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Physical & Chemical properties

Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
18 March 2018
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Deviations:
not specified
GLP compliance:
not specified
Type of method:
static method
Test no.:
#1
Temp.:
100 °C
Vapour pressure:
375 hPa
Test no.:
#2
Temp.:
75 °C
Vapour pressure:
214 hPa
Test no.:
#3
Temp.:
50 °C
Vapour pressure:
102 hPa
Test no.:
#4
Temp.:
20 °C
Vapour pressure:
40 hPa
Remarks on result:
other: Extrapolated vapour pressure value

Vapour Pressure Results

The sample was a waxy substance so was pre-heated to a liquid (40 °C) enabling it to be charged to the test cell. The test cell was installed into the vessel before applying vacuum to remove the air. The sample was heated at a rate of 5 K.min-1 with stirring and pressure readings taken at 25 °C intervals to 150 °C. The sample appeared to melt between 25-50 °C. The values above 50 °C have been quoted, as representative temperature measurements could not be obtained until all the sample was homogeneous and being stirred adequately. We suspect there was some decomposition at some temperature above 100°C and on completion of the test it was observed that the sample was slightly darker in colour.

Corrections have been made for any residual pad gas remaining in the sample container at the start of the experiment.

Temperature,°C

Vapour Pressure,hPa

50

102

75

214

100

375

These data have been extrapolated to give a vapour pressure of 40 hPa at 20 °C.

Description of key information

Vapour pressure is 40 hPa at 20 °C (EU A.4, static method).

Key value for chemical safety assessment

Vapour pressure:
40 hPa
at the temperature of:
20 °C

Additional information

Result is extrapolated from experimental data at higher temperatures.