Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General advice :
Move out of dangerous area.
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Treat symptomatically.
Get medical attention if symptoms occur.

If inhaled :
If inhaled, remove to fresh air.
Get medical attention if symptoms occur.

In case of skin contact :
Immediate medical treatment is necessary as untreated
wounds from corrosion of the skin heal slowly and with difficulty.
If on skin, rinse well with water.
If on clothes, remove clothes.

In case of eye contact :
Small amounts splashed into eyes can cause irreversible
tissue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

If swallowed :
Keep respiratory tract clear.
Do NOT induce vomiting.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Take victim immediately to hospital.

Fire-fighting measures

Suitable extinguishing media :
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media :
High volume water jet

Specific hazards during firefighting :
Do not allow run-off from fire fighting to enter drains or water courses.

Hazardous combustion products :
No hazardous combustion products are known

Special protective equipment for firefighters :
Wear self-contained breathing apparatus for firefighting if necessary.

Specific extinguishing methods :
No data is available on the product itself.

Further information :
Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Accidental release measures

Personal precautions :
Use personal protective equipment.

Environmental precautions :
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform respective authorities.

Methods for cleaning up :
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

Handling and storage

Advice on safe handling :
Do not breathe vapours/dust.
Avoid contact with skin and eyes.
Smoking, eating and drinking should be prohibited in the application area.
To avoid spills during handling keep bottle on a metal tray.
Dispose of rinse water in accordance with local and national regulations.

Advice on protection against fire and explosion :
Normal measures for preventive fire protection.

Hygiene measures :
When using do not eat or drink. When using do not smoke.
Wash hands before breaks and at the end of workday.

Requirements for storage areas and containers :
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Keep in properly labelled containers.

Recommended storage temperature :
2 - 40 °C

Further information on storage stability :
Stable under normal conditions.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN 2735

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Marine transport (UN RTDG/IMDG)

UN number:
UN2735
Shipping information
Proper shipping name and description:
AMINES, LIQUID, CORROSIVE, N.O.S.
Chemical name:
(POLYOXYPROPYLENEDIAMINE)
Labels:
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Air transport (UN RTDG/ICAO/IATA)

UN number:
UN2735
Shipping information
Proper shipping name and description:
AMINES, LIQUID, CORROSIVE, N.O.S.
Chemical name:
(POLYOXYPROPYLENEDIAMINE)
Labels:
8
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Exposure controls / personal protection

Eye protection :
Eye wash bottle with pure water
Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing problems.

Hand protection
Material : butyl-rubber
Break through time : > 8 h

Material : Nitrile rubber
Break through time : > 480 min
Glove thickness : 0,85 mm

Material : PVC
Break through time : 230 min

Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves.

Skin and body protection :
Impervious clothing
Choose body protection according to the amount and concentration of the dangerous substance at the work place.

Respiratory protection :
No personal respiratory protective equipment normally required

Stability and reactivity

Reactivity :
No dangerous reaction known under conditions of normal use.

Chemical stability :
Stable under normal conditions.

Hazardous reactions :
No hazards to be specially mentioned.

Conditions to avoid :
None known.

Materials to avoid :
None known.

Hazardous decomposition products :
Ammonia
Carbon monoxide
Carbon dioxide (CO2)
Aldehydes
Ketones
Nitrogen oxides (NOx)

Disposal considerations

Product :
The product should not be allowed to enter drains, water courses or the soil.
Do not contaminate ponds, waterways or ditches with chemical or used container.
Send to a licensed waste management company.
Dispose of as hazardous waste in compliance with local and national regulations.
Dispose of contents/ container to an approved waste disposal plant.

Contaminated packaging :
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.