Registration Dossier
Registration Dossier
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EC number: 210-890-4 | CAS number: 625-36-5
Guidance on Safe Use
Administrative data
First-aid measures
Immediately remove contaminated clothing. If the patient is likely to become unconscious, place and
transport in stable sideways position (recovery position). First aid personnel should pay attention to
their own safety.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a corticosteroid from a controlled/metered dose inhaler.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Fire-fighting measures
5.1. Extinguishing media
Suitable extinguishing media:
dry powder, carbon dioxide, foam
Unsuitable extinguishing media for safety reasons:
water
5.2. Special hazards arising from the substance or mixture
hydrogen chloride, carbon oxides, nitrogen oxides
The substances/groups of substances mentioned can be released in case of fire.
5.3. Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Fire debris must be disposed of in accordance with offical regulations.
Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Breathing protection required. Avoid contact with the skin, eyes and clothing.
6.2. Environmental precautions
Do not empty into drains.
6.3. Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder,
kieselguhr). Dispose of absorbed material in accordance with regulations.
Handling and storage
7.1. Precautions for safe handling
Protect against moisture.
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should
be kept handy.
7.2. Conditions for safe storage, including any incompatibilities
Suitable materials for containers: glass, High density polyethylene (HDPE)
Further information on storage conditions: Keep container tightly closed and dry; store in a cool
place. Storage at a proportionate temperature is required, to avoid 'breathing' of containers.
Storage stability:
Storage duration: 6 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the
warrantee of application properties can be deduced.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
8.1. Control parameters
Components with occupational exposure limits
625-36-5: 3-Chloropropionyl chloride
8.2. Exposure controls
Personal protective equipment
Respiratory protection:
Self-contained breathing apparatus.
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
butyl rubber (butyl) - 0.7 mm coating thickness
fluoroelastomer (FKM) - 0.7 mm coating thickness
Suitable materials short-term contact and/or splashes (recommended: At least protective index 2,
corresponding > 30 minutes of permeation time according to EN 374)
chloroprene rubber (CR) - 0.5 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).
General safety and hygiene measures
Avoid contact with the skin, eyes and clothing. Do not breathe vapour/spray.
Stability and reactivity
10.1. Reactivity
Corrosion to metals: Corrosive effect on metals.
Reactions with
water/air:
Reaction with: air
Flammable gases: yes
Which flammable gases: When heated can give off ignitable
vapours., Gaseous hydrocarbons
that may form explosive mixture
with air; hydrogen chloride
formation., See user defined text.
Reaction with: water
Flammable gases: no
Toxic gases: yes
Which toxic gases: hydrogen chloride (HCl)
Corrosive gases: yes
Which corrosive gases: hydrogen chloride (HCl)
Smoke or fog: yes
Type of smoke or fog: Hydrochloric acid
Which Peroxides:
Formation of
flammable gases:
Remarks: Forms no flammable gases in the
presence of water.
10.2. Chemical stability
The product is stable if stored and handled as prescribed/indicated.
10.3. Possibility of hazardous reactions
Evolution of corrosive gases/vapours. Reacts with water and basic components to generate heat. On
contact with water, gaseous decomposition products are formed, which cause build-up of pressure in
tightly closed containers. Reacts with alcohols, amines, aqueous acids and alkalies. Reacts with
water and moisture, with formation of hydrogen chloride. Partly very violent reactions with bases and
numerous organic classes of substances such as alcohols and amines. Addition of water leads to
increase in temperature. Vapours may form ignitable mixture with air. Substance/product is highly
reactive. In damp air hydrochloric acid formation is possible. Violent reactions with water and/or
alcohols, with formation of hydrochloric acid. Violent and explosive reaction with water.
10.4. Conditions to avoid
Avoid electro-static charge. Avoid humidity. Avoid heat. Avoid prolonged storage. Disregard of the
conditions mentioned may result in undesirable decomposition reactions.
10.5. Incompatible materials
Substances to avoid:
alkaline reactive substances, alcohols, bases, amines, water
10.6. Hazardous decomposition products
Hazardous decomposition products:
hydrogen chloride
Disposal considerations
13.1. Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to
dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in
cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for
recycling after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
