Registration Dossier

Administrative data

First-aid measures

Ingestion: Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at
rest in a position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick
as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical
personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs.
Get medical attention if adverse health effects persist or are severe. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband.

Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper
and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation
occurs.

Skin contact: Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get
medical attention if irritation occurs.

Inhalation: If inhaled, remove to fresh air. Get medical attention if symptoms occur. If not breathing, give
artificial respiration. If breathing is difficult, administer oxygen.

Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training.

Fire-fighting measures

Suitable extinguishing media: In case of fire, use water spray (fog), foam, dry chemical or CO2.

Unsuitable extinguishing media: Do not use water jet.

Hazardous thermal decomposition products: In a fire or if heated, a pressure increase will occur and the container may burst.
Hazards from the substance or mixture: No specific data.

Special protective equipment for fire-fighters: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a
fire. No action shall be taken involving any personal risk or without suitable training.

Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for firefighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

For non-emergency personnel: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment.

For emergency responders: If specialized clothing is required to deal with the spillage, take note of any information in 'Exposure controls/personal protection' on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Environmental precautions: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Large spill : Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor.

Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if watersoluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Handling and storage

Precautions for safe handling

Protective measures: Put on appropriate personal protective equipment (see 'Exposure controls/personal protection'). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Advice on general occupational hygiene : Eating, drinking and smoking should be prohibited in areas where this material is handled, storedand processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also 'Exposure controls/personal protection' for additional information on hygiene measures.

Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and wellventilatedarea, away from incompatible materials (see 'Stability and reactivity') and food and drink. Keep container tightly closed and sealeduntil ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do notstore in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases.

Recommended monitoring procedures: If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Appropriate engineering controls: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value.

Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Eye/face protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.

Respiratory protection : Use appropriate respiratory protection if there is the potential to exceed the exposure limit(s). Seek professional advice prior to respirator selection and use. Select respirator based on suitability to provide adequate worker protection for given working conditions and level of airborne contaminant.

Hand Protection: Wear chemical resistant gloves. Nitrile gloves of minimum thickness 0.4 mm have an expected breakthrough time of 480 minutes or less when in frequent contact with the product. Due to variable exposure conditions the user must consider that the practical use of a chemical-protective glove in practice may be much shorter than the permeation time above. Manufacturer’s directions for use, especially about the minimum thickness and the minimum breakthrough time, must be observed. This information does not replace suitability tests by the end user since glove protection varies depending on the conditions under which the product is used.

Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental exposure controls: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Stability and reactivity

Reactivity: No specific test data related to reactivity available for this product or its ingredients
Chemical stability: Under recommended handling and storage conditions the product is stable.
Incompatible materials: Strong oxidizing and reducing agents.
Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid: High temperatures, sparks and open flames.

Disposal considerations

Methods of disposal: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.