Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 221-410-8 | CAS number: 3087-36-3
Guidance on Safe Use
Guidance on Safe Use
Currently viewing:
Administrative data
First-aid measures
· General information:
Immediately remove any clothing soiled by the product.
Take note of the following instructions:
· After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in the recovery position for transportation.
Call a doctor immediately.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation occurs, consult a doctor.
After eye contact:
Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Do not induce vomiting; call for medical help immediately.
· Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Immediately remove any clothing soiled by the product.
Take note of the following instructions:
· After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in the recovery position for transportation.
Call a doctor immediately.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation occurs, consult a doctor.
After eye contact:
Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Do not induce vomiting; call for medical help immediately.
· Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture
Can form explosive gas-air mixtures.
In case of fire, the following can be released:
Carbon monoxide and carbon dioxide
Metal oxide fume
· Advice for firefighters
· Protective equipment:
Mount respiratory protective device.
Do not inhale explosion gases or combustion gases.
Wear personal protective equipment.
· Additional information
Cool endangered container(s) with water spray.
Heating of container(s) will cause pressure rise with risk of bursting and subsequent explosion (BLEVE).
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture
Can form explosive gas-air mixtures.
In case of fire, the following can be released:
Carbon monoxide and carbon dioxide
Metal oxide fume
· Advice for firefighters
· Protective equipment:
Mount respiratory protective device.
Do not inhale explosion gases or combustion gases.
Wear personal protective equipment.
· Additional information
Cool endangered container(s) with water spray.
Heating of container(s) will cause pressure rise with risk of bursting and subsequent explosion (BLEVE).
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Accidental release measures
· Personal precautions, protective equipment and emergency procedures:
Wear personal protective equipment. Keep unprotected persons away.
· Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to specifications.
Ensure adequate ventilation.
Clean the affected area carefully; suitable cleaners are:
Warm water
Wear personal protective equipment. Keep unprotected persons away.
· Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to specifications.
Ensure adequate ventilation.
Clean the affected area carefully; suitable cleaners are:
Warm water
Handling and storage
· Precautions for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Store in cool, dry place in tightly closed receptacles.
Keep away from heat and direct sunlight.
Prevent static electric sparks.
Prevent formation of aerosols.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Protect from heat.
Traces of flammable substances may collect in the steam chamber of enclosed systems. Keep clear of ignition sources.
Fumes can combine with air to form an explosive mixture.
When heated the product forms flammable fumes.
The product is flammable.
Heating of container(s) will cause pressure rise with risk of bursting and subsequent explosion (BLEVE).
The vapour may be invisible and is heavier than air. It spreads along the ground and may enter sewers and basements.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store only in the original container.
· Information about storage in one common storage facility:
Do not store together with acids.
Do not store together with oxidising and acidic materials.
Store away from foodstuffs.
· Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Protect from heat and direct sunlight.
Protect from humidity and water.
· Specific end use(s): No further relevant information available.
Ensure good ventilation/exhaustion at the workplace.
Store in cool, dry place in tightly closed receptacles.
Keep away from heat and direct sunlight.
Prevent static electric sparks.
Prevent formation of aerosols.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Protect from heat.
Traces of flammable substances may collect in the steam chamber of enclosed systems. Keep clear of ignition sources.
Fumes can combine with air to form an explosive mixture.
When heated the product forms flammable fumes.
The product is flammable.
Heating of container(s) will cause pressure rise with risk of bursting and subsequent explosion (BLEVE).
The vapour may be invisible and is heavier than air. It spreads along the ground and may enter sewers and basements.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store only in the original container.
· Information about storage in one common storage facility:
Do not store together with acids.
Do not store together with oxidising and acidic materials.
Store away from foodstuffs.
· Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Protect from heat and direct sunlight.
Protect from humidity and water.
