Registration Dossier

Administrative data

First-aid measures

Emergency measure - Inhalation: Apply symptomatic treatment if intoxication sign appear,
refer to hospital or doctor.
Emergency measure - Eyes: Wash carefully.
Emergency measure - Skin: Wash carefully.
Emergency measure - Ingestion: No specific treatment can be suggested and no antidotes are
known. Apply symptomatic treatment, gastric lavage. Refer to
hospital or doctor.

Fire-fighting measures

Recommended extinguishing agent: CO2, foam, waterfog, dry chemicals.

Product arising from burning: HCl, HF and HCN may be evolved.

(Information derived from previous experience of analogues
products).

Product determined by test: Y

Protective equipment: Self-contained breathing apparatus and full protective gear.

Accidental release measures

Emergency measures in case of spillage: Wear appropriate protective equipment and clothing.

Absorb spilled liquid with dry clay, sawdust or diatomaceus
earth, then sweep up and place in a waste disposal
container. Flush contaminated area with detergent and water,
avoid discharge to the waste water system.

Handling and storage

Handling: Handle with the care due to any chemical. Minimise contact
with eyes and skin by wearing appropriate protective
clothing and equipment. Wear protection over nose and mouth.

Storage: Store the product in its unopened and undamaged original
packages, in well aired cool and dry stores or in shady and
well ventilated places. It is recommended that the product
be kept away from sources of heat, sparks or flames. The
storage areas should be located at suitable distance from
inhabited buildings, animal shelters and food stores, and
should be inaccessible to unauthorized people and domestic
animals.

Packaging of the substance and or preparation: Technical tetraconazole:

120 Lt drums in polyethylene HD HMWPE



Preparations:


1 or 5 Lt receptacles


in polyethylene-glue-ethylenevinyl alcohol closed with a
heat-sealed gasket with a polypropylene plug with internal
threading

or

in high-density polyethylene closed with aluminium membrane
for heat induction and a plastic cap or with a polypropilene
cap with inner thread.

Transport information

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Marine transport (IMDG)

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Air transport ICAO/IATA

Remarks
Transport: ADR/RID Class 9 Item 11° (c)

IMO Class 9
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Exposure controls / personal protection

Stability and reactivity

Danger other than fire: The product degradates when exposed to strong alkalies or to
overheating.

Chemical reaction with water: Stable in water.

Disposal considerations

Industry - Possibility of recovery/recycling: Recovery/recycling of used substance cannot be envisaged
under pratical conditions.

Industry - Possibility of neutralisation: There are no specific procedures or means of neutralization
of potentially hazardous effects.

In case of ingestion no specific treatment or antidote can
be suggested. Apply symptomatic treatment and gastric
lavage. In case of fire adopt normal procedures for
protection against possible formation of HF, HCl and

HCN.

Industry - Possibility of destruction - incineration: Dilute with solvent or other materials to reduce the
chlorine content to 2% max. Use a suitable hoven fed by a
mixture of air and methane at 1100-1200 C. Convey in an
absorption system with aqueous suspension of 18-20 % Ca(OH)2

the HF and HCl which form.

Public at large - Possibility of recovery/recycling: Recovery/recycling of used substance cannot be envisaged
under practical conditions.

Public at large - Possibility of neutralisation: There are no specific procedures or means of neutralization
of potentially hazardous effects.

In case of ingestion no specific treatment or antidote can
be suggested. Apply symptomatic treatment and gastric
lavage. No antidote is known. No specific treatments are
known.

In case of fire adopt normal procedures for protec-

tion against possible formation of HF, HCl and HCN.

Public at large - Possibility of destruction: controlled discharge: The substance is slowly degraded.

Public at large - Possibility of destruction - incineration: See 6.1.5

Public at large - Possibility of destruction - water purification: The substance is slowly degraded.