Registration Dossier

Administrative data

First-aid measures

General advice: If potential for exposure exists refer to Section 8 for specific personal protective
equipment.

Skin Contact: Wash skin with plenty of water.

Eye Contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a physician, preferably an ophthalmologist.

Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel.

Most important symptoms and effects, both acute and delayed: Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), no additional symptoms and effects are anticipated.

Indication of immediate medical attention and special treatment needed: No specific antidote. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

Fire-fighting measures

Extinguishing Media: Water. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers.

Hazardous Combustion Products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Sulfur oxides. Nitrogen oxides. Carbon monoxide. Carbon dioxide.

Unusual Fire and Explosion Hazards: Container may rupture from gas generation in a fire situation. Do not permit dust to accumulate. When suspended in air dust can pose an explosion hazard. Minimize ignition sources. If dust layers are exposed to elevated temperatures, spontaneous combustion may occur.

Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Consider feasibility of a controlled burn to minimize environment damage. Foam fire extinguishing system is preferred because uncontrolled water can spread possible contamination. Soak thoroughly with water to cool and prevent re-ignition. Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound from venting safety device or discoloration of the container. Hand held dry chemical or carbon dioxide extinguishers may be used for small fires. Dust explosion hazard may result from forceful application of fire extinguishing agents. Move container from fire area if this is possible without hazard.

Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If protective equipment is not available or not used, fight fire from a protected
location or safe distance.

Accidental release measures

Personal precautions, protective equipment and emergency procedures: Isolate area. Keep unnecessary and unprotected personnel from entering the area. Spilled material may cause a slipping hazard. Use appropriate safety equipment.

Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater.

Methods and materials for containment and cleaning up: Contain spilled material if possible. Small spills: Sweep up. Collect in suitable and properly labeled containers.

Handling and storage

Risk Management Measures: This substance is handled under Strictly Controlled Conditions in accordance with REACH Regulation Article 17(3) for on-site isolated intermediates and ECHA Guidance on Intermediates, version 2-December 2010 (Reference: ECHA-2010-G-17-EN). The substance is synthesised only in one site in the EU, with the Manufacturer and the User being the same legal entity. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at the manufacturing and use site.

General Handling: Avoid contact with eyes. Do not swallow. Avoid breathing dust or mist. Use with adequate ventilation. Wash thoroughly after handling. Keep out of reach of children. No smoking, open flames or sources of ignition in handling and storage area. Good housekeeping and controlling of dusts are necessary for safe handling of product. Keep away from heat, sparks and flame.

Storage: Store in a dry place. Store in original container. Do not store near food, foodstuffs, drugs or potable water supplies.


Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

Risk Management Measures: This substance is handled under Strictly Controlled Conditions in accordance with REACH Regulation Article 17(3) for on-site isolated intermediates and ECHA Guidance on Intermediates, version 2-December 2010 (Reference: ECHA-2010-G-17-EN). The substance is synthesised only in one site in the EU, with the Manufacturer and the User being the same legal entity. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at the manufacturing and use site.

Eye/Face Protection: Use safety glasses (with side shields). Safety glasses (with side shields) should be consistent with EN 166 or equivalent.

Skin Protection: Wear clean, body-covering clothing.

Hand protection: Use gloves chemically resistant to this material when prolonged or frequently repeated contact could occur. Use chemical resistant gloves classified under Standard EN374: Protective gloves against chemicals and micro-organisms. Examples of preferred glove barrier materials include: Neoprene. Nitrile/butadiene rubber (“nitrile” or “NBR”). Polyvinyl chloride (“PVC” or “vinyl”). When prolonged or frequently repeated contact may occur, a glove is recommended to prevent contact with the solid material. NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.

Respiratory Protection: Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or where indicated by your risk assessment process. For most conditions no respiratory protection should be needed; however, if discomfort is experienced, use an approved air-purifying respirator. Use the following CE approved air-purifying respirator: Organic vapor cartridge with a particulate pre-filter, type AP2.

Ingestion: Use good personal hygiene. Do not consume or store food in the work area. Wash hands before smoking or eating.

Ventilation: Use local exhaust ventilation, or other engineering controls to maintain airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, general ventilation should be sufficient for most operations. Local exhaust ventilation may be necessary for some operations.

Stability and reactivity

Reactivity: No dangerous reaction known under conditions of normal use.

Chemical stability: Stable under recommended storage conditions. See Storage, Section 7.

Possibility of hazardous reactions: Polymerization will not occur.

Conditions to Avoid: Exposure to elevated temperatures can cause product to decompose. Generation of gas during decomposition can cause pressure in closed systems.

Incompatible Materials: Avoid contact with oxidizing materials.

Hazardous decomposition products: Decomposition products depend upon temperature, air supply and the presence of other materials. Toxic gases are released during decomposition.

Disposal considerations

Waste treatment methods: If wastes and/or containers cannot be disposed of according to the product label directions, disposal of this material must be in accordance with your local or area regulatory authorities. This information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. If the material as supplied becomes a waste, follow all applicable regional, national and local laws.