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EC number: 682-238-0 | CAS number: 1190931-27-1
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Oxidising properties
Administrative data
Link to relevant study record(s)
- Endpoint:
- oxidising solids
- Type of information:
- other: Expert assessment
- Adequacy of study:
- supporting study
- Study period:
- 2009
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- other: Expert assessment based on guideline criteria and generally accepted scientific principles.
- Qualifier:
- according to guideline
- Guideline:
- other: UN Recommendations on the Transport of Dangerous Goods (Manual of Tests and Criteria, Fourth revised edition, 2003, Appendix 6, “Orange Book”)
- Deviations:
- no
- Principles of method if other than guideline:
- A set of criteria is compiled to identify subtances which may be oxidizing substances.
- GLP compliance:
- no
- Remarks:
- Estimation method, thus GLP criteria not applicable.
- Sample tested:
- other: not specified (migrated information)
- Parameter:
- other: not specified (migrated information)
- Remarks on result:
- other: result not specified (migrated information)
- Remarks:
- Applying the internationally recognized UN Recommendation criteria, cC6O4 ammonium salt is found to be non-oxidizing and therefore is not to be tested experimentally.
- Interpretation of results:
- GHS criteria not met
- Conclusions:
- Applying the internationally recognized UN Recommendation criteria, cC6O4 ammonium salt is found to be non-oxidizing and therefore is not to be tested experimentally for the classification as oxidizing substances.
Thus it can be concluded beyond a reasonable doubt that cC604 ammonium salt is not capable of causing fire or enhancing the risk of fire when in contact with combustible material. - Executive summary:
Criteria The UN Recommendations on the Transport of Dangerous Goods (Manual of Tests and Criteria, Fourth revised edition, 2003, Appendix 6, “Orange Book”) define a screening procedure for substances which may have oxidizing properties:
For organic compounds, the classification procedure using experimental testing need not be applied if:
• the compound does not contain oxygen, fluorine or chlorine; or
• the compound contains oxygen, fluorine or chlorine and these elements are chemically bonded only to carbon or hydrogen.
For inorganic substances, the procedure using experimental testing need not be applied if the substance does not contain any oxygen or halogen atoms.
For organic components the oxygen balance, as calculated based on the UN Recommendations on the Transport of Dangerous Goods, can be used as a further criterion for the assessment of oxidizing properties. In principle a negative oxygen balance indicates a surplus of carbon atoms for a complete reaction according to the following reaction scheme:
CxHyOz + [x + (y/4) – (z/2)] · O2 → x · CO2 + (y/2) · H2O
where CxHyOz is the test item.
The test item cC6O4 ammonium salt is an organic compound which contains oxygen and fluorine. Therefore the second criterion of the Orange Book has to be applied. cC6O4 ammonium salt contains oxygen and fluorine and these elements are chemically bonded only to carbon. Therefore the classification procedure using experimental testing need not be applied.
Additionally, it can be stated that the oxygen balance of cC6O4 ammonium salt is negative as calculated based on the UN Recommendations on the Transport of Dangerous Goods. In principle this means, that there is a surplus of carbon atoms for a complete reaction according to the following reaction scheme:
CxHyOz + [x + (y/4) – (z/2)] · O2 → x · CO2 + (y/2) · H2O
where CxHyOz is the test item.
Reference
The test item cC6O4 ammonium salt is an organic compound which contains oxygen and fluorine. Therefore the second criterion of the Orange Book has to be applied. cC6O4 ammonium salt contains oxygen and fluorine and these elements are chemically bonded only to carbon. Therefore the classification procedure using experimental testing need not be applied.
Additionally, it can be stated that the oxygen balance of cC6O4 ammonium salt is negative as calculated based on the UN Recommendations on the Transport of Dangerous Goods. In principle this means, that there is a surplus of carbon atoms for a complete reaction according to the following reaction scheme:
CxHyOz + [x + (y/4) – (z/2)] · O2 → x · CO2 + (y/2) · H2O
where CxHyOz is the test item.
Description of key information
The determination of the oxidising properties of the test item was performed
in accordance with the UN Recomendations on the Transport of Dangerous
Goods (Manual of tests and Criteria, fourth revised edition, 2003,
Appendix 6, "Orange Book") that define a screening procedure for
substances which may have oxidizing properties. Following this criteria,
cC6O4 ammonium salt is concluded to be not oxidising and therefore an
experimental test does not need to be performed.
Key value for chemical safety assessment
- Oxidising properties:
- non oxidising
Additional information
Justification for classification or non-classification
cC6O4 ammonium salt contains oxygen and fluorine and these elements are chemically bonded only to carbon. Additionally, it can be stated that the oxygen balance of cC6O4 ammonium salt is negative. Since the criteria for a no oxidising substance are satisfied (following the UN Recommendations on the Transport of Dangerous Goods, Manual of tests and Criteria, fourth revised edition, 2003, Appendix 6, "Orange Book") cC6O4 ammonium salt is not to be classified.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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