Registration Dossier

Administrative data

First-aid measures

General information: Remove injured from exposure. Remove contaminated clothing and shoes.
Consult a physician.
After inhalation: Remove to fresh air. In case of sickness or symptoms appeared consult a
physician.
After skin contact: Take off contaminated clothing immediately, wash the skin with plenty of water and soap.
After eye contact: Flush with plenty of water for at least 15 minutes.
Assure adequate flushing by separating the eyelids with fingers.
Consult a specialist for medical surveillance.
After swallowing: Wash out the mouth with water, drink copious amount of water (if conscious).
Consult with a physician immediately.
Do not induce vomiting.

Most important symptoms and effects,both acute and delayed:
Not available.

Indication of any immediate medical
attention and special treatment needed:
No specific antidote.
Treat symptomatically and supportively.

Fire-fighting measures

Extinguishing media: Water spray, carbon dioxide, extinguishing powder, foam.

Unsuitable extinguishing media: Do not use full water­jet when extinguishing.

Special hazards arising from the
substance or mixture:CO, CO2

Advice for firefighters: When extinguishing fires, use breathing apparatus with an independent source of air.

Fire hazard class Flammable solid

Fire and explosion hazard Highly flammable liquid. Vapours may form explosive mixtures with air.
Take precautionary measures against static electricity.

Accidental release measures

Personal precautions, protective
equipment and emergency procedures:
As a general rule, when handling avoid all contact and inhalation of dust,mists, and/or vapours associated with the material.

Environmental precautions: It is forbidden to pour into natural water or canal systems and communal
waste container.
Hinder substance from entering soil, sewers or living water.

Methods and material for containment and cleaning up:
In case of spill adsorb the liquid in a non­flammable material (sand, soil,perlit) and collect in a suiltable container for disposal. Wash the effected area with water, and aerate. Wear full protective equipment.

Handling and storage

Handling:
Keep away from sources of ignition. Electrostatic charge must be prevented.
Safety measures: Avoid ignition sources.
Fire and explosion protection
measures:
Flammable liquid. Vapours mixed with air may result explosive mixture.

Conditions for safe storage, including
any incompatibilities:
Keep container tightly closed in a dry and well­ventilated place.
Store below 30°C.

Transport information

Land transport (ADR/RID)

UN number:
UN 1224 KETONES, LIQUID, N.O.S.
Proper shipping name and description:
KETONES, LIQUID, N.O.S. (Cycloheptanone)
Language:
English
Packaging group:
III
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Marine transport (IMDG)

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Exposure controls / personal protection

National occupational exposure limit values:
AK: Unknown ; CK: Unknown ; MK: Unknown
Other occupational exposure limit values:
No data.
Relevant regulations and recommended monitoring procedures:
91/322/EEC; 98/24/EC directives and its modifications (2000/39/EC, 2006/15/EC)
Exposure controls:

Appropriate engineering controls: Suitable general and local exhaust ventilation.

Personal protection equipment
Eye/face protection: Tightly fitting, chemical resistant safety googles or full face mask.
Hand protection: Chemical resistant gloves.
Respiratory protection Gas­mask with ABEK2 filtering cartridge.
Personal protection, general hygienic
measures:
Remove contaminated clothing. Wash before reuse.
Wash hands and face with plentiful water after working with the substance.

Environmental exposure controlls: Do not let into drains.
Material and contaminated packaging should handle as hazardous wastes.

Stability and reactivity

Reactivity: Not known.
Stability: Stable at normal conditions.

Possibility of hazardous reactions: Not known.

Conditions to avoid (heat, pressure,
light, shock):
Ensure storage specifications

Incompatible materials: Amines.
Avoid contact with strong acids, bases, and strong oxidising materials.

Hazardous decomposition products Not known.

Disposal considerations

Disposal of the product related
waste:
Dispose the product according to national, state and local regulations.

Disposal of contaminated packaging:
Dispose according to the state and local regulations.
Relevant community, national and regional provisions:
Directive 2008/98/EC of the European Parliament and of the Council of 19November 2008 on wasteDirective 91/689/EEC of hazardous wastes.