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Endpoint:
relative density
Type of information:
experimental study
Adequacy of study:
key study
Study period:
17 October 2016 to 11 November 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Cross-referenceopen allclose all
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reference
Endpoint:
melting point/freezing point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
17 October 2016 to 11 November 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Qualifier:
according to guideline
Guideline:
EU Method A.1 (Melting / Freezing Temperature)
Deviations:
no
Qualifier:
according to guideline
Guideline:
OECD Guideline 102 (Melting point / Melting Range)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
pour point
Specific details on test material used for the study:
SOURCE OF TEST MATERIAL
- Source and lot/batch No. of test material: CBI
- Expiration date of the lot/batch: 10 June 2018

STABILITY AND STORAGE CONDITIONS OF TEST MATERIAL
- Storage condition of test material: Room temperature, in the dark
Key result
Remarks on result:
other: Overall pour point result: -12 to -9 ± 3 °C (261 to 264 ± 3 K)

Preliminary Test:

The pour point of the preliminary test was -11 ± 3 °C (262 ± 3 K).

Main Test:

The results of the main test are shown in the following table:

Determination 1 Determination 2
Stationary point (⁰C) -15.0 -12.0
Pour Point (⁰C) -12.0 -9.0
Overall pour point result: -12 to -9 ± 3 °C (261 to 264 ± 3 K)
Conclusions:
The pour point of the test item has been determined to be -12 to -9 ± 3 °C (261 to 264 ± 3 K).
Executive summary:

The melting/freezing temperature of the test substance was determined to be -12 to -9 ± 3 °C (261 to 264 ± 3 K) using pour point method designed to be compatible with Method A.1 Melting/Freezing Temperature of Commission Regulation (EC) No 440/2008 of 30 May 2008 and Method 102 of the OECD Guidelines for Testing of Chemicals, 27 July 1995.

Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reference
Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
17 October 2016 to 11 November 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Qualifier:
according to guideline
Guideline:
EU Method A.2 (Boiling Temperature)
Deviations:
no
Qualifier:
according to guideline
Guideline:
OECD Guideline 103 (Boiling Point)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
differential scanning calorimetry
Specific details on test material used for the study:
SOURCE OF TEST MATERIAL
- Source and lot/batch No. of test material: CBI
- Expiration date of the lot/batch: 10 June 2018

STABILITY AND STORAGE CONDITIONS OF TEST MATERIAL
- Storage condition of test material: Room temperature, in the dark
Key result
Atm. press.:
100.2 kPa
Decomposition:
yes
Decomp. temp.:
202 °C
Remarks on result:
other: Decomposition from approximately 202 °C (475 K)
Thermal Event Interpretation Temperature (⁰C)
Exotherm onset of decomposition Determination 1 Determination 2
203.63 202.23

Atmospheric pressure: 102 kPa

After heating to 400 °C, the samples had lost approximately 26% and 27% of their original weight respectively.

Conclusions:
The test item has been determined to decompose from approximately 202 °C (475 K) at 102 kPa). As a result, no value for the boiling point of the test item could be determined.
Executive summary:

Decomposition from approximately 202 °C (475 K) at 102 kPa by differential scanning calorimetry, designed to be compatible with Method A.2 Boiling Temperature of Commission Regulation (EC) No 440/2008 of 30 May 2008 and Method 103 of the OECD Guidelines for Testing of Chemicals, 27 July 1995. As a result, no value for the boiling point of the test item could be determined.

Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reference
Endpoint:
water solubility
Type of information:
experimental study
Adequacy of study:
key study
Study period:
17 October 2016 to 11 November 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Qualifier:
according to guideline
Guideline:
EU Method A.6 (Water Solubility)
Deviations:
no
Qualifier:
according to guideline
Guideline:
OECD Guideline 105 (Water Solubility)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
flask method
Specific details on test material used for the study:
SOURCE OF TEST MATERIAL
- Source and lot/batch No. of test material: CBI
- Expiration date of the lot/batch: 10 June 2018

STABILITY AND STORAGE CONDITIONS OF TEST MATERIAL
- Storage condition of test material: Room temperature, in the dark
Key result
Water solubility:
< 0.001 other: gTOC/L
Conc. based on:
test mat.
Loading of aqueous phase:
0.1 g/L
Incubation duration:
24 h
Temp.:
20 °C
pH:
5.8
Details on results:
The preliminary estimates of water solubility at 20.0 ± 0.5 °C are shown in the following information:

