, n.o.s. (contains N,N',N''-tributyl-1-methyl silane triamine
and toluene)
Special provisions / remarks
- Remarks:
- Bulk transport in tankers is not intended.
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 2733
Shipping information
- Proper shipping name and description:
- Amines, flammable, corrosive, n.o.s. (contains N,N',N''-tributyl-1-methyl silane triamine
and toluene)
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Control parameters
Maximum airborne concentrations at the workplace:
CAS No. Material Type mg/m3 ppm
108-88-3 Toluene AGW 190,0 50,0
109-73-9 n-Butylamine AGW 6,1 2,0
CAS No. Param. Value other material Time
108-88-3 TOLUOL 1,0 mg/l VOLLBLUT B
108-88-3 O-KRESOL 3,0 mg/l URIN B,C
Exposure controls
Exposure in the work place limited and controlled
General protection and hygiene measures:
Avoid contact with eyes and skin. Do not breathe vapours. Do not eat, drink or smoke when handling.
Personal protection equipment:
Respiratory protection
In case of long or strong exposure: gas mask filter K
Eye protection
tight fitting protective goggles . Provide work station with eye bathing equipment.
Hand protection
Protective gloves made of butyl rubber . Gloves suitable for up to 60 minutes' use.
Skin protection
protective clothing . Where there is risk of splashing: protective clothing, protective goggles/face protection .
Exposure to the environment limited and controlled
Prevent material from entering surface waters, drains or sewers and soil.
Aminobutane AGW 6,1 2,0
Aerosol - inhalable fraction 10,0
Toluene (CAS no. 108-88-3): Refer to Technical Rules for Hazardous Substances "TRGS 900" for more details on the German
AGW.
Maximum airborne concentrations at the workplace:
CAS No. Material Type mg/m3 ppm
108-88-3 Toluene AGW 190,0 50,0
109-73-9 n-Butylamine AGW 6,1 2,0
CAS No. Param. Value other material Time
108-88-3 TOLUOL 1,0 mg/l VOLLBLUT B
108-88-3 O-KRESOL 3,0 mg/l URIN B,C
Exposure controls
Exposure in the work place limited and controlled
General protection and hygiene measures:
Avoid contact with eyes and skin. Do not breathe vapours. Do not eat, drink or smoke when handling.
Personal protection equipment:
Respiratory protection
In case of long or strong exposure: gas mask filter K
Eye protection
tight fitting protective goggles . Provide work station with eye bathing equipment.
Hand protection
Protective gloves made of butyl rubber . Gloves suitable for up to 60 minutes' use.
Skin protection
protective clothing . Where there is risk of splashing: protective clothing, protective goggles/face protection .
Exposure to the environment limited and controlled
Prevent material from entering surface waters, drains or sewers and soil.
Aminobutane AGW 6,1 2,0
Aerosol - inhalable fraction 10,0
Toluene (CAS no. 108-88-3): Refer to Technical Rules for Hazardous Substances "TRGS 900" for more details on the German
AGW.
Stability and reactivity
Reactivity; Chemical stability; Possibility of hazardous reactions
If stored and handled in accordance with standard industrial practices no hazardous reactions are known.
Relevant information can possibly be found in other parts of this section.
Conditions to avoid
moisture
Incompatible materials
Reacts with: water . Reaction causes the formation of: amines .
Hazardous decomposition products
Under the effect of humidity, water and protic agents: n-butyl amine .
If stored and handled in accordance with standard industrial practices no hazardous reactions are known.
Relevant information can possibly be found in other parts of this section.
Conditions to avoid
moisture
Incompatible materials
Reacts with: water . Reaction causes the formation of: amines .
Hazardous decomposition products
Under the effect of humidity, water and protic agents: n-butyl amine .
Disposal considerations
Waste treatment methods
Material
Recommendation:
Dispose of according to regulations by incineration in a special waste incinerator. Small quantities may be disposed of by
incineration in an approved facility. Observe local/state/federal regulations.
Uncleaned packaging
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used.
Observe local/state/federal regulations.
Waste Disposal Legislation Ref.No.(EC)
It is not possible to determine a waste code for this product in accordance with the European Waste Catalogue (EWC) since it is
only possible to classify it according to how it is used by the customer. The waste code is to be determined within the EU in liaison
with the waste-disposal operator.
Material
Recommendation:
Dispose of according to regulations by incineration in a special waste incinerator. Small quantities may be disposed of by
incineration in an approved facility. Observe local/state/federal regulations.
Uncleaned packaging
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used.
Observe local/state/federal regulations.
Waste Disposal Legislation Ref.No.(EC)
It is not possible to determine a waste code for this product in accordance with the European Waste Catalogue (EWC) since it is
only possible to classify it according to how it is used by the customer. The waste code is to be determined within the EU in liaison
with the waste-disposal operator.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
