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Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

4.1 Description of first aid measures
General advice
:
Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled
:
If symptoms persist, call a physician.
If unconscious, place in recovery position and get medical attention immediately.
In case of eye contact
:
Remove contact lenses.
Flush eyes with water as a precaution.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed
:
Induce vomiting immediately and call a physician.
Keep respiratory tract clear.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Take victim immediately to hospital.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms
:
Inhalation may provoke the following symptoms:
Shortness of breath
Asthma
Ingestion may provoke the following symptoms:
Stomach/intestinal disorders

Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media
:
Use extinguishing measures that are appropriate to local cir-cumstances and the surrounding environment.
Unsuitable extinguishing media
:
High volume water jet
5.2 Special hazards arising from the substance or mixture
Specific hazards during fire-fighting
:
Stibine may evolve under reducing conditions (such as con-tact with strong acids or alkalis in the presence of a metal) or in the presence of nascent hydrogen.
Stibine is a colourless, bad smelling gas, highly toxic similar to arsine.
Do not allow run-off from fire fighting to enter drains or water courses.
Hazardous combustion prod-ucts
:
Metal oxides
5.3 Advice for firefighters
Special protective equipment for firefighters
:
Wear self-contained breathing apparatus for firefighting if nec-essary.
Further information
:
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions
:
Use personal protective equipment.
Avoid dust formation.
Avoid breathing dust.
6.2 Environmental precautions
Environmental precautions
:
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform respective authorities.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
:
Keep in suitable, closed containers for disposal.

Handling and storage

7.1 Precautions for safe handling
Advice on safe handling
:
Avoid formation of respirable particles.
Do not breathe vapours/dust.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-plication area.
Dispose of rinse water in accordance with local and national regulations.
Advice on protection against fire and explosion
:
Avoid dust formation. Provide appropriate exhaust ventilation at places where dust is formed.
Hygiene measures
:
When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
:
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully re-sealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. To maintain product quality, do not store in heat or direct sunlight.
Other data
:
Keep in a dry place. No decomposition if stored and applied as directed.

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

8.1 Control parameters
Occupational Exposure Limits Components CAS-No. Value type (Form of exposure) Control parameters Basis
sodium hexahy-droxoantimonate
33908-66-6
TLV 8 hr
0,5 mg/m3
(antimony)
BE OEL
lead monoxide
1317-36-8
TWA
0,15 mg/m3
(Lead)
98/24/EC I
Further information
Binding
Biological occupational exposure limits Substance name CAS-No. Control parameters Sampling time Basis
lead monoxide
1317-36-8
Lead (Lead): 0,7 mg/l
(Blood)
98/24/EC II
8.2 Exposure controls
Engineering measures
Handle only in a place equipped with local exhaust (or other appropriate exhaust).
Personal protective equipment
Eye protection
:
Safety glasses with side-shields conforming to EN166
Hand protection
Material
:
PVC
Break through time
:
> 240 min
Glove thickness
:
1,1 mm
Glove length
:
Standard glove type.
Remarks
:
The data about break through time/strength of material is not valid for undissolved solids/dust.
Skin and body protection
:
Dust impervious protective suit
Respiratory protection
:
Suitable mask with particle filter P3 (European Norm 143)
Filter type
:
Particulates type (P)
In the case of dust or aerosol formation use respirator with an approved filter.
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.

Stability and reactivity

10.1 Reactivity
Stable at normal ambient temperature and pressure.
10.2 Chemical stability
No decomposition if stored and applied as directed.
10.3 Possibility of hazardous reactions
Hazardous reactions
:
No decomposition if stored and applied as directed.
10.4 Conditions to avoid
Conditions to avoid
:
None known.
10.5 Incompatible materials
Materials to avoid
:
Alkali metals
Reducing agents
10.6 Hazardous decomposition products
No decomposition if stored normally.

Disposal considerations

13.1 Waste treatment methods
Product
:
The product should not be allowed to enter drains, water courses or the soil.
Dispose of in accordance with the European Directives on waste and hazardous waste.
In accordance with local and national regulations.
Do not contaminate ponds, waterways or ditches with chemi-cal or used container.
According to the European Waste Catalogue, Waste Codes are not product specific, but application specific.
Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.
Send to a licensed waste management company.
Contaminated packaging
:
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.