Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 947-819-8 | CAS number: -
Vapour pressure
Administrative data
Link to relevant study record(s)
- Endpoint:
- vapour pressure
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 2017
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Qualifier:
- according to guideline
- Guideline:
- OECD Guideline 104 (Vapour Pressure Curve)
- Version / remarks:
- and EU A.4 using the effusion method: Knudsen Cell
- GLP compliance:
- yes (incl. QA statement)
- Type of method:
- effusion method: Knudsen cell
- Specific details on test material used for the study:
- Iodobis(triphenylphospino)copper, BRUGGOLEN® H3301, Batch no. 16101213
Production date 12.10.2016
Expiry date 12.10.2026 - Key result
- Temp.:
- 20 °C
- Vapour pressure:
- 0.001 Pa
- Temp.:
- 25 °C
- Vapour pressure:
- 0.001 Pa
- Conclusions:
- The vapour pressure of the test item Iodobis(triphenylphospino)copper was determined at nine different temperatures (30-150°C) according to OECD 104 resp EU A.4 using the ef-fusion method (weight loss). Experiment 1-4 (nominal temperature 30-75 °C) showed only a poor reproducible weight loss. When visible contaminations, caused by explosive evapo-ration of the test item, were observed, the cells were meticulously cleaned and weighed. This weight was used as initial weight for the subsequent measurements. To avoid bias, these measurements were not used for calculations.
Five experiments could be evaluated as they showed relevant and reproducible weight loss. All evaluated experiments showed good reproducibility, giving relative standard devi-ations of less than 25 % and good correlation.
Therefore, the result of the test can be considered valid. - Executive summary:
The vapour pressure of Iodobis(triphenylphospino)copper was determined according to OECD 104 resp. EU A.4 using the effusion method (weight loss).
Vapour pressure was examined at nine different temperatures. Five temperatures could be evaluated as they showed reproducible weight loss. For these temperatures, 1/T was plot-ted against log (p).
Vapour Pressures (Effusion Method)
Experiment T Mean p Stand. Dev. p RSD p No. K Pa Pa % 5 363.2 1.21E-02 2.59E-03 21.3 6 378.2
1.70E-02
2.64E-03
15.5
7
393.2
2.89E-02
7.13E-03
24.6
8
408.2
4.25E-02
3.59E-03
8.4
9
423.2
6.51E-02
5.45E-03
8.4
In this table, E-0X represents multiplication with 10-x.
Stand. Dev. = Standard Deviation; RSD = Relative Standard Deviation
The graph 1/T vs. log (p) shows a straight line with a correlation coefficient of - 0.9969.
For the test item Iodobis(triphenylphospino)copper, the following vapour pressures at 20 °C and at 25 °C were calculated from the regression equation:
Vapour pressure at 20 °C: 6.46 * 10-04Pa
Vapour pressure at 25 °C: 8.30 * 10-04Pa
Reference
Experimentally Determined Vapour Pressures
| T | T | p | Standard Deviation p | RSD p |
| °C | K | Pa | Pa | % |
| 90.0 | 363.2 | 1.21E-02 | 2.59E-03 | 21.3 |
| 105.0 | 378.2 | 1.70E-02 | 2.64E-03 | 15.5 |
| 120.0 | 393.2 | 2.89E-02 | 7 .13E-03 | 24.6 |
| 135.0 | 408.2 | 4.25E-02 | 3.59E-03 | 8.4 |
| 150.0 | 423.2 | 6.51E-02 | 5.45E-03 | 8.4 |
Description of key information
Vapour pressure at 20 °C: 6.46 * 10-04Pa
Vapour pressure at 25 °C: 8.30 * 10-04Pa
Key value for chemical safety assessment
- Vapour pressure:
- 0.001 Pa
- at the temperature of:
- 20 °C
Additional information
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
