Registration Dossier
Registration Dossier
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EC number: 202-393-6 | CAS number: 95-13-6
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
If inhaled
- Remove victim to fresh air and keep at rest in a position comfortable for breathing.
- When breathing is stopped or weak, loosened clothing and respiratory airway is secured, then try artificial respiration.
- Keep warm covering victim with a blanket.
- Get medical attention.
If on skin
- Remove immediately all contaminated clothing and shoes.
- Rinse contacted area with warm or cold water, and wash well with soap.
- If skin irritation or rash occurs: Get medical advice/attention.
- Wash contaminated clothing before reuse.
If in eye
- Immediately flush eyes with clean water for at least 15 minutes.
- Remove contact lenses, if present and easy to do. Continue rinsing.
- Open eyelids well by fingers when rinse the eyes so that all area of the eyeballs and eyelids are rinsed well even a victim tries closing eyes.
- If irritation persists, get immediately medical advice/attention.
If swallowed
- Do not induce vomiting. Move a victim to a medical centre and get treatments.
- Rinse immediately inside the mouth with water.
- If vomiting occurs, try not to enter the airway keeping the body inclined.
Expected acute and delayed effects
- Skin irritation: rush, fester and redness.
- If inhaled vapours: respiratory irritation, causes headache, induces vomiting.
Most serious symptoms and effects
- If in eyes: Causes serious eye irritation.
- If on skin: May cause an allergic skin reaction.
- Causes damage to liver, kidney and spleen through prolonged or repeated exposure.
- May be fatal if swallowed and enters airways.
Protection of first-aiders
- Wear protective equipment which designated by the manufacturer.
- When take first-aid measures, attention not to contact on skin or in eyes.
- Remove victim to fresh air and keep at rest in a position comfortable for breathing.
- When breathing is stopped or weak, loosened clothing and respiratory airway is secured, then try artificial respiration.
- Keep warm covering victim with a blanket.
- Get medical attention.
If on skin
- Remove immediately all contaminated clothing and shoes.
- Rinse contacted area with warm or cold water, and wash well with soap.
- If skin irritation or rash occurs: Get medical advice/attention.
- Wash contaminated clothing before reuse.
If in eye
- Immediately flush eyes with clean water for at least 15 minutes.
- Remove contact lenses, if present and easy to do. Continue rinsing.
- Open eyelids well by fingers when rinse the eyes so that all area of the eyeballs and eyelids are rinsed well even a victim tries closing eyes.
- If irritation persists, get immediately medical advice/attention.
If swallowed
- Do not induce vomiting. Move a victim to a medical centre and get treatments.
- Rinse immediately inside the mouth with water.
- If vomiting occurs, try not to enter the airway keeping the body inclined.
Expected acute and delayed effects
- Skin irritation: rush, fester and redness.
- If inhaled vapours: respiratory irritation, causes headache, induces vomiting.
Most serious symptoms and effects
- If in eyes: Causes serious eye irritation.
- If on skin: May cause an allergic skin reaction.
- Causes damage to liver, kidney and spleen through prolonged or repeated exposure.
- May be fatal if swallowed and enters airways.
Protection of first-aiders
- Wear protective equipment which designated by the manufacturer.
- When take first-aid measures, attention not to contact on skin or in eyes.
Fire-fighting measures
Extinguish agents
- Powder, carbon dioxide, fire foam, dry sand or water spray.
Prohibited agents
- Direct pouring of cylinder shape water.
Special hazardous information
- May produce large amount of dark smoke. Toxic gases, e.g. carbon monoxide may be contained in emitted gases.
- In case of fire, may produce irritating, toxic and/or corrosive gases.
- Containers may be explosive when heated.
Special fire-fighting procedures
- Take action from the windward.
- Since a flash point is very low, spray water if fire-fighting is not effective.
- Move container and place it in a safe area if it is not dangerous. If it is not possible, keep cool by spraying water against the container.
- Continue cooling containers with plenty of water after extinction.
Protection of fire-fighters
- Wear appropriate respiratory devise and protective clothing for chemicals.
- Off-limits around the fire except responsible persons.
- Powder, carbon dioxide, fire foam, dry sand or water spray.
Prohibited agents
- Direct pouring of cylinder shape water.
Special hazardous information
- May produce large amount of dark smoke. Toxic gases, e.g. carbon monoxide may be contained in emitted gases.
- In case of fire, may produce irritating, toxic and/or corrosive gases.
- Containers may be explosive when heated.
Special fire-fighting procedures
- Take action from the windward.
- Since a flash point is very low, spray water if fire-fighting is not effective.
- Move container and place it in a safe area if it is not dangerous. If it is not possible, keep cool by spraying water against the container.
- Continue cooling containers with plenty of water after extinction.
