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Classification & Labelling & PBT assessment

GHS

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General Information

Implementation:
EU
Type of classification:
harmonised classification
Remarks:

INDEX NR: 014-001-00-9

The Committee for Risk Assessment (RAC) adopted a new harmonised classification for trichlorosilane on 11th June 2020. Once agreed by the European Commission the new Annex VI entry to Regulation (ECO No 1272/2008 will be:

Flam. Liq. 1 (H224)

Water-react. 1 (H260)

Acute Tox. 3 (H331)

Acute Tox. 4 (H302)

Skin Corr. 1A (H314)

Eye Dam. 1 (H318)

With additional H-phrases:

EUH014

EUH029

EUH071

Related composition

Related composition:
Trichlorosilane
trichlorosilane

Classificationopen allclose all

Explosives
Reason for no classification:
data conclusive but not sufficient for classification
Flammable gases and chemically unstable gases
Reason for no classification:
data conclusive but not sufficient for classification
Aerosols
Reason for no classification:
data conclusive but not sufficient for classification
Reason for no classification:
hazard class not assessed
Oxidising gases
Reason for no classification:
data conclusive but not sufficient for classification
Gases under pressure
Reason for no classification:
data conclusive but not sufficient for classification
Flammable liquids
Hazard category:
Flam. Liquid 1
Hazard statement:
H224: Extremely flammable liquid and vapour.
Flammable solids
Reason for no classification:
data conclusive but not sufficient for classification
Self-reactive substances and mixtures
Reason for no classification:
data conclusive but not sufficient for classification
Pyrophoric liquids
Hazard category:
Pyr. Liquid 1
Hazard statement:
H250: Catches fire spontaneously if exposed to air.
Pyrophoric solids
Reason for no classification:
data conclusive but not sufficient for classification
Self-heating substances and mixtures
Reason for no classification:
data conclusive but not sufficient for classification
Substances and mixtures which in contact with water emit flammable gases
Reason for no classification:
data conclusive but not sufficient for classification
Oxidising liquids
Reason for no classification:
data conclusive but not sufficient for classification
Oxidising solids
Reason for no classification:
data conclusive but not sufficient for classification
Organic peroxides
Reason for no classification:
data conclusive but not sufficient for classification
Corrosive to metals
Reason for no classification:
data conclusive but not sufficient for classification
Desensitized explosives
Reason for no classification:
data lacking
Acute toxicity - oral
Hazard category:
Acute Tox. 4
Hazard statement:
H302: Harmful if swallowed.
Acute toxicity - dermal
Reason for no classification:
data conclusive but not sufficient for classification
Acute toxicity - inhalation
Hazard category:
Acute Tox. 4
Hazard statement:
H332: Harmful if inhaled.
Skin corrosion / irritation
Hazard category:
Skin Corr. 1A
Hazard statement:
H314: Causes severe skin burns and eye damage.
Serious eye damage / eye irritation
Reason for no classification:
data conclusive but not sufficient for classification
Respiratory sensitisation
Reason for no classification:
data conclusive but not sufficient for classification
Skin sensitisation
Reason for no classification:
data conclusive but not sufficient for classification
Aspiration hazard
Reason for no classification:
data conclusive but not sufficient for classification
Reproductive toxicity
Reason for no classification:
data conclusive but not sufficient for classification
Effects on or via lactation
Reason for no classification:
data conclusive but not sufficient for classification
Germ cell mutagenicity
Reason for no classification:
data conclusive but not sufficient for classification
Carcinogenicity
Reason for no classification:
data conclusive but not sufficient for classification
1. Specific target organ toxicity - single (STOT-SE)
Reason for no classification:
data conclusive but not sufficient for classification
1. Specific target organ toxicity - repeated (STOT-RE)
Reason for no classification:
data conclusive but not sufficient for classification
1.
Concentration range (%):
>= 1
Hazard categories:
STOT Single Exp. 3
Hazardous to the aquatic environment (acute / short-term)
Reason for no classification:
data conclusive but not sufficient for classification
Hazardous to the aquatic environment (long-term)
Reason for no classification:
data conclusive but not sufficient for classification
Hazardous to the ozone layer
Reason for no classification:
data conclusive but not sufficient for classification
Additional hazard statements:
EUH014
EUH029

Labelling

Signal word:
Danger

Hazard pictogram

GHS02: flame
GHS07: exclamation mark
GHS05: corrosion

Hazard statements

H224: Extremely flammable liquid and vapour.
H250: Catches fire spontaneously if exposed to air.
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H332: Harmful if inhaled.

Additional labelling requirements

EUH014: Reacts violently with water.
EUH029: Contact with water liberates toxic gas.

Notes

Note T