Registration Dossier

Administrative data

First-aid measures

General advice
- Show the safety data sheet to the doctor in attendance.
- First aider needs to protect himself.
- Place affected clothing in a sealed bag for subsequent decontamination.

In case of inhalation
- If inhaled, remove to fresh air.
- Get immediate medical advice/ attention.

In case of skin contact
- Take off contaminated clothing and shoes immediately.
- Wash off with soap and water.
- Wash immediately and thoroughly for a prolonged period (at least 15 minutes).
- Get immediate medical advice/ attention.

In case of eye contact
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- Get immediate medical advice/ attention.

In case of ingestion
- Do NOT induce vomiting.
- Do not give anything to drink.
- Obtain medical attention.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media
- All extinguishing agents can be used.
- Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
- None known.

Special hazards arising from the substance or mixture
- Aqueous solution causes burns of eyes, skin and mucous membranes.
- Under fire conditions:
- Corrosive or suffocating vapours are released.
- Dense white fumes are given off which may obscure the area.

Advice for firefighters
Special protective equipment for firefighters
- Full protective suit
- In the event of fire, wear self-contained breathing apparatus.

Specific fire fighting methods
- Avoid release to the environment.
- Evacuate personnel to safe areas.
- Do not inhale fumes.
Further information
- Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
- Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
- Avoid contact with eyes, skin and respiratory system.
- Wear suitable protective equipment.
- Personal protective equipment
- Complete suit protecting against chemicals
- Eye/face protection

Environmental precautions
- Do not allow uncontrolled discharge of product into the environment.
- Contain the spilled material by bunding.

Methods and materials for containment and cleaning up
Prohibition
- The product should not be allowed to enter drains, water courses or the soil.
Recovery
- Recover as much of the product as possible.
- Keep in suitable, closed containers for disposal.
- Keep in properly labelled containers.
- corrosion-resistant.
Decontamination/cleaning
- Wash non-recoverable remainder with large amounts of water.
- Recover the cleaning water for subsequent disposal.
Disposal
- Dispose of wastes in an approved waste disposal facility.

Handling and storage

Precautions for safe handling
- Handle in accordance with good industrial hygiene and safety practice.
- Do NOT handle without gloves.
- Provide adequate ventilation.
Hygiene measures
- Emergency equipment immediately accessible, with instructions for use.
- Ensure that eyewash stations and safety showers are close to the workstation location.
- Use clean, well-maintained personal protection equipment.
- Store personal protection equipment in a clean location away from the work area.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Contaminated work clothing should not be allowed out of the workplace.
- The user is responsible for monitoring the working environment in accordance with local laws and regulations.

Conditions for safe storage, including any incompatibilities
Technical measures/Storage conditions
- Store in original container.
- Keep tightly closed.
- Keep in a dry, cool and well-ventilated place.
- Keep in an area equipped with alkali resistant flooring.

- Take all necessary measures to avoid accidental discharge of products into drains and waterways due to the rupture of containers or transfer systems.

- Keep away from: Strong oxidizing agents

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN 3263
Shipping information
Proper shipping name and description:
CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (2,5-dihydroxy-3,6-dimethyl-3,6-bis(dihydroxyphosphinyl)-1,4,2,5-dioxadiphosphorinane-2,5-dioxide, hexasodium salt)
Labels:
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Inland waterway transport (UN RTDG/ADN(R))

UN number:
UN 3263
Shipping information
Proper shipping name and description:
CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (2,5-dihydroxy-3,6-dimethyl-3,6-bis(dihydroxyphosphinyl)-1,4,2,5-dioxadiphosphorinane-2,5-dioxide, hexasodium salt)
Labels:
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Marine transport (UN RTDG/IMDG)

UN number:
UN 3263
Shipping information
Proper shipping name and description:
CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (2,5-dihydroxy-3,6-dimethyl-3,6-bis(dihydroxyphosphinyl)-1,4,2,5-dioxadiphosphorinane-2,5-dioxide, hexasodium salt)
Labels:
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Air transport (UN RTDG/ICAO/IATA)

UN number:
UN 3263
Shipping information
Proper shipping name and description:
CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (2,5-dihydroxy-3,6-dimethyl-3,6-bis(dihydroxyphosphinyl)-1,4,2,5-dioxadiphosphorinane-2,5-dioxide, hexasodium salt)
Labels:
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Exposure controls / personal protection

Control parameters

- Contains no substances with occupational exposure limit values.

Exposure controls
Individual protection measures
Respiratory protection
- Respirator with a particle filter (EN 143)

Hand protection
- The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
- Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time.
- Gloves must be inspected prior to use.

Suitable material
- PVC or other plastic material gloves

Eye protection
- Safety goggles

Skin and body protection
- Choose body protection according to the amount and concentration of the dangerous substance at the work place.
- Remove and wash contaminated clothing.

Hygiene measures
- Emergency equipment immediately accessible, with instructions for use.
- Ensure that eyewash stations and safety showers are close to the workstation location.
- Use clean, well-maintained personal protection equipment.
- Store personal protection equipment in a clean location away from the work area.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Contaminated work clothing should not be allowed out of the workplace.
- The user is responsible for monitoring the working environment in accordance with local laws and regulations.

Protective measures
- The protective equipment must be selected in accordance with current CEN standards and in cooperation with the supplier of the protective equipment.
- Selection of appropriate personal protective equipment should be based on an evaluation of the performance characteristics of the protective equipment relative to the task(s) to be performed, conditions present, duration of use, and the potential hazards and/or risks that may occur during use.

Environmental exposure controls
- Do not allow uncontrolled discharge of product into the environment.
- Contain the spilled material by bunding.
- Treat recovered material as described in the section "Disposal considerations".

Stability and reactivity

Reactivity
- Stable at normal ambient temperature and pressure.
Chemical stability
- Stable under recommended storage conditions.
Possibility of hazardous reactions
- None known.
Conditions to avoid
- 200°C
- May decompose:
- on heating
Incompatible materials
- Strong oxidizing agents

Hazardous decomposition products
- On combustion or on thermal decomposition (following the evaporation of water) releases:
- toxic and corrosive vapours.
- Oxides of phosphorus
- Phosphorus trihydride (phosphine)
- The phosphine will burn on to phosphorus pentoxide unless there is insufficient fresh air

Disposal considerations

Product Disposal
Prohibition
- Do not dispose of together with household waste.
- Should not be released into the environment.

- Refer to manufacturer/supplier for information on recovery/recycling.
- Dispose of as hazardous waste in compliance with local and national regulations.
- Do NOT put down the drain. Must undergo physico-chemical treatment prior to disposal.

Advice on cleaning and disposal of packaging
- Do not re-use empty containers.
- Dispose of contents/ container to an approved waste disposal plant.

- Dispose of as hazardous waste in compliance with local and national regulations.

- Dispose of in accordance with local regulations.


Measure for waste avoidance or recovery
- Do not dispose of together with household waste.