Loading Rate (g/L) / Concentration (gTOC/L) / pH
0.1 / <1.0E-3 / 6.3
1 / 2.1E-3 / 6.3

Definitive Test: The results for the total organic carbon analysis are shown in the following table:
Solution / TOC (mgTOC/L):
Matrix blank A= 0.395
Matrix blank B= 0.340
Sample 1A= 0.573
Sample 1B= 0.676
Sample 2A= 0.582
Sample 2B= 0.584
Sample 3A= 0.981
Sample 3B= 0.949

Definitive Test

The concentration (g/L) of test item in the sample solutions is shown in the following table:

Sample Number Concentration (gTOC/L) Solution pH
1 < 1.0 E-3 5.8
2 < 1.0 E-3 5.8
3 < 1.0 E-3 5.8

Overall result: less than 1.0 x 10-3 gTOC/L at 20.0 ± 0.5 ºC

Conclusions:
The water solubility of the test item has been determined at 20.0 ± 0.5 °C and a nominal loading rate of 0.1 g/L to be less than 1.0 x 10-3 gTOC/L.
Executive summary:

Water Solubility was determined to be less than 1.0 x 10-3 gTOC/L at 20.0 ± 0.5 °C from a nominal loading rate of 0.1 g/L using the flask method, designed to be compatible with Method A.6 Water Solubility of Commission Regulation (EC) No 440/2008 of 30 May 2008 and Method 105 of the OECD Guidelines for Testing of Chemicals, 27 July 1995.

Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reference
Endpoint:
surface tension
Type of information:
experimental study
Adequacy of study:
key study
Study period:
17 October 2016 to 11 November 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Qualifier:
according to guideline
Guideline:
EU Method A.5 (Surface Tension)
Deviations:
no
Qualifier:
according to guideline
Guideline:
OECD Guideline 115 (Surface Tension of Aqueous Solutions)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
ring method
Specific details on test material used for the study:
SOURCE OF TEST MATERIAL
- Source and lot/batch No. of test material: CBI
- Expiration date of the lot/batch: 10 June 2018

STABILITY AND STORAGE CONDITIONS OF TEST MATERIAL
- Storage condition of test material: Room temperature, in the dark
Key result
Surface tension:
72 mN/m
Temp.:
21.6 °C
Conc.:
0.001 other: g/mL
Remarks on result:
other: sample 2
Key result
Surface tension:
72.3 mN/m
Temp.:
21.6 °C
Conc.:
0.001 other: g/mL
Remarks on result:
other: sample 3

SAMPLE 1:

Age of Solution (min) / Reading (mN/m) / Temperature (deg C)

79 / 37.0 / 21.8

90 / 67.0 / 21.8

103 / 67.0 / 21.8

114 / 67.0 / 21.8

123 / 67.0 / 21.8

SAMPLE 2:

Age of Solution (min) / Reading (mN/m) / Temperature (deg C)

1098 / 70.0 / 21.8

1110 / 71.0 / 21.8

1124 / 71.5 / 21.6

1142 / 72.0 / 21.6

1166 / 72.0 / 21.6

1178 / 72.0 / 21.4

1196 / 72.0 / 21.4

1207 / 72.0 / 21.4

SAMPLE 3:

Age of Solution (min) / Reading (mN/m) / Temperature (deg C)

72 / 72.5 / 21.6

87 / 72.0 / 21.6

99 / 72.0 / 21.6

111 / 72.5 / 21.8

123 / 72.5 / 21.8

Mean Sample 1 result : 67.0 mN/m

pH of Sample 1 : 5.5

Mean Sample 2 result* : 72.0 mN/m

pH of Sample 2 : 6.2

Mean Sample 3 result : 72.3 mN/m

pH of Sample 2 : 5.9 Mean result (Samples 2 and 3): 72.2 mN/m

Overall temperature : 21.6 ± 0.5 ºC

Conclusions:
The surface tension of duplicate solutions prepared at a nominally 90 % saturated solutions of test item in water has been determined to be 72.2 mN/m at 21.6 ± 0.5 °C. The test item was considered not to be surface-active.
Executive summary:

The surface tension was determined to be 72.2 mN/m (90% saturated solution) at 21.6 ± 0.5 °C using a ring method, designed to be compatible with Method A5 Surface Tension of Commission Regulation (EC) No 440/2008 of 30 May 2008 and Method 115 of the OECD Guidelines for Testing of Chemicals, 27 July 1995. The test item was considered not to be surface-active.

Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reference
Endpoint:
partition coefficient
Type of information:
experimental study
Adequacy of study:
key study
Study period:
17 October 2016 to 11 November 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Reason / purpose for cross-reference:
other: Study report pertains to multiple endpoints.
Qualifier:
according to guideline
Guideline:
EU Method A.8 (Partition Coefficient - Shake Flask Method)
Deviations:
no
Qualifier:
according to guideline
Guideline:
OECD Guideline 117 (Partition Coefficient (n-octanol / water), HPLC Method)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
HPLC method
Partition coefficient type:
octanol-water
Specific details on test material used for the study:
SOURCE OF TEST MATERIAL
- Source and lot/batch No. of test material: CBI
- Expiration date of the lot/batch: 10 June 2018

STABILITY AND STORAGE CONDITIONS OF TEST MATERIAL
- Storage condition of test material: Room temperature, in the dark
Analytical method:
high-performance liquid chromatography
Key result
Type:
log Pow
Partition coefficient:
> 10 000 000 000
Remarks on result:
other: The partition coefficient of the test item has been determined to be greater than 1.0E10, log10 Pow >10.0.
Details on results:
Preliminary Estimate: The estimated log10 Pow for the representative structure of the test item was calculated to be from 31.1

Definitive Test: The partition coefficient of the test item has been determined to be >1.0 x 10^10 with a log10 Pow of >10.0.
Conclusions:
The partition coefficient of the test item has been determined to be >1.0 E10 with a log10 Pow of >10.0.
Executive summary:

The partition coefficient (n-octanol/water) was determined to be greater than 1.0 x 10^10, log10 Pow of >10.0, using the HPLC method, designed to be compatible with Method A.8 Partition Coefficient of Commission Regulation (EC) No 440/2008 of 30 May 2008 and Method 117 of the OECD Guidelines for Testing of Chemicals, 13 April 2004.

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2017
Report date:
2017

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.3 (Relative Density)
Deviations:
no
Qualifier:
according to guideline
Guideline:
OECD Guideline 109 (Density of Liquids and Solids)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
pycnometer method

Test material

Constituent 1
Reference substance name:
Fatty acids, C16-18-UNSATD., trimers, tris(16-Methylheptadecyl) esters
EC Number:
600-407-9
Cas Number:
103213-22-5
IUPAC Name:
Fatty acids, C16-18-UNSATD., trimers, tris(16-Methylheptadecyl) esters
Test material form:
liquid
Specific details on test material used for the study:
SOURCE OF TEST MATERIAL
- Source and lot/batch No. of test material: CBI
- Expiration date of the lot/batch: 10 June 2018

STABILITY AND STORAGE CONDITIONS OF TEST MATERIAL
- Storage condition of test material: Room temperature, in the dark
Dynamic viscosity of test material:
Purified water with a resistivity of greater than 15MΩ.

Results and discussion

Density
Key result
Type:
relative density
Density:
0.893
Temp.:
20 °C

Any other information on results incl. tables

Measurement Determination
1 2
Mass of pycnometer (g) 17.3512 17.0608
Mass of pycnometer and purified water at 20.2 °C (g) 27.5639 27.2288
Mass of pycnometer and test item at 20.2 °C (g) 26.4855 26.1613
Density of water at 20.2 °C (kg/m3) 998.20
Density (kg/m3) 893 893
Mean density : 893 kg/m3
Mean relative density : 0.893
Temperature : 20.0 ± 0.5 °C

Applicant's summary and conclusion

Conclusions:
The density of the test item has been determined to be 893 kg/m3 at 20.0 ± 2.0 °C and a relative density of 0.893.
Executive summary:

The test substance density was determined to be 893 kg/m3 at 20.0 ± 2.0 °C, relative density of 0.893, by gas comparison pycnometer, designed to be compatible with Method A.3 Relative Density of Commission Regulation (EC) No 440/2008 of 30 May 2008 and Method 109 of the OECD Guidelines for Testing of Chemicals, 02 October 2012.