Registration Dossier

Administrative data

First-aid measures

· Description of first aid measures
· General information:
Immediately remove any clothing soiled by the product.
Take note of the following instructions:
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Wash with water.
Remove contaminated clothing immediately.
If skin irritation occurs, consult a doctor.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing: Do not induce vomiting; call for medical help immediately.

· Most important symptoms and effects, both acute and delayed
No further relevant information available.

· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

Fire-fighting measures

· Extinguishing media
· Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions.
· For safety reasons unsuitable extinguishing agents: Water with full jet

· Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Phosphorus oxides (e.g. P2O5)
Carbon monoxide and carbon dioxide

· Advice for firefighters
· Protective equipment:
Do not inhale explosion gases or combustion gases.
Wear personal protective equipment.
· Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Collect contaminated fire fighting water separately. It must not enter the sewage system.

Accidental release measures

· Personal precautions, protective equipment and emergency procedures
Wear personal protective equipment. Keep unprotected persons away.
Use respiratory protective device against the effects of fumes/dust/aerosol.

· Environmental precautions:
Do not allow to enter sewers/ surface or ground water.
Damp down dust with water spray.
Keep contaminated washing water and dispose of appropriately.

· Methods and material for containment and cleaning up:
Sweep the spill area; avoid raising dust.
Dispose contaminated material as waste according to specifications.
Ensure adequate ventilation.

Handling and storage

· Precautions for safe handling
Prevent formation of dust.
Store in cool, dry place in tightly closed receptacles.
· Information about fire - and explosion protection: The product is not flammable.

· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility:
Do not store together with alkalis (caustic solutions).
Do not store together with oxidising and acidic materials.
Store away from foodstuffs.
· Further information about storage conditions: Keep container tightly sealed.

· Specific end use(s): No further relevant information available.

Transport information

Land transport (ADR/RID)

UN number:
None
Proper shipping name and description:
None
Class:
None
Packaging group:
None
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
None
Proper shipping name and description:
None
Class:
None
Packaging group:
None
Remarksopen allclose all

Marine transport (IMDG)

UN number:
None
Proper shipping name and description:
None
Class:
None
Packaging group:
None
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
None
Proper shipping name and description:
None
Class:
None
Packaging group:
None
Remarks
GRACE recommendation for air transport: Cargo aircraft only.

Additional transport information

Additional transport information
Not dangerous according to the above specifications.

· Environmental hazards: Not applicable.
· Special precautions for user: Not applicable.
· Transport in bulk according to Annex II of Marpol and the IBC Code: Not applicable.

Exposure controls / personal protection

· Control parameters
· Ingredients with limit values that require monitoring at the workplace: 126-73-8 tributyl phosphate
WEL (Great Britain) Short-term value: 5 mg/m³
Long-term value: 5 mg/m³

· DNELs (126-73-8 tributyl phosphate)
Oral DNEL(long-systemic): 0.22 mg/kg bw /day (General population), ECHA 2016
DNEL(acute-systemic): 0.88 mg/kg bw /day (General population), ECHA 2016
Dermal DNEL(acute-systemic): 0.88 mg/kg bw /day (General population), ECHA 2016; 1.78 mg/kg bw /day (Worker), ECHA 2016
DNEL(long-systemic): 0.22 mg/kg bw /day (General population), ECHA 2016; 0.44 mg/kg bw /day (Worker), ECHA 2016
DNEL(acute-local): 0.88 mg/m² (General population), ECHA 2016; 1.78 mg/m² (Worker), ECHA 2016
DNEL(long-local): 0.22 mg/m² (General population), ECHA 2016; 0.44 mg/m² (Worker), ECHA 2016
Inhalative DNEL(acute-systemic): 3.08 mg/m³ (General population), ECHA 2016; 12.52 mg/m³ (Worker), ECHA 2016
DNEL(long-systemic): 0.77 mg/m³ (General population), ECHA 2016; 3.13 mg/m³ (Worker), ECHA 2016
DNEL(acute-local): 3.08 mg/m³ (General population), ECHA 2016; 12.52 mg/m³ (Worker), ECHA 2016
DNEL(long-local): 0.77 mg/m³ (General population), ECHA 2016; 3.13 mg/m³ (Worker), ECHA 2016

· PNECs (126-73-8 tributyl phosphate)
82 mg/l (aqua-freshwater), ECHA 2016
1 mg/l (Sewage Treatment Plant), ECHA 2016
· Additional information: Valid lists at time of creation were used as basis.

· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
Filter P2
· Protection of hands:
Protective gloves.
Check the condition of the gloves prior to each use.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
Preventive skin protection by use of skin-protecting agents is recommended.
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
EN 388: Minimum requirements for efficiency level 1 for all groups.
Butyl rubber, BR
Nitrile rubber, NBR
Recommended thickness of the material: >= 0.11 mm
· Penetration time of glove material
EN 420: Minimum requirements for efficiency level 1 for all groups.
The exact break through time has to be obtained from the manufacturer of the protective gloves and has to be observed.
For the mixture of chemicals mentioned below the penetration time has to be at least 480 minutes (Permeation according to EN 374 Part 3: Level 6).
· For the permanent contact gloves made of the following materials are suitable:
Butyl rubber, BR
Nitrile rubber, NBR
· Not suitable are gloves made of the following materials: cloth gloves
· Eye protection:
Tightly sealed goggles
· Body protection:
Protective work clothing.
Decontamination of clothing and surfaces are covered under operating and emergency procedures.

Stability and reactivity

· Reactivity: No further relevant information available.
· Chemical stability
No decomposition if used according to specifications.
No decomposition if used and stored according to specifications.
· Possibility of hazardous reactions: No dangerous reactions known.
· Conditions to avoid
In case of thermal decomposition caused by smouldering and incomplete combustion toxic fumes may be developed.
· Incompatible materials: Protect from contamination.
· Hazardous decomposition products:
Phosphorus oxides (e.g. P2O5)
Carbon monoxide and carbon dioxide

Disposal considerations

· Waste treatment methods
· Recommendation: Disposal must be made according to official regulations.
· Waste disposal key:
The disposal of the product has to be carried out in accordance with the legal requirements. EWC waste codes are strictly industry-oriented, therefore waste classification has to be done by the waste producer.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.