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EC number: 286-924-7 | CAS number: 85392-65-0
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Oxidising properties
Administrative data
Link to relevant study record(s)
- Endpoint:
- oxidising solids
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 4 October 2010 to 21 December 2010
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- UN Manual of Tests and Criteria: Test O.1 (Test for oxidizing solids)
- Deviations:
- yes
- Remarks:
- Electrical resistance of ignition wire used was 3.9 Ω/m.
- GLP compliance:
- yes (incl. QA statement)
- Contact with:
- powdered cellulose
- Duration of test (contact time):
- 3 min
- Sample tested:
- 1:1 sample-to-cellulose ratio
- Parameter:
- mean burning time
- Result:
- 0 s
- Remarks on result:
- other: Pale grey smoke, the pile was slightly charred
- Sample tested:
- 4:1 sample-to-cellulose ratio
- Parameter:
- mean burning time
- Result:
- 0 s
- Remarks on result:
- other: Pale grey smoke, no sign of ignition during the 3 minutes the power was applied.
- Sample tested:
- reference: 3:7 mixture potassium bromate + cellulose
- Parameter:
- mean burning time
- Result:
- 136 s
- Remarks on result:
- other: An orange/blue spluttering flame which left dark grey ash
- Interpretation of results:
- GHS criteria not met
- Conclusions:
- Tetraammonium decachloro-mu-oxodiruthenate (4-) is not classified as an oxidising solid in accordance with Regulation (EC) No 1272/2008 of 16 December 2008 on Classification, Labelling and Packaging of Substances and Mixtures.
- Executive summary:
Tremain and Atwal (2011) is a GLP compliant study following UN method O1 and is considered suitable for use as they key study for this endpoint. Tetraammonium decachloro-mu-oxodiruthenate (4-) is not classified as an oxidising solid in accordance with Regulation (EC) No 1272/2008 of 16 December 2008 on Classification, Labelling and Packaging of Substances and Mixtures.
Reference
Results of 3:7 (by mass) reference mixture of potassium bromate and cellulose | |||||
Test Number | Burning Time (s) | Observations | |||
1 | 147 | An orange/blue spluttering flame which left dark grey ash | |||
2 | 139 | An orange/blue spluttering flame which left dark grey ash | |||
3 | 116 | An orange/blue spluttering flame which left dark grey ash | |||
4 | 133 | An orange/blue spluttering flame which left dark grey ash | |||
5 | 145 | An orange/blue spluttering flame which left dark grey ash | |||
Mean burning time: 136 s | |||||
Results of 4:1 (by mass) test item and cellulose mixture | |||||
Test Number | Burning Time (s) | Observations | |||
1 | - | Pale grey smoke, no sign of ignition during the 3 minutes the power was applied | |||
2 | - | Dark grey smoke, no sign of ignition during the 3 minutes the power was applied | |||
3 | - | Dark grey smoke, no sign of ignition during the 3 minutes the power was applied | |||
4 | - | Dark grey smoke, no sign of ignition during the 3 minutes the power was applied | |||
5 | - | Dark grey smoke, no sign of ignition during the 3 minutes the power was applied | |||
Results of 1:1 (by mass) test item and cellulose mixture | |||||
1 | - | Pale grey smoke, the pile was slightly charred | |||
2 | - | Pale grey smoke, the pile was slightly charred | |||
3 | - | Pale grey smoke, the pile was slightly charred | |||
4 | - | Pale grey smoke, the pile was slightly charred | |||
5 | - | Pale grey smoke, the pile was slightly charred | |||
The 4:1 and 1:1 test item:cellulose mixtures did not ignite and burn during the 3 minutes that the power was applied. This indicates that the test item is not an oxidising solid.
Description of key information
Tetraammonium decachloro-mu-oxodiruthenate (4-) is not classified as an oxidising solid in accordance with CLP regulations.
Key value for chemical safety assessment
- Oxidising properties:
- non oxidising
Additional information
Tremain and Atwal (2011) is a GLP compliant study following UN method O.1 and is considered suitable for use as they key study for this endpoint. Tetraammonium decachloro-mu-oxodiruthenate (4-) is not classified as an oxidising solid in accordance with Regulation (EC) No 1272/2008 of 16 December 2008 on Classification, Labelling and Packaging of Substances and Mixtures.
Justification for classification or non-classification
Based on the result of a GLP compliant study following UN method O.1, tetraammonium decachloro-mu-oxodiruthenate (4-) is not classified as a oxidising solids in accordance with CLP regulations.
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