Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

4.1 Description of first aid measures
General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection).
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility.
Skin Contact: Wash skin with plenty of water. Suitable emergency safety shower facility should be available in work area.
Eye Contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a physician, preferably an ophthalmologist. Suitable emergency eye wash facility should be available in work area.
Ingestion: Do not induce vomiting. Call a physician and/or transport to emergency facility immediately.

4.2 Most important symptoms and effects, both acute and delayed
Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), no additional symptoms and effects are anticipated.

4.3 Indication of immediate medical attention and special treatment needed
Maintain adequate ventilation and oxygenation of the patient. If burn is present, treat as any thermal burn, after decontamination. If lavage is performed, suggest endotracheal and/or esophageal control. Danger from lung aspiration must be weighed against toxicity when considering emptying the stomach. The decision of whether to induce vomiting or not should be made by a physician. No specific antidote. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

Fire-fighting measures

5.1 Extinguishing Media
Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective.
Extinguishing Media to Avoid: Do not use direct water stream. Straight or direct water streams may not be effective to extinguish fire.

5.2 Special hazards arising from the substance or mixture
Hazardous Combustion Products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Carbon monoxide. Carbon dioxide.
Unusual Fire and Explosion Hazards: Violent steam generation or eruption may occur upon application of direct water stream to hot liquids. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Flammable mixtures may exist within the vapor space of containers at room temperature. Flammable concentrations of vapor can accumulate at temperatures above flash point.

5.3 Advice for firefighters
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay upwind. Keep out of low areas where gases (fumes) can accumulate. Water may not be effective in extinguishing fire. Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Do not use direct water stream. May spread fire. Eliminate ignition sources. Move container from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Avoid accumulation of water. Product may be carried across water surface spreading fire or contacting an ignition source.
Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location.

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures: Isolate area. Keep unnecessary and unprotected personnel from entering the area. Keep personnel out of low areas. Keep upwind of spill. Ventilate area of leak or spill. No smoking in area. Vapor explosion hazard. Keep out of sewers. For large spills, warn public of downwind explosion hazard. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Ground and bond all containers and handling equipment. Use appropriate safety equipment.

6.2 Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater.

6.3 Methods and materials for containment and cleaning up: Ground and bond all containers and handling equipment. Small spills: Contain spilled material if possible. Large spills: Dike area to contain spill. Pump with explosion-proof equipment. If available, use foam to smother or suppress. Collect in suitable and properly labeled containers.

Handling and storage

7.1 Precautions for safe handling
General Handling: Keep away from heat, sparks and flame. Do not swallow. Avoid contact with eyes, skin, and clothing. Avoid breathing vapor. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Electrically bond and ground all containers and equipment before transfer or use of material. Never use air pressure for transferring product. No smoking, open flames or sources of ignition in handling and storage area. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Electrically bond and ground all containers, personnel and equipment before transfer or use of material. Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers.

7.2 Conditions for safe storage, including any incompatibilities
Storage
Flammable mixtures may exist within the vapor space of containers at room temperature. Keep container closed. Minimize sources of ignition, such as static build-up, heat, spark or flame. Store in original container.

7.3 Specific end uses
See the technical data sheet on this product for further information.

Transport information

Land transport (ADR/RID)

UN number:
UN3272
Proper shipping name and description:
Proper Shipping Name: ESTERS, N.O.S.
Chemical name:
PROPYL PROPIONATE
Language:
English
Class:
3
Packaging group:
PG III
Labels:
3
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN3272
Proper shipping name and description:
ESTERS, N.O.S.
Chemical name:
PROPYL PROPIONATE
Language:
English
Class:
3
Packaging group:
PG III
Labels:
3
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN3272
Proper shipping name and description:
ESTERS, N.O.S.
Chemical name:
PROPYL PROPIONATE
Class:
3
Packaging group:
PG III
EmS code:
F-E,S-D
Labels:
3
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN3272
Proper shipping name and description:
ESTERS, N.O.S.
Chemical name:
PROPYL PROPIONATE
Class:
3
Packaging group:
PG III
Labels:
3
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

8.1 Control parameters
Exposure Limits: None established

8.2 Exposure controls
Personal Protection
Eye/Face Protection: Use chemical goggles. Chemical goggles should be consistent with EN 166 or equivalent.

Skin Protection: When prolonged or frequently repeated contact could occur, use protective clothing chemically resistant to this material. Selection of specific items such as faceshield, boots, apron, or full-body suit will depend on the task.

Hand protection: Use gloves chemically resistant to this material when prolonged or frequently repeated contact could occur. Use chemical resistant gloves classified under Standard EN374: Protective gloves against chemicals and micro-organisms. Examples of preferred glove barrier materials include: Butyl rubber. Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Polyvinyl alcohol ("PVA"). Examples of acceptable glove barrier materials include: Natural rubber ("latex"). Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyvinyl chloride ("PVC" or "vinyl"). Viton. When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN 374) is recommended. NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.

Respiratory Protection: Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use an approved respirator. Selection of air-purifying or positive-pressure supplied-air will depend on the specific operation and the potential airborne concentration of the material. For emergency conditions, use an approved positive-pressure self-contained breathing apparatus. Use the following CE approved air-purifying respirator: Organic vapor cartridge, type A (boiling point >65 ºC)

Ingestion: Avoid ingestion of even very small amounts; do not consume or store food or tobacco in the work area; wash hands and face before smoking or eating.

Engineering Controls
Ventilation: Use engineering controls to maintain airborne level below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations.

Stability and reactivity

10.1 Reactivity
No dangerous reaction known under conditions of normal use.

10.2 Chemical stability
Thermally stable at typical use temperatures.

10.3 Possibility of hazardous reactions
Polymerization will not occur.

10.4 Conditions to Avoid: Exposure to elevated temperatures can cause product to decompose.

10.5 Incompatible Materials: Avoid contact with: Acids. Strong bases. Strong oxidizers. Strong reducing agents.

10.6 Hazardous decomposition products
Decomposition products depend upon temperature, air supply and the presence of other materials.

Disposal considerations

13.1 Waste treatment methods
This product, when being disposed of in its unused and uncontaminated state should be treated as a hazardous waste according to EC Directive 2008/98/EC. Any disposal practices must be in compliance with all national and provincial laws and any municipal or local by-laws governing hazardous waste. For used, contaminated and residual materials additional evaluations may be required. Do not dump into any sewers, on the ground, or into any body of water.