· Specific end use(s): No further relevant information available.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 1993
Shipping information
- Proper shipping name and description:
- 1993 FLAMMABLE LIQUID, N.O.S. (titanium(4+) ethanolate)
- Labels:
- 3
Special provisions / remarks
- Remarks:
- · Excepted quantities (EQ): E2
· Limited quantities (LQ): 5L
· Excepted quantities (EQ): Code E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
· Transport category: 3
· Tunnel restriction code: D/E
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 1993
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID, N.O.S. (titanium(4+) ethanolate)
- Labels:
- 3
Special provisions / remarks
- Remarks:
- · Limited quantities (LQ): 5L
· Excepted quantities (EQ): Code E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 1993
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID, N.O.S. (titanium(4+) ethanolate)
- Labels:
- 3
Special provisions / remarks
- Remarks:
- UN No. 1993
Special provisions: -
Danger Code: 3L
UN packing group: III
PASSENGER AND CARGO AIRCRAFT: Excepted Quantities: E1
Packing instruction: 355
max. net quantity per package: 60 L
Limited Quantity: Packing instruction: Y344; max. net quantity per package: 10 L
CARGO AIRCRAFT: Packing instruction: 366; max. net quantity per package: 220 L
GRACE recommends CARGO AIRCRAFT only.
SpecialProvisionsopen allclose all
Exposure controls / personal protection
· Additional information about design of technical facilities: No further data.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace: Not required.
DNELs:
Inhalative
DNEL(long-systemic)
950 mg/m³ (Worker), ECHA 2016
· Additional information: Valid lists at time of creation were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
Filter A/P2
· Protection of hands:
Protective gloves.
Check the condition of the gloves prior to each use.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
Preventive skin protection by use of skin-protecting agents is recommended.
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Butyl rubber, BR
Nitrile rubber, NBR
Recommended thickness of the material: >= 0.7 mm
· Penetration time of glove material
EN 420: Minimum requirements for efficiency level 1 for all groups.
The exact break through time has to be obtained from the manufacturer of the protective gloves and has to be observed.
For the mixture of chemicals mentioned below the penetration time has to be at least 480 minutes (Permeation according to EN 374 Part 3: Level 6).
· For the permanent contact gloves made of the following materials are suitable:
Butyl rubber, BR
Nitrile rubber, NBR
· Not suitable are gloves made of the following materials:
Leather gloves
cloth gloves
Rubber gloves
· Eye protection:
Tightly sealed goggles
· Body protection: Protective work clothing.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace: Not required.
DNELs:
Inhalative
DNEL(long-systemic)
950 mg/m³ (Worker), ECHA 2016
· Additional information: Valid lists at time of creation were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
Filter A/P2
· Protection of hands:
Protective gloves.
Check the condition of the gloves prior to each use.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
Preventive skin protection by use of skin-protecting agents is recommended.
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Butyl rubber, BR
Nitrile rubber, NBR
Recommended thickness of the material: >= 0.7 mm
· Penetration time of glove material
EN 420: Minimum requirements for efficiency level 1 for all groups.
The exact break through time has to be obtained from the manufacturer of the protective gloves and has to be observed.
For the mixture of chemicals mentioned below the penetration time has to be at least 480 minutes (Permeation according to EN 374 Part 3: Level 6).
· For the permanent contact gloves made of the following materials are suitable:
Butyl rubber, BR
Nitrile rubber, NBR
· Not suitable are gloves made of the following materials:
Leather gloves
cloth gloves
Rubber gloves
· Eye protection:
Tightly sealed goggles
· Body protection: Protective work clothing.
Stability and reactivity
· Reactivity: No further relevant information available.
· Chemical stability: No decomposition if used according to specifications.
· Possibility of hazardous reactions: Violent reactions with strong alkalis and oxidising agents.
· Conditions to avoid
In case of thermal decomposition caused by smouldering and incomplete combustion toxic fumes may be developed.
· Incompatible materials: Protect from contamination.
· Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Metal oxide smoke
· Chemical stability: No decomposition if used according to specifications.
· Possibility of hazardous reactions: Violent reactions with strong alkalis and oxidising agents.
· Conditions to avoid
In case of thermal decomposition caused by smouldering and incomplete combustion toxic fumes may be developed.
· Incompatible materials: Protect from contamination.
· Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Metal oxide smoke
Disposal considerations
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
