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Diss Factsheets
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EC number: 231-137-6 | CAS number: 7440-27-9
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Guidance on Safe Use
Administrative data
First-aid measures
Get the affected person out in the fresh air and call a doctor.
• After skin contact: Foreign bodies which have penetrated the skin must be removed
and the wound cleaned thoroughly.
Remove contaminated clothing.
If skin irritation continues, consult a doctor.
• After eye contact: Foreign bodies must be removed, consult a doctor if necessary.
Fire-fighting measures
• For safety reasons unsuitable extinguishing agents: Water
Carbon dioxide
• Special hazards caused by the substance, its products of combustion or resulting gases: Can form explosive gas-air mixtures.
• Protective equipment: Wear self-contained respiratory protective device.
Accidental release measures
precautions: Use respiratory protective device against the effects of fumes/dust/aerosol.
• Measures for environmental protection: Do not allow product to reach sewage system or any watercourse.
• Measures for cleaning/collecting: Do not flush with water or aqueous cleansing agents
When cold, sweep it up carefully.
Avoid dust development.
Handling and storage
• Information for safe handling: Keep receptacles tightly sealed.
Prevent formation of dust.
Fill only in inert gas.
Ensure good ventilation/exhaustion at the workplace.
Take note of emission threshold.
• Information about fire - and
explosion protection: Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Inflammable and explosive dust-air mixtures can develop in
combination with air.
• Storage:
• Requirements to be met by
storerooms and receptacles: Containers must be clearly and indelibly identified.
• Information about storage in
one common storage facility: Store away from foodstuffs.
• Further information about
storage conditions: Store in cool, dry conditions in well sealed receptacles.
• Storage class: Comply with on-site storage guidelines for substances able to
heat up spontaneously (pyrophoric).
• Class according to regulation
on flammable liquids: Not applicable
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3189
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Marine transport (UN RTDG/IMDG)
- UN number:
- • Maritime transport IMDG:
• IMDG Class: -
• Marine pollutant: -
• Remarks: Not tested
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- • Air transport ICAO-TI and IATA-DGR:
• ICAO/IATA Class: -
• Remarks: Not tested
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Exposure controls / personal protection
design of technical facilities: Provide a suitable suction with filter and good ventilation of the working area
for all processing steps.
Suitable breathing apparatus must be used (see personal safety equipment) for repair and maintenance
work on suction systems,
especially when changing the filters.
• Ingredients with limit values that require monitoring at the workplace:
7440-48-4 cobalt
ERB (Germany) 0.5 μg/m³ (A) bzw. 5μg/m³ (A)
MAK (Germany) inhalable fraction; see Abschn.XIII
• DNELs
DNELs for OSH purposesIn
Germany, occupational exposure limits (AGW) of the Technical Rules on
Hazardous Substances (TRGS) 900 continue to constitute workplace atmospheric limit values thatare binding upon employers. Should no AGW and for example no maximum workplace concentration (MAK value) of the German Research Foundation (DFG) be available, the employer must also
consider the DNEL during risk assessment.(Source: Institut für Arbeitsschutz der Deutschen Gesetzlichen Unfallversicherung (IFA))current values are available: http://www.dguv.de/ifa/gestis/gestis-dnelliste/index.jsp.
7440-48-4 cobalt
Inhalative Long-term exposure - inhalation - local effects: 0.04 mg/m³ (Ind)
0.0063 mg/m³ (Consumer)
7440-48-4 cobalt
TRGS 905 (see: https://www.baua.de/DE/Angebote/Rechtstexte-und-Technische-Regeln/Regelwerk/
TRGS/pdf/TRGS-905.pdf?__blob=publicationFile)
Cobalt metal ( in form of inhalable dust/aerosole), EC# 231-158-0, CAS# 7440-48-4: Carc. 1B
14th Adaptation to Technical Progress (14th ATP) to the EU CLP Regulation:
Index No: 027-001-00-9
Chemical name: cobalt
EC No: 231-158-0
CAS No: 7440-48-4
Hazard class and Category Code(s): Carc 1B, Muta 2, Repr 1B, Resp Sens 1, Skin Sens 1, AqCh
ronic 4
Hazard Statement Code(s): H350, H341, H360F, H334, H317, H413
Pictogram, Signal Word Code(s): GHS08, Dgr
SCLs, M-factors and ATEs: [Interim GCL for carcinogenicity; 0.1 %]
• Additional Occupational
Exposure Limit Values for possible hazards during processing: Compliance with the general dust limit value(s) (lung penetrating
and/or inhalable fraction) must be ensured.
• Additional information: The lists valid during the making were used as basis.
• Recommended analysis
procedures: cobalt:
- NIOSH, no. 7027
- OSHA, no. ID 121 / ID-125
• Personal protective equipment:
• General protective and
hygienic measures: Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
• Respiratory protection: In the case of dust formation (limit value exceeded),
breathing apparatus must be worn.
Time limits for wearing must be observed.
Breathing mask, apparatus with particle filter P2 or P3,
for example:
- Full face mask (EN 136)
- Breathing mask (EN 149) FFP2 or FFP3
10 times the limit value (FFP2)
30 times the limit value (FFP3)
Recommendation: P3
• Protection of hands: Avoid repeated and prolonged contact with the skin, use
protective gloves.
Preventive skin protection by use of skin-protecting
agents is recommended.
• Material of gloves: Material of gloves should be impenetrable (e.g. nitrile caoutchouc). Depending on
use heat protective gloves are required.
• Penetration time of glove material -
• Eye protection:
Tightly sealed goggles (EN 166)
• Limitation and supervision of
exposure into the environment The legal issue values and limitations are to be paid attention!
Stability and reactivity
conditions to be avoided: It does not degrade if properly used with a protective gas (argon).
Attention:
At high temperatures the substance has an exothermic reaction
in combination with nitrogen.
• Materials to be avoided: Aqueous media (e.g. acid, alkaline solutions, water), substances
with an oxidizing effect
• Dangerous reactions Hydrogen is released when it comes into contact with water, and
explosive gaseous mixtures can develop.
In combination with air or atmospheres with an oxidizing effect
fine powders can develop spontaneous heating or become
pyrophoric.
• Dangerous decomposition
products: No dangerous decomposition products known.
Disposal considerations
• Uncleaned packaging:
• Recommendation: Empty contaminated packagings thoroughly. They may be
recycled after thorough and proper cleaning.
Packagings that may not be cleansed are to be disposed of in
the same manner as the product.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.