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Physical & Chemical properties

Flash point

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Reference
Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
26 November 2015 - 16 March 2016
Reliability:
1 (reliable without restriction)
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Deviations:
no
Qualifier:
according to guideline
Guideline:
ISO No., other: UN Transport Regulation Class 3 (2009)
Deviations:
no
Qualifier:
according to guideline
Guideline:
ISO 2719 (Determination of flash point - Pensky-Martens closed cup method)
Version / remarks:
2002
GLP compliance:
yes (incl. QA statement)
Type of method:
closed cup
Flash point:
69 °C
Atm. press.:
1 019.7 hPa
Remarks on result:
other: Preliminary test (Amount of test item 49 g) lowest temperature where an ignition was observed
Flash point:
66 °C
Atm. press.:
1 019.6 hPa
Remarks on result:
other: Main test (Amount of test item 52.6 g) the lowest temperature where an ignition was observed was 65.8°C (Corrected flash point)
Flash point:
66 °C
Atm. press.:
1 019.7 hPa
Remarks on result:
other: Main test (Amount of test item 53.3 g) the lowest temperature where an ignition was observed was 65.8°C (Corrected flash point)

Preliminary test

Table 1: Preliminary test

Amount of test item / g

Temperature / °C

Ignition (+/-)

Air pressure / hPa

49

69.0

+

1019.7

In the preliminary test the lowest temperature where an ignition was observed was 69.0 °C.

Main Test

The results of the main test are summarized in the following table. The result “ignition” is indicated by + and “no ignition” by -.

Table 2: Main test

Amount of test item / g

Temperature /
°C

Ignition /
(+/-)

Air pressure /
hPa

Corrected flash point / °C

52.6

66.0

+

1019.6

65.8

53.3

66.0

+

1019.7

65.8

In the main test the lowest temperature where an ignition was observed was 65.8 °C.

The measured flash points are corrected to the ambient pressure and averaged to be 65.8 °C.

The resulting average corrected flash point rounded down to the nearest multiple of 0.5 °C is 65.5 °C.

Conclusions:
Final Results:
The test item N,N-Dimethyloctan-1-amine has a flash point of 65.5 °C (average corrected and rounded down to the nearest multiple of 0.5 °C) according to Regulation EC No. 440/2008 Method A.9. Flash Point and DIN EN ISO 2719 (2003).
According to the results of the test on the flash point, the test item is classified as following:
UN Transport Regulation: With a flash point of 65.5 °C (> 60 °C), the test item does not have to be classified as flammable liquid in class 3 according to the UN Transport Regulation.
GHS (CLP Regulation EC 1272/2008 Annex 1: 2.6): With a flash point of 65.5 °C (> 60 °C), the test item does not have to be classified as flammable liquid according to GHS or CLP Regulation EC 1272/2008 Annex 1.
Directive 67/548/EEC: With a flash point of 65.5 °C (> 55 °C) the test item has not to be classified.

Executive summary:

Report:Hernandez, C.(2016): N,N-Dimethyloctan-1-amine Determination of physico-chemical properties Flash Point (EC A.9 and UN Class 3)

Source:consilab Gesellschaft für Anlagensicherheit mbH, Industriepark Höchst, G830/G840, 65926 Frankfurt am Main, Germany;

unpublished Report:CSL-15 -1314.06; Eurofins Study-No. S15 -06210

Guidelines: DIN EN ISO 2719 (2003) and EC A.9

Deviations:no

GLP:yes (incl. certificate)

Materials and Methods: closed cup

Study period: 26 November 2015 to 16 March 2016

Results : The test itemN,N-Dimethyloctan-1-amine has a flash point of 65.5 °C (average corrected and rounded down to the nearest multiple of 0.5 °C) according to Regulation EC No. 440/2008 Method A.9. Flash Point and DIN EN ISO 2719 (2003).

According to the results of the test on the flash point, the test item is classified as following:

UN Transport Regulation: With a flash point of 65.5 °C (> 60 °C), the test item does not have to be classified as flammable liquid in class 3 according to the UN Transport Regulation.

GHS (CLP Regulation EC 1272/2008 Annex 1: 2.6): With a flash point of 65.5 °C (> 60 °C), the test item does not have to be classified as flammable liquid according to GHS or CLP RegulationEC 1272/2008 Annex 1.

Directive 67/548/EEC: With a flash point of 65.5 °C (> 55 °C) the test item has not to be classified.

Table 1: Classifications

 

UN Transport Regulation

GHS (CLP Regulation EC 1272/2008)

Directive 67/548/EEC

Flammable Liquid

Not classified in Class 3 as Flammable liquid

Not classified as Flammable liquid

Not classified as Flammable liquid

Description of key information

Key value for chemical safety assessment

Flash point at 101 325 Pa:
65.5 °C

Additional information