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Reference
Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2018-06-15 to 2018-06-18
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
equivalent or similar to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Key result
Remarks on result:
no self ignition observed under the test conditions

In the investigation of self-ignition in the Grewer Oven for the pure test item a slight endothermic process was detected starting at approx.50 °C. After the test, the test item in the wire basket was a black mass. No self-ignition could be observed up to the maximum oven temperature of 400 °C.

 

Results of the screening test for self-ignition in the Gewer-Oven

Experiment

Onset self-
ignition / °C

Maximum temperature / °C

Pure test item

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Conclusions:
No self-ignition could be observed up to the maximum oven temperature of 400 °C.
Executive summary:

A study was conducted according to VDI 2263, part 1 1990, test methods for the determination of the safety characteristics of dusts; UN Transport Regulations, Appendix 6, Screening Procedures (Substances which may be liable to spontaneous combustion (Division 4.2)) to determine the self-ignition temperature of the test item. For this purpose, the test item was filled in a small wire basket of a volume of 8 cm3 and this wire-basket was placed into the oven. In this oven, the self-ignition behavior of five samples can be determined simultaneously.An additional basket was filled with a reference material (graphite). No self-ignition could be observed up to the maximum oven temperature of 400 °C.

Description of key information

No self-ignition could be observed up to the maximum oven temperature of 400 °C.

Key value for chemical safety assessment

Additional information

A study was conducted according to VDI 2263, part 1 1990, test methods for the determination of the safety characteristics of dusts; UN Transport Regulations, Appendix 6, Screening Procedures (Substances which may be liable to spontaneous combustion (Division 4.2)) to determine the self-ignition temperature of the test item. For this purpose, the test item was filled in a small wire basket of a volume of 8 cm3 and this wire-basket was placed into the oven. In this oven, the self-ignition behavior of five samples can be determined simultaneously. An additional basket was filled with a reference material (graphite).No self-ignition could be observed up to the maximum oven temperature of 400 °C.