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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Endpoint summary

Administrative data

Description of key information

Additional information

The UVCB substance is an inorganic, complex metal containing material.

 

Intermediate B7 - Speiss, Copper

 

Product obtained by liquation during the solidification of molten matte produced  during smelting (under reducing conditions) complex copper ores and complex secondary copper-containing materials. It consists primarily of copper metal and sulphides, and  iron-arsenic  and nickel-antimony intermetallic compounds

 

EC name

Substances covered / synonyms

EC number/

EINECS No.

CASNo.

Speiss, copper*

Copper speiss,

bottom alloy

273-836-9

69029-97-6

 

At room temperature, the substance is a solid.

 

The majority of the available data on physical and chemical properties of the UVCB is taken from the report Liippo, et al, 2010 –a comprehensive study performed on the UVCB to characterize it (physico-chemical and mineralogical properties) in view of the upcoming REACH registrations of copper intermediates by the REACH Copper Consortium.

 

 In particular, a comprehensive chemical and mineralogical characterization of representative samples was performed (and reported under IUCLID 4.23). The study from Liippo et al (Outotec Lab) furthermore includes thermo gravimetric / differential scanning calorimetric (TG/DSC) measurements (under Air flux and Nitrogen atmosphere) that allowed determining melting, oxidation and related thermal stability properties of the UVCB.

The Outotec study included: Chemical assays (Inductively coupled argon plasma optic emission spectrometer, sulphur and carbon analyzes, Measurement of amount of magnetic material), Granulometry, density and specific surface measurements, determination of melting and oxidation temperatures (Thermogravimetry / differential scanning calorimetry), Water solubility tests, Mineralogical characterization (X-ray Diffraction, Optical Microscopy, Scanning Electron Microscopy) and Mineral Quantification. Based on the tests results, the study furthermore includes expert judgements addressing flammable, self-ignition, explosive and oxidising properties of the materials.

 

The selection and collection of the representative samples was made based on expert knowledge and according to standardized sampling protocols developed by the REACH Copper Consortium, an industry joint-venture regrouping major manufacturing and importing companies of the UVCB substance. Details on the sampling approach and the representative samples are reported as supporting information in IUCLID 1.4 and 4.1.

 

The relevant physico-chemical properties of the material (as well as IUCLID sections) are summarised below:

Speiss B7 Speiss, representative (grinded, homogenised & sieved) 09TT02684 09TT03209

Table 1: Summary of the results

ECI Comments / Remarks IUCLID Section Copper speiss
Lab code   09TT02684
State / Colour 4.1 Solid, Grey
Relative Density g/m3 4.4 7.9
Specific surface area 4.5 n.a.
Granulometry, D50, µm 4.5 126
Water solubility 4.8 poor to low (*)
Melting temperature,°C 4.2 403
Oxidation Temperature,°C 4.15 200
Assays / Chemistry 4.23 See table
Mineralogy 4.23 See table
Flammability 4.13 Negative
Self-ignition  4.12 Negative
Explosive properties 4.14 Negative 
Oxidizing properties 4.15 Negative
Relative Density, OECD 109; specific surface area, BET method; water solubility,OECD 105; melting and oxidation temperature TG/DSC analysis

(*) poor in preliminary test, with exception at high loading and shaking over long period.