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Diss Factsheets

Physical & Chemical properties

Flash point

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
21 June 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Justification for type of information:
The study was conducted according to an internationally recognised method, and under GLP. The substance is considered to be adequately characterised. Therefore full validation applies.
Reason / purpose for cross-reference:
reference to same study
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Deviations:
no
Qualifier:
according to guideline
Guideline:
EPA OPPTS 830.6315 (Flammability)
Deviations:
no
Qualifier:
according to guideline
Guideline:
ISO 2719 (Determination of flash point - Pensky-Martens closed cup method)
Deviations:
no
Principles of method if other than guideline:
Not applicable
GLP compliance:
yes (incl. QA statement)
Remarks:
inspected on October 13 and 14, 2014 / signed on April 08, 2015
Type of method:
non-equilibrium method closed cup
Key result
Flash point:
ca. 43.5 °C
Atm. press.:
ca. 101 325 Pa

Findings

Determination of the Flash Point

The results of the determinations are presented in the following tables.

Table 4.11/2.- Findings

Program

Expected flash point (setting)

in °C

Flash point (found)
in °C

Mean
in °C

Notes

Search

176

46.6

 

not used for calculation(pre-test)

EN ISO 2719-B

46

43.5

43.5

difference < 2°C

EN ISO 2719-B

46

43.5

 

Evaluation and Result

The flash point is given as the mean value of the duplicate determination. The measured flash point is therefore 43.5°C (corresponding to 316.7 K).

Discussion

Both determinations showed no difference. Therefore, the validity criterion is met and the determination was considered valid.

Interpretation of results:
Category 3 (flammable liquids) based on GHS criteria
Conclusions:
The flash point of test substance is below the classification thresholds of 60°C (CLP criteria) or 93°C (GHS criteria). Therefore the test substance is classified as a flammable liquid.
Executive summary:

The flash point of the test substance was determined under GLP according toEU Method A.9 (Flash-Point), using a non-equilibrium closed cup method (ISO2719 -Part B).

A pre-test and a main test with two experiments were performed using a flashpoint tester.

The flashpoint ofthe test item is stated as 43.5 °C (corresponding to 316.7 K).

This value is the mean value of two independent determinations.

The flash point of test substance is lower than the classification thresholds of 60°C of the Regulation (EC) No. 1272/2008 (CLP criteria) and UN Globally Harmonised System (GHS).

Therefore the test substance is classified as a flammable liquid Category 3 according to CLP criteria and according to UN Globally Harmonised System (GHS).

Description of key information

The flash point of the test item was stated as 43.5°C.

The substance is classified as a FLAMMABLE LIQUID Category 3 according to Regulation (EC) N°1272/2008 (CLP criteria) and UN Globally Harmonized System (GHS criteria).

Note that the result obtained on this kind of substance should be largely influence by small amounts of volatile constituents.

Key value for chemical safety assessment

Flash point at 101 325 Pa:
43.5 °C

Additional information

The flash point of the test substance was determined under GLP according to EU Method A.9 (Flash-Point), using a non-equilibrium closed cup method (ISO2719 -Part B). It is considered as a key study. The result is retained as key data for purpose of CSA.

This study is relevant for the classification regarding flammable properties.