Protection of fire-fighters
- Wear appropriate respiratory devise and protective clothing for chemicals.
- Off-limits around the fire except responsible persons.
Accidental release measures
Human health precaution
- Immediately separate the released area against all directions and an appropriate distance.
- Off-limits around the released area by stretching a rope.
- Wear appropriate protective equipment and avoid contacting on skin or eye, or inhalation of gases.
- Evacuate persons in leeward. Stay in the windward.
- Leave from a lower place.
Environmental precautions
- Attention releasing products into rivers so as to avoid any effects may occur to the environment.
- Avoid releasing contaminated waste water into the environment without appropriate treatment.
Recovery and neutralisation
- Small amount of leakage: Absorbing with sand and recover in an empty container which can be locked up. Use a safety shovels so that sparks do not generate is recommended.
- Large amount of leakage: enclose the leakage with embankment, cover the surface with a fire-form and recover into an empty container which can be locked up. Treat as well as the small amount of leakage.
Methods for cleaning up, devices
- Stop leakage if it is not dangerous.
- Avoid scattering by covering a plastic sheet.
Prevention of secondary hazards
- Cut off immediately any combustion sources (No smoking and avoid sparks or flame).
- Do not pour water into a container.
- Immediately separate the released area against all directions and an appropriate distance.
- Off-limits around the released area by stretching a rope.
- Wear appropriate protective equipment and avoid contacting on skin or eye, or inhalation of gases.
- Evacuate persons in leeward. Stay in the windward.
- Leave from a lower place.
Environmental precautions
- Attention releasing products into rivers so as to avoid any effects may occur to the environment.
- Avoid releasing contaminated waste water into the environment without appropriate treatment.
Recovery and neutralisation
- Small amount of leakage: Absorbing with sand and recover in an empty container which can be locked up. Use a safety shovels so that sparks do not generate is recommended.
- Large amount of leakage: enclose the leakage with embankment, cover the surface with a fire-form and recover into an empty container which can be locked up. Treat as well as the small amount of leakage.
Methods for cleaning up, devices
- Stop leakage if it is not dangerous.
- Avoid scattering by covering a plastic sheet.
Prevention of secondary hazards
- Cut off immediately any combustion sources (No smoking and avoid sparks or flame).
- Do not pour water into a container.
Handling and storage
Handling
Technical measures
- Take facilitation measures described in "EXPOSURE CONTROLS/PERSONAL PROTECTION" and wear protective equipment.
Local/general ventilation
- Take local or overall ventilation described in "EXPOSURE CONTROLS/PERSONAL PROTECTION".
Precautions for safe handling
- Prohibit using any combustion sources e.g. flame, static discharge or sparks close to the handling place.
- Take precautionary measures against static discharge. Wear electro conductive clothing and shoes.
- Avoid leakage of liquid or releasing of vapours as can as possible.
- Use only in outdoor or well-ventilated area.
- Install a local ventilation system where vapours may produce.
- Wear protective clothing if contacting or inhalation is concerned.
- Contaminated work clothing should not be allowed out of the workplace.
- Do not put the substance into eyes.
- Do not touch, inhale or swallow the substance.
- Do not eat, drink or smoke when using this product.
- Wash hands thoroughly after handling.
Storage
Technical measures
- It is suitable to use outside wall, pillars and floor with non-flammable materials to build the storage place so that there is no concerns of spreading fire.
- Storage place should be; roof is built with non-flammable materials, roof is blown with a light material e.g. metal boards, no ceiling is installed.
- Floor in a storage area should avoid flooding or infiltrating.
- Floor in a storage area should avoid infiltrating of dangerous products, set an appropriate inclination and a saving box.
- Install light and ventilation devices in a storage place so that it is necessary to storage and handle dangerous products.
Storage condition
- Store apart from flame, heat and ignition source.
- Store in a cool well ventilated place.
- Store apart from oxidizing agents.
- Avoid direct sunshine or fire.
- Store locked up.
Packaging materials
- Use containers in accordance with the Fire Service Law.
Technical measures
- Take facilitation measures described in "EXPOSURE CONTROLS/PERSONAL PROTECTION" and wear protective equipment.
Local/general ventilation
- Take local or overall ventilation described in "EXPOSURE CONTROLS/PERSONAL PROTECTION".
Precautions for safe handling
- Prohibit using any combustion sources e.g. flame, static discharge or sparks close to the handling place.
- Take precautionary measures against static discharge. Wear electro conductive clothing and shoes.
- Avoid leakage of liquid or releasing of vapours as can as possible.
- Use only in outdoor or well-ventilated area.
- Install a local ventilation system where vapours may produce.
- Wear protective clothing if contacting or inhalation is concerned.
- Contaminated work clothing should not be allowed out of the workplace.
- Do not put the substance into eyes.
- Do not touch, inhale or swallow the substance.
- Do not eat, drink or smoke when using this product.
- Wash hands thoroughly after handling.
Storage
Technical measures
- It is suitable to use outside wall, pillars and floor with non-flammable materials to build the storage place so that there is no concerns of spreading fire.
- Storage place should be; roof is built with non-flammable materials, roof is blown with a light material e.g. metal boards, no ceiling is installed.
- Floor in a storage area should avoid flooding or infiltrating.
- Floor in a storage area should avoid infiltrating of dangerous products, set an appropriate inclination and a saving box.
- Install light and ventilation devices in a storage place so that it is necessary to storage and handle dangerous products.
Storage condition
- Store apart from flame, heat and ignition source.
- Store in a cool well ventilated place.
- Store apart from oxidizing agents.
- Avoid direct sunshine or fire.
- Store locked up.
Packaging materials
- Use containers in accordance with the Fire Service Law.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Engineering measures
- Use explosion-proof electrical/ventilating/lighting equipment.
- Take precautionary measures against static discharge.
- Install eye washer and safety shower near handling and storage area.
- Handle with a closed equipment or device.
- Install local ventilation for indoor use.
Personal protective equipment
Respiratory protection
- Use protective equipment for respiration.
- If exposure is concerned, use hazard mask (for organic chemicals), air-supplied mask, respirator or oxygen respirator.
Hand protection
- Use appropriate protective gloves (oil-proof).
Eye protection
- Use eye protective equipment.
- Wear a goggle for chemical spray or an appropriate face protection.
- Wear safety glasses. If eye or face contact is concerned due to splashing or spray, wear an inclusive chemical splash goggle or face shield.
Skin and body protection
- Wear protective equipment for face.
- Use anti-static discharge apron and boots.
- When splashing, full cover chemical proof protective clothing (e.g. acid suit) and boots is needed.
Hygiene measures
- Do not eat, drink or smoke when using this product.
- Wash hands well with soap after handling.
- Use explosion-proof electrical/ventilating/lighting equipment.
- Take precautionary measures against static discharge.
- Install eye washer and safety shower near handling and storage area.
- Handle with a closed equipment or device.
- Install local ventilation for indoor use.
Personal protective equipment
Respiratory protection
- Use protective equipment for respiration.
- If exposure is concerned, use hazard mask (for organic chemicals), air-supplied mask, respirator or oxygen respirator.
Hand protection
- Use appropriate protective gloves (oil-proof).
Eye protection
- Use eye protective equipment.
- Wear a goggle for chemical spray or an appropriate face protection.
- Wear safety glasses. If eye or face contact is concerned due to splashing or spray, wear an inclusive chemical splash goggle or face shield.
Skin and body protection
- Wear protective equipment for face.
- Use anti-static discharge apron and boots.
- When splashing, full cover chemical proof protective clothing (e.g. acid suit) and boots is needed.
Hygiene measures
- Do not eat, drink or smoke when using this product.
- Wash hands well with soap after handling.
Stability and reactivity
Stability
- Stable under normal handling condition.
Possible hazardous reactions
- May ignite when heating.
- Polymerize when irradiating by light.
- May cause explosion during nitrification with nitric acid and sulphuric acid.
Conditions to avoid
- Keep away from flame or spark generator. Direct sunlight and heat.
Incompatible compounds
- Oxidizing agents
Hazardous decomposition products
- Decompose and generate irritating smoke and gases when heating. Carbon monoxide, carbon dioxide, etc.
- Stable under normal handling condition.
Possible hazardous reactions
- May ignite when heating.
- Polymerize when irradiating by light.
- May cause explosion during nitrification with nitric acid and sulphuric acid.
Conditions to avoid
- Keep away from flame or spark generator. Direct sunlight and heat.
Incompatible compounds
- Oxidizing agents
Hazardous decomposition products
- Decompose and generate irritating smoke and gases when heating. Carbon monoxide, carbon dioxide, etc.
Disposal considerations
Waste from residues
- Follow related regulations and standards of local authorities when disposing.
- Absorb with sawdust, waste, diatomite or absorbing mat, and label contents. Consult a certified waste trader or ask the local authority if they deal with waste.
Contaminated packaging
- Recycle containers after cleaning or dispose appropriately in accordance with laws and local regulations.
- Remove completely remaining products from a container before disposal.
- Follow related regulations and standards of local authorities when disposing.
- Absorb with sawdust, waste, diatomite or absorbing mat, and label contents. Consult a certified waste trader or ask the local authority if they deal with waste.
Contaminated packaging
- Recycle containers after cleaning or dispose appropriately in accordance with laws and local regulations.
- Remove completely remaining products from a container before disposal.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
