2-phenylbutyryl chloride

Guidance on Safe Use

First-aid measures

First-aid measures general : Remove person to uncontaminated area.

First-aid measures after inhalation : Assure fresh air breathing. Obtain medical attention if breathing difficulty persists.

First-aid measures after skin contact : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Consult a doctor.

First-aid measures after eye contact : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

First-aid measures after ingestion : Rinse mouth. Do not induce vomiting because of corrosive effects. Get medical advice/attention.

If the person feels unwell : Take medical advice immediately. Place the victim in the recovery position.

Fire-fighting measures

Suitable extinguishing media : Bank fires with firefighting foam. Carbon dioxide (CO2). Powder.

Fire hazard : Under fire conditions, hazardous fumes will be present. carbon oxides (CO and CO2). Hydrochloric acid HCl.

Precautionary measures fire : Do not breathe fumes from fires or vapours from decomposition. Evacuate the danger area.

Firefighting instructions : Fight fire from safe distance and protected location. Use water spray or fog for cooling exposed containers.

Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Selfcontained breathing apparatus.

Other information : Large amounts of the product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters.

Accidental release measures

General measures : Ventilate area. Contain the spilled material by bunding.

Emergency procedures : Evacuate area.

Protective equipment : Wear suitable protective clothing, gloves and eye or face protection. Use self-contained breathing apparatus.

Environmental precautions : Do not discharge into drains or the environment. Dispose of at a licensed waste collection centre.

Methods and material for containment and cleaning up

For containment : Clean up any spills as soon as possible, using an absorbent material to collect it. Dike for recovery or absorb with appropriate material.

Methods for cleaning up : Wash away remainder with plenty of water.

Other information : Use non-corrodable disposal containers.

Handling and storage

This substance is handled under Strictly Controlled Conditions in accordance with the REACH regulation Article 17(3) for on-site isolated intermediate and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site.

Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.

Additional hazards when processed : Vapour exhaust preferably at emission point.

Precautions for safe handling : Do not get in eyes, on skin, or on clothing. Handle carefully. Avoid all unnecessary exposure. Do not breathe gas, fumes, vapour or spray. Use personal protective equipment as required.

Hygiene measures : Take off immediately all contaminated clothing. Do no eat, drink or smoke when using this product. Wash hands and other exposed areas with soap and water before leaving work.

Storage conditions : Keep in a cool, well-ventilated place away from moisture. Store in tightly closed containers.

Heat-ignition : Keep away from heat.

Special rules on packaging : Store in tightly closed packings.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3265

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

Chemical name:

2-phenylbutyryl chloride

Labels:

8

Special provisions / remarks

Special provisions:

Hazard identification number (Kemler No.) : 80
Classification code (ADR) : C3
Tunnel restriction code : E
LQ : LQ07
Excepted quantities (ADR) : E1
EAC code : 2X

Inland waterway transport (UN RTDG/ADN(R))

UN number:

3265

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

Chemical name:

2-phenylbutyryl chloride

Labels:

8

Special provisions / remarks

Remarks:

Hazard identification number (Kemler No.) : 80
Classification code (ADR) : C3
Tunnel restriction code : E
LQ : LQ07
Excepted quantities (ADR) : E1
EAC code : 2X

Marine transport (UN RTDG/IMDG)

UN number:

3265

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

Chemical name:

2-phenylbutyryl chloride

Labels:

8

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

3265

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

Chemical name:

2-phenylbutyryl chloride

Labels:

8

Special provisions / remarks

Remarks:

Instruction "cargo" (ICAO) : 856
Instruction "passenger" (ICAO) : 852
Instruction "passenger" - Limited quantities (ICAO) : Y841

SpecialProvisions

Exposure controls / personal protection

This substance is handled under Strictly Controlled Conditions in accordance with the REACH regulation Article 17(3) for on-site isolated intermediate and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site.

Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.

Hand protection : Wear suitable gloves resistant to chemical penetration. Nitrile-rubber protective gloves, (to European standard EN 374 or equivalent).

Eye protection : Wear tight fitting safety glasses or facial screen. Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure.

Skin and body protection : Wear suitable protective clothing. In case of repeated or prolonged exposure : Impervious protective suit with gloves, boots, and full head and face protection must be worn.

Respiratory protection : Provide good ventilation in process area to prevent formation of vapour. Where excessive vapour may result, wear approved mask : gas mask with filter type A2B2.

Other information : Emergency safety showers should be available in the immediate vicinity of any potential exposure. (to European standard EN 15154 or equivalent).

Stability and reactivity

Reactivity : No additional information available

Chemical stability : Stable under normal conditions of use.

Possibility of hazardous reactions : No additional information available

Conditions to avoid : Heat. Moisture.

Incompatible materials : Strong oxidizing agents.

Hazardous decomposition products : Carbon oxides (CO, CO2). Hydrochloric acid HCl.

Disposal considerations

Regional legislation (waste) : Dispose in a safe manner in accordance with local/national regulations.

Waste treatment methods : Dispose of this material and its container at hazardous or special waste collection point. Do not empty into drains.