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Diss Factsheets

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
oxidising solids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.17 (Oxidising Properties (Solids))
Version / remarks:
Published in O.J. L 142 (2008).
Deviations:
yes
Remarks:
The test substance was not dried as it contents high hydrophilic sulfonate salts that rapidly bind air humidity.
GLP compliance:
yes (incl. QA statement)
Specific details on test material used for the study:
Name: Saturn Grey LCGCAS: 31765-95-4Batch No.: 8010/2008Appearance: black powderStorage: dark dry room, closed container, at laboratory temperatureExpiration date: February 2018
Contact with:
powdered cellulose
Key result
Sample tested:
test mixture as specified
Remarks:
60 % w/w sample with cellulose
Parameter:
burning rate
Remarks on result:
mixture does not ignite and burn
Sample tested:
reference mixture as specified
Remarks:
60 = barium nitrate with cellulose
Parameter:
burning rate
Result:
0.81 mm/s

Table No. 1: Burning rate results

Test substance

(% w/w)

Burning time

(s)

Burning rate

(mm/s)

Note

10

171

do not propagate

-

20

25

do not propagate

-

30

14

do not propagate

without flame

40

13

do not propagate

without flame

50

-

do not propagate

without flame

60

-

do not propagate

without flame

70

-

do not propagate

without flame

80

-

do not propagate

without flame

90

-

do not propagate

without flame

Reference substance

barium nitrate

(% w/w)

Burning time

(s)

Burning rate

(mm/s)

Note

10

329

0.61

-

20

311

0.64

-

30

393

0.51

-

40

471

0.42

-

50

312

0.64

-

60

247

0.81

-

70

309

0.65

-

80

-

do not propagate

without flame

90

-

do not propagate

without flame

 

Interpretation of results:
GHS criteria not met
Conclusions:
Based on results obtained from trial test, it is obvious that none of the test substance mixtures with cellulose burned all distance of 200 mm of the pile. Thus test substance, Direct Black 112, should not be considered as a substance with oxidizing properties.
Executive summary:

The oxidizing properties of the test substance, Direct Black 112, were determined. The procedure was performed according to the method A.17 Oxidizing properties (Solids), Council Regulation (EC) Mo. 440/2008, published in O.J. L 142, 2008. Based on results obtained from trial test, it is obvious that none of the test substance mixtures with cellulose burned all distance of 200 mm of the pile. Thus test substance, Direct Black 112, should not be considered as a substance with oxidizing properties.

Description of key information

Based on results obtained from trial test, it is obvious that none of the test substance mixtures with cellulose burned all distance of 200 mm of the pile. Thus test substance, Direct Black 112, should not be considered as a substance with oxidizing properties.

Key value for chemical safety assessment

Oxidising properties:
non oxidising

Additional information

Justification for classification or non-classification