Sulfite liquors and Cooking liquors, green

GHS

General Information

Implementation:

EU

Type of classification:

self-classification

Remarks:

The specific concentration limits in this classification apply to sulfide (S^2-) contents Conc. ≥ 21 % sulfide % (wt.) in Green liquor (in dry solids and in mixtures with water).

Related composition

Related composition:

Green liquor, Sameness range composition 001a (dry solids)

Green liquor, Company specific composition

Classification

Physical hazards

Explosives

Reason for no classification:

data conclusive but not sufficient for classification

Flammable gases and chemically unstable gases

Reason for no classification:

data conclusive but not sufficient for classification

Aerosols

Reason for no classification:

data conclusive but not sufficient for classification

Reason for no classification:

hazard class not assessed

Oxidising gases

Reason for no classification:

data conclusive but not sufficient for classification

Gases under pressure

Reason for no classification:

data conclusive but not sufficient for classification

Flammable liquids

Reason for no classification:

data conclusive but not sufficient for classification

Flammable solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-reactive substances and mixtures

Reason for no classification:

data conclusive but not sufficient for classification

Pyrophoric liquids

Reason for no classification:

data conclusive but not sufficient for classification

Pyrophoric solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-heating substances and mixtures

Reason for no classification:

data conclusive but not sufficient for classification

Substances and mixtures which in contact with water emit flammable gases

Reason for no classification:

data conclusive but not sufficient for classification

Oxidising liquids

Reason for no classification:

data conclusive but not sufficient for classification

Oxidising solids

Reason for no classification:

data conclusive but not sufficient for classification

Organic peroxides

Reason for no classification:

data conclusive but not sufficient for classification

Corrosive to metals

Hazard category:

Met. Corr. 1

Hazard statement:

H290: May be corrosive to metals.

Desensitized explosives

Reason for no classification:

data lacking

Health hazards

Acute toxicity - oral

Hazard category:

Acute Tox. 3

Hazard statement:

H301: Toxic if swallowed.

Acute toxicity - dermal

Hazard category:

Acute Tox. 3

Hazard statement:

H311: Toxic in contact with skin.

Acute toxicity - inhalation

Reason for no classification:

data conclusive but not sufficient for classification

Skin corrosion / irritation

Hazard category:

Skin Corr. 1A

Hazard statement:

H314: Causes severe skin burns and eye damage.

Serious eye damage / eye irritation

Reason for no classification:

data conclusive but not sufficient for classification

Respiratory sensitisation

Reason for no classification:

data lacking

Skin sensitisation

Reason for no classification:

data conclusive but not sufficient for classification

Aspiration hazard

Reason for no classification:

data conclusive but not sufficient for classification

Reproductive toxicity

Reason for no classification:

data conclusive but not sufficient for classification

Effects on or via lactation

Reason for no classification:

data lacking

Germ cell mutagenicity

Reason for no classification:

data lacking

Carcinogenicity

Reason for no classification:

data lacking

1. Specific target organ toxicity - single (STOT-SE)

Reason for no classification:

data conclusive but not sufficient for classification

1. Specific target organ toxicity - repeated (STOT-RE)

Reason for no classification:

data conclusive but not sufficient for classification

Environmental hazards

Hazardous to the aquatic environment (acute / short-term)

Hazard category:

Aquatic Acute 1

Hazard statement:

H400: Very toxic to aquatic life.

Hazardous to the aquatic environment (long-term)

Reason for no classification:

data inconclusive

M-Factor acute:

1

Hazardous to the ozone layer

Reason for no classification:

data conclusive but not sufficient for classification

Additional hazard classes

Additional hazard classes:

GHS06: skull and crossbones
Supplementary hazard information due to liberation of very toxic hydrogen sulfide gas if in contact with acids.

Additional hazard statements:

EUH032: Contact with acids liberates very toxic gas

Labelling

Signal word:

Danger

Hazard pictogram

GHS05: corrosion

GHS06: skull and crossbones

GHS09: environment

Hazard statements

H290: May be corrosive to metals.

H301+H311: Toxic if swallowed or in contact with skin.

H314: Causes severe skin burns and eye damage.

H400: Very toxic to aquatic life.

Precautionary statements

P260: Do not breathe dust/fume/gas/mist/vapours/spray.

P264: Wash ... thoroughly after handling.

P270: Do not eat, drink or smoke when using this product.

P271: Use only outdoors or in a well-ventilated area.

P273: Avoid release to the environment.

P280: Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310: Immediately call a POISON CENTER/doctor/…

P363: Wash contaminated clothing before reuse.

P390: Absorb spillage to prevent material damage.

P391: Collect spillage.

P406: Store in a corrosion resistant/... container with a resistant inner liner.

P501: Dispose of contents/container to ...

Manufacturer/supplier to specify proper methods of disposal in SDS/ES

Additional labelling requirements

EUH032: Contact with acids liberates very toxic gas.