Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Endpoint summary

Administrative data

Description of key information

Additional information

Environmental fate (hydrogen chloride and hydrochloric acid):

Hydrogen chloride gas for the production of hydrochloric acid (the only non-intermediate use of the gas covered by this dossier), even if not an intermediate in the sense of REACH, is nevertheless produced, transported and used in a completely closed system under strictly controlled conditions (see exposure scenario ES1 and ES2). HCl gas will either react away with hydroxyl radicals or will , in contact with moisture in air, soil or biological media , immediately dissociate to form hydrochloric acid (ref x[1]). Accidently escaped gas will thus mostly precipitate as diluted hydrochloric acid to water or soil. Therefore, the environmental fate of accidently escaped HCl gas is basically identical to the fate of hydrochloric acid in water or soil.   

 

Production methods and/or Conditions for safe use and/or Exposure scenarios

Hydrogen chloride gas for the production of hydrochloric acid (the only non-intermediate use of the gas covered by this dossier), even if not an intermediate in the sense of REACH, is nevertheless produced, transported and used in an integrated, completely closed system under strictly controlled conditions.

Therefore, in the absence of exposure and/or environmental emission potential (other than accidental) no separate risk assessment is deemed necessary for this use up to and including the point where the gas is absorbed in water to form hydrochloric acid. (See exposure scenarios for production of HCl and Production of hydrochloric acid).


[1] Ref x: [Organisation for Economic Cooperation and Development (OECD); Screening Information Data Set (SIDS) for Hydrogen Chloride, CAS # 7647-01-0, p. 4-5 (2002). http://www.inchem.org/documents/sids/sids/7647010.pdf **PEER REVIEWED** 


Environmental fate and pathways

According to the OECD SIDS 2002 Hydrogen chloride SIAR:

Hydrogen chloride is readily dissociated in water into hydrated protons and chloride ion.

The physico-chemical properties indicate that hydrogen chloride released into the environment is distributed into the air and water.

Hydrogen chloride can react with hydroxyl radicals to form chloride free radicals and water and its half-life time is calculated as 11 days. No accumulation of hydrogen chloride per se in living organisms is expected due to its high solubility and dissociation properties.

The hazard of hydrochloric acid for the environment is caused by the proton (pH effect). For this reason the effect of hydrochloric acid on the organisms depends on the buffer capacity of the aquatic ecosystem. Also the variation in acute toxicity for aquatic organisms can be explained for a significant extent by the variation in buffer capacity of the test medium.