Registration Dossier
Registration Dossier
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EC number: 221-029-7 | CAS number: 2978-58-7
Explosiveness
Administrative data
- Endpoint:
- explosiveness
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 3 June 2014 to 30 June 2014
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: see 'Remark'
- Remarks:
- Study conducted in compliance with agreed protocols, with no or minor deviations from standard test guidelines and/or minor methodological deficiencies, which do not affect the quality of the relevant results. The study report was conclusive, done to a valid guideline and the study was conducted under GLP conditions.
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 014
- Report date:
- 2014
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.14 (Explosive properties)
- Deviations:
- no
- GLP compliance:
- yes (incl. QA statement)
Test material
- Reference substance name:
- 1,1-dimethylprop-3-ynylamine
- EC Number:
- 221-029-7
- EC Name:
- 1,1-dimethylprop-3-ynylamine
- Cas Number:
- 2978-58-7
- Molecular formula:
- C5H9N
- IUPAC Name:
- 2-methylbut-3-yn-2-amine
- Test material form:
- other: liquid
- Details on test material:
- - Appearance: pale yellow liquid
Constituent 1
Results and discussion
Small-scale preliminary testsopen allclose all
- Parameter:
- other: More sensitive to shock than m-dinitrobenzene
- Remarks:
- migrated information
- Remarks on result:
- negative (not further specified)
- Parameter:
- other: More sensitive to friction than m-dinitrobenzene
- Remarks:
- migrated information
- Remarks on result:
- not measured/tested
- Parameter:
- other: Explosive under influence of flame
- Remarks:
- migrated information
- Remarks on result:
- negative (not further specified)
- Parameter:
- other: Explosive (not specified)
- Remarks:
- migrated information
- Remarks on result:
- not measured/tested
Any other information on results incl. tables
> Thermal Sensitivity (by Diffrential Scanning Calorimetry)
The sample was observed to undergo two exothermic events during the test. The first commenced from 142.4°C and had a heat of decomposition of -16.2 J/g and the second commenced from 192.2°C and had a heat of decomposition of -1643.7 J/g. No further significant energetic activity was noted up to 500°C.
(see graph attached to this study summary).
> Thermal Sensitivity (Koenen Tube)
Mass of sample (g) |
Orifice diameter (mm) |
Time to first ignition (s) |
Explosion |
23.0 |
6 |
28 |
X |
23.0 |
6 |
32 |
X |
23.0 |
6 |
33 |
X |
23.0 |
2 |
29 |
X |
23.0 |
2 |
35 |
X |
23.0 |
2 |
31 |
X |
X = No exposiion (fewer than 3 fractions)
> Mechanical Sensitivity - Shock (by BAM Fallhammer apparatus)
Replicate |
1 |
2 |
3 |
4 |
5 |
6 |
Result |
N |
N |
N |
N |
N |
N |
N = no sign of reaction of decomposition (colour change)
Applicant's summary and conclusion
- Interpretation of results:
- non explosive
- Remarks:
- Migrated information
- Conclusions:
- Under the conditions of the test, the test material was determined to be non-explosive.
- Executive summary:
The explosivity of the test material was determined using thermal sensitivity and mechanical sensitivity tests (shock) in a study performed under GLP conditions and in accordance with the standardised guidelines EU method A.14.
A Koenen test apparatus was used for determination of sensitivity to heat (flame) following a preliminary investigation using differential scanning calorimetry apparatus. Fall hammer apparatus was utilised for determination of sensitivity to shock.
Under the conditions of the test no evidence of explosivity were observed. The test material was therefore determined to be non-explosive.
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