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EC number: 226-241-3 | CAS number: 5332-73-0
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data

Skin sensitisation
Administrative data
- Endpoint:
- skin sensitisation: in vivo (non-LLNA)
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 21 January 1991 - 7 March 1991
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- comparable to guideline study
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 1 991
- Report date:
- 1991
Materials and methods
Test guideline
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- OECD Guideline 406 (Skin Sensitisation)
- Deviations:
- no
- GLP compliance:
- yes
- Type of study:
- Buehler test
- Justification for non-LLNA method:
- The Murine Local Lymph Node Assay (LLNA) is the first-choice method for in vivo testing according to the REACH Regulation. However, this test was performed before entry into force of the REACH Regulation.
Test material
- Reference substance name:
- 3-methoxypropylamine
- EC Number:
- 226-241-3
- EC Name:
- 3-methoxypropylamine
- Cas Number:
- 5332-73-0
- Molecular formula:
- C4H11NO
- IUPAC Name:
- 3-methoxypropan-1-amine
- Test material form:
- liquid
Constituent 1
- Specific details on test material used for the study:
- - Name of test material (as cited in study report): 6398-24-1, Project #90-018
- Substance type: clear colorless liquid
- Physical state: liquid
- Analytical purity: responsibility of the sponsor
- Stability under test conditions: no apparent change in the physical appearance of the test article during administration
- Storage condition of test material: responsibility of the sponsor
In vivo test system
Test animals
- Species:
- guinea pig
- Strain:
- Hartley
- Sex:
- male/female
- Details on test animals and environmental conditions:
- TEST ANIMALS
- Source: Buckberg Lab Animals, Tomkins Cove, New York
- Weight at study initiation: 300-700 g
- Age at study initiation: no data
- Housing: individually in wire mesh cages
- Diet (e.g. ad libitum): purina guinea pig diet, ad libitum
- Water (e.g. ad libitum): fresh tap water, ad libitum
- Acclimation period: minimum 5 days
ENVIRONMENTAL CONDITIONS
- Temperature (°C): 20 ± 3°C
- Humidity (%): 30-70 %
- Photoperiod (hrs dark / hrs light): 12 hrs dark / 12 hrs light
Study design: in vivo (non-LLNA)
Induction
- Route:
- epicutaneous, occlusive
- Vehicle:
- other: 80% ethanol (inductions) and acetone (challenge)
- Concentration / amount:
- Volume administered: 0.3 ml/dose
Induction: 5.0% (v/v); challenge: 5.0% (v/v)
Challenge
- Route:
- epicutaneous, occlusive
- Vehicle:
- other: 80% ethanol (inductions) and acetone (challenge)
- Concentration / amount:
- Volume administered: 0.3 ml/dose
Induction: 5.0% (v/v); challenge: 5.0% (v/v)
- No. of animals per dose:
- dose range: 8 (4 males, 4 females);
test article: 20 (10 males, 10 females);
positive control: 5 (2 males, 3 females);
negative control: 10 (5 males, 5 females) - Details on study design:
- RANGE FINDING TESTS:
8 animals (4 males, 4 females) were each exposed to 4 concentrations of the test material in either 80% ethanol (test concentrations of 1, 10, 50 and 100%) or acetone (test concentrations of 1.0, 2.5, 5.0 and 10%)
Primary irritation responses were graded after 24h as follows:
0 = no reaction
+ = slighly patchy erythema
1 = slight of confluent or moderate patchy erythema
2 = moderate erythema
3 = severe erythema with/without edema
The highest non-irritatting concentration was that concentration in the vehicle that induced responses not exceeding two + and two 0 grades in the group of 4 animals.
Based upon the results of the dose-range-finding studies and in discussion with the sponsor, the test article was dosed at 5.0% in 80% ethanol for induction and at 5.0% in acetone for challenge.
MAIN STUDY
A. INDUCTION EXPOSURE
- No. of exposures: 3 inductions
- Exposure period: Once a week for three weeks, a total of three six-hour inductions.
- Test groups: test substance in vehicle (80% ethanol)
- Control group: vehicle only
- Site: left shoulder
- Frequency of applications: once a week
- Duration: 6 h
- Concentrations: 5.0%
B. CHALLENGE EXPOSURE
- No. of exposures: 1
- Day(s) of challenge: 14 days after the last induction sensitizing exposure
- Test groups: test substance in vehicle (acetone)
- Control group: vehicle only (left flank), test article (right flank)
- Site: naive site on left side
- Concentrations: 5.0%
- Evaluation (hr after challenge): 24 and 48h
OTHER:
24h after challenge, all animals were depilated with Neet Cream Hair Remover (Whitehall Laboratories, Inc., New York). A minimum of 2h after depilation, test sites were graded. - Challenge controls:
- The negative control group was challenged with vehicle (acetone) on the left flank.
- Positive control substance(s):
- yes
- Remarks:
- 1-chloro-2,4-dinitrobenzene (0.3%)
Results and discussion
- Positive control results:
- A positive response was elicited in the animals receiving the positive control article, 1-chloro-2,4-dinitrobenezen (DNCB)
In vivo (non-LLNA)
Resultsopen allclose all
- Key result
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- test chemical
- Dose level:
- 5.0%
- No. with + reactions:
- 3
- Total no. in group:
- 20
- Clinical observations:
- severity= 0.5
- Key result
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- test chemical
- Dose level:
- 5.0%
- No. with + reactions:
- 6
- Total no. in group:
- 20
- Clinical observations:
- severity= 0.7
- Key result
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- positive control
- Dose level:
- 0.3%
- No. with + reactions:
- 5
- Total no. in group:
- 5
- Clinical observations:
- severity= 3.0
- Key result
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- positive control
- Dose level:
- 0.3%
- No. with + reactions:
- 5
- Total no. in group:
- 5
- Clinical observations:
- severity= 3.0
- Key result
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- negative control
- Dose level:
- vehicle (acetone)
- No. with + reactions:
- 0
- Total no. in group:
- 10
- Clinical observations:
- severity= 0.0
- Key result
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- negative control
- Dose level:
- vehicle (acetone)
- No. with + reactions:
- 0
- Total no. in group:
- 10
- Clinical observations:
- severity= 0.0
- Key result
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- other: naive control
- Dose level:
- 5.0% test article
- No. with + reactions:
- 0
- Total no. in group:
- 10
- Clinical observations:
- severity= 0.1
- Key result
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- other: naive control
- Dose level:
- 5.0% test article
- No. with + reactions:
- 0
- Total no. in group:
- 10
- Clinical observations:
- severity= 0.1
Any other information on results incl. tables
Results dose-range finding test:
Vehicle 80% ethanol: 1.0% dose caused no reaction, 10% dose caused slightly patchy erythema (1/4), slight or confluent or moderate patchy erythema (2/4) and severe erythema (1/4), 50% and 100% doses caused severe erythema.
Vehicle acetone: 1.0% and 2.5% doses caused no reaction, 5.0% dose caused no reaction (1/4) and slightly patchy erythema (3/4), 10% dose caused no reaction (2/4), slightly patchy erythema (1/4) and severe erythema (1/4).
The highest non-irritating dose (max. two animals with slightly patchy erythema) for challenge exposure was chosen to be 5% in acetone. The highest dose to cause mild irritation for induction exposure was chosen to be 5% in 80% ethanol.
Applicant's summary and conclusion
- Interpretation of results:
- Category 1B (indication of skin sensitising potential) based on GHS criteria
- Conclusions:
- Based upon the observations made in the assay, the substance induced and challenged at a 5.0% concentration caused delayed contact hypersensitivity in guinea pigs